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US3642431A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of removing hydrogen sulfide from gaseous mixtures

Assignee: Chevron USA Inc
•
Filing: 1969-09-19
•
Granted: 1972-02-15
•
Expires: 1989-09-19
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Abstract

Abstract The process for selectively removing H2S and like sulfides from fluids containing them by contact with a substantially hydroxylfree solvent such as N-methyl-2-pyrrolidone, a dicarboxylic acid anhydride soluble in said solvent and an alkali hydrosulfide. Preferably, in the process an admixture of H2S and CO2 in natural gas is contacted with the contacting solution to react the H2S with said anhydride, the CO2 and/or like hydrocarbons are rejected from the contacting solution by mild heating and/or pressure reduction and thereafter H2S is regenerated by heating the remaining solution.

Inventors

  • 👤 Shigeto Suzuki
  • 👤 Karl H Kilgren
  • 👤 Giok H Tjoa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 06:21
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52; B01D53/526; C; C07; C07C; C07C7/00; C07C7/148; C07C7/14875

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 11 words
The process of claim 1 wherein said solvent is a pyrrolidone.
Claim 2
Dependent Claim 23 words
The process of claim 1 wherein said solvent is N-methyl-2-pyrrolidone and said contacting is carried out at a temperature below about 250* F.
Claim 3
Dependent Claim 13 words
The process of claim 1 wherein said anhydride is an alkenyl succinic anhydride.
Claim 4
Dependent Claim 13 words
The process of claim 1 wherein said anhydride is an alkylated succinic anhydride.
Claim 5
Dependent Claim 12 words
The process of claim 1 wherein said anhydride is a phthalic anhydride.
Claim 6
Dependent Claim 21 words
The process of claim 1 wherein solvent initially contains a compound capable of producing an alkali Hydrosulfide under the reaction conditions.
Claim 7
Dependent Claim 12 words
The process of claim 1 wherein said alkali hydrosulfide is potassium hydrosulfide.
Claim 8
Dependent Claim 19 words
The process of claim 1 wherein said dicarboxylic acid anhydride is free from olefinic groups in the anhydride ring.

References Cited (Backward Citations)

US1580451A Cited
US1990217A Cited
US3120993A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-02-14 1975-08-16 1976-02-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-02-14 1979-08-16 1980-02-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-02-14 1983-08-16 1984-02-15 $7700.00 Window Closed / Lapsed

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