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US3644113A Expired / Lapsed US ⏱️ 0.0 years remaining

Agglomerate including graft copolymers of acylic acid and methyl cellulose and method of making

Assignee: International Minerals and Chemical Corp
•
Filing: 1968-09-04
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Granted: 1972-02-22
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Expires: 1988-09-04
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Abstract

Abstract Water-soluble graft copolymers of acrylic acid and methyl cellulose, including water-soluble salts thereof, are useful as binders in the agglomeration of finely divided materials. The graft copolymers are especially useful as binders in the pelletization of minerals and ores, such as taconite.

Inventors

  • 👤 William J Lang
  • 👤 Joseph M Chelini

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 14:03
CPC Classifications
C; C22; C22B; C22B1/00; C22B1/14; C22B1/24; C22B1/242; C08; C08F; C08F251/00

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 62 words
A method in accordance with claim 1 wherein said graft copolymerization product is an ultraviolet light or peroxygen-type compound induced graft copolymerization product, and from about 0.002 to about 20 pounds of said graft copolymer per ton of said material and from zero to about 30 pounds of a bentonite clay per ton of said material is added to said wetted mass.
Claim 2
Dependent Claim 44 words
A method in accordance with claim 1 wherein said graft copolymerization product is a peroxide free radical induced graft copolymerization product, and said wetted mass contains from about 2 to about 20 percent by weight of water, based on the weight of said material.
Claim 3
Dependent Claim 30 words
A method in accordance with claim 3 wherein from about 0.2 to about 20 pounds of said graft copolymer per ton of said material is added to said wetted mass.
Claim 4
Dependent Claim 15 words
A method in accordance with claim 3 wherein said finely divided material is a mineral.
Claim 5
Dependent Claim 15 words
A method in accordance with claim 5 wherein said bentonite clay is a bentonitic clay.
Claim 6
Dependent Claim 15 words
A method in accordance with claim 5 wherein said bentonite clay is a subbentonitic clay.
Claim 7
Dependent Claim 18 words
A method in accordance with claim 7 wherein said bentonite clay is a soda ash treated subbentonitic clay.
Claim 8
Dependent Claim 30 words
A method in accordance with claim 5 wherein from about 0.5 to about 5 pounds of said graft copolymer per ton of said material is added to said wetted mass.
Claim 9
Dependent Claim 39 words
A method in accordance with claim 9 wherein said finely divided material is an iron ore and said wetted mass contains from about 5 to about 12 percent by weight of water, based on the weight of said material.
Claim 10
Dependent Claim 14 words
A method in accordance with claim 10 wherein said finely divided material is taconite.
Claim 11
Dependent Claim 47 words
A method in accordance with claim 10 wherein from about 0.002 to about 0.15 pound of said graft copolymer per ton of said material and from about 8 to about 30 pounds of a bentonitic clay per ton of said material is added to said wetted mass.
Claim 12
Dependent Claim 49 words
A method in accordance with claim 10 wherein from about 0.004 to about 0.15 pound of said graft copolymer per ton of said material and from about 12 to about 30 pounds of a soda ash-treated subbentonitic clay per ton of said material is added to said wetted mass.
Claim 13
Dependent Claim 23 words
A method in accordance with claim 10 wherein said finely divided material has a size of about 90 percent minus 325 mesh. 90
Claim 14
Dependent Claim 68 words
As a composition of matter, an agglomerate of finely divided material held together by a binder comprising a water-soluble graft copolymer or said graft copolymer and a bentonite clay, said graft copolymer being a graft copolymerization product of acrylic acid and from about 0.1 to about 10 percent, based on the weight of said acrylic acid, of methyl cellulose, or a water-soluble salt of said graft copolymerization product.
Claim 15
Dependent Claim 58 words
A composition of matter in accordance with claim 15 containing from about 0.002 to about 20 pounds of said graft copolymer per ton of said material and from about zero to about 30 pounds of said bentonite clay per ton of said material and said graft copolymerization product is an ultraviolet light or peroxygen-type compound graft copolymerization product.
Claim 16
Dependent Claim 46 words
A composition of matter in accordance with claim 16 wherein said graft copolymer is a peroxide free radical induced graft copolymerization product, and water in the amount of from about 5 to about 12 percent by weight, based on the weight of said material, is present.
Claim 17
Dependent Claim 18 words
A composition of matter in accordance with claim 17 wherein said finely divided material is an iron ore.
Claim 18
Dependent Claim 32 words
A composition of matter in accordance with claim 18 wherein said agglomerate is held together by from about 0.5 to about 5 pounds of said graft copolymer per ton of said material.
Claim 19
Dependent Claim 49 words
A composition of matter in accordance with claim 18 wherein said agglomerate is held together by from about 0.002 to about 0.15 pound of said graft copolymer per ton of said material and from about 8 to about 30 pounds of a bentonitic clay per ton of said material.
Claim 20
Dependent Claim 52 words
A composition of matter in accordance with claim 18 wherein said agglomerate is held together by from about 0.004 to about 0.15 pound of said graft copolymer per ton of said material and from about 12 to about 30 pounds of a soda ash treated subbentonitic clay per ton of said material.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-02-21 1975-08-23 1976-02-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-02-21 1979-08-23 1980-02-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-02-21 1983-08-23 1984-02-22 $7700.00 Window Closed / Lapsed

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