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US3640753A Expired / Lapsed US ⏱️ 0.0 years remaining

Manufacture of poromeric materials

Assignee: BASF SE
•
Filing: 1969-10-31
•
Granted: 1972-02-08
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Expires: 1989-10-31
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Abstract

Abstract The process of making poromeric materials which comprises impregnating webs of fibrous material with aqueous liquids containing olefinically unsaturated monomers which can be polymerized using redox catalysts, and, if desired, high polymeric plastics in dissolved, emulsified or dispersed form, freezing the webs of fibrous materials impregnated with the aqueous liquids, polymerizing the monomers using redox catalysts and thawing out and separating out the water and any residual monomer from the resulting poromeric materials. These poromeric materials are suitable as floor coverings, insulating materials, leather substitutes and coating materials.

Inventors

  • 👤 Carl Heinrich Krauch
  • 👤 Axel Sanner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 23:53
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/28; D; D06; D06M; D06M14/00; C08J2357/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 39 words
A process as in claim 1 wherein the aqueous liquids additionally contain C. high polymeric plastics which are dispersible or soluble in water, in an amount of from 0.1 to 50 percent by weight based on the aqueous liquid.
Claim 2
Dependent Claim 146 words
A process for the manufacture of poromeric materials which comprises impregnating webs of fibrous material with aqueous liquids containing monoolefinically unsaturated monomers which can be polymerized with redox catalysts, in an amount of from 0.1 to 30 percent by weight based on the aqueous liquid, and high polymeric plastics which are dispersible or soluble in water, in an amount of from 0.1 to 50 percent by weight based on the aqueous liquid in dissolved, emulsified or dispersed form, cooling the webs of fibrous material impregnated with the said aqueous liquids to temperatures at which the said liquids undergo at least partial solidification, polymerizing the unsaturated monomers using redox catalysts, at least one component of which is not added until after the said liquids have undergone complete or partial crystalline solidification, thawing out and separating the water and any residual unsaturated monomers from the resulting poromeric materials.
Claim 3
Dependent Claim 27 words
A process as in claim 1 wherein the monoolefinically unsaturated monomers are acrylic or methacrylic esters of alcohols having one to eight carbon atoms, acrylamides or methacrylamides.
Claim 4
Dependent Claim 76 words
A process as in claim 1 wherein the polyolefinically unsaturated monomers are those having the general formula X-R-Y where X and Y are vinyl, allyl, acryloyl or methacryloyl radicals and R is -O-, -NH-, a bivalent radical of an aliphatic or aromatic dicarboxylic acid having four to eight carbon atoms, a bivalent radical of a glycol having two to 10 carbon atoms or a bivalent radical of an aliphatic diamine having two to six carbon atoms.
Claim 5
Dependent Claim 60 words
A process as in claim 1 wherein the high polymeric plastics are in aqueous dispersion and are selected from the group consisting of homopolymers and copolymers of acrylic esters of alcohols having one to eight carbon atoms, of methacrylic esters of alcohols having one to eight carbon atoms, of acrylamides, of methacrylamides and of mixtures of said homopolymers and copolymers.
Claim 6
Dependent Claim 25 words
A process as in claim 3 wherein the monomers are acrylic or methacrylic esters of alcohols having one to eight carbon atoms, acrylamides or methacrylamides.
Claim 7
Dependent Claim 60 words
A process as in claim 3 wherein the high polymeric plastics are in aqueous dispersion and are selected from the group consisting of homopolymers and copolymers of acrylic esters of alcohols having one to eight carbon atoms, of methacrylic esters of alcohols having one to eight carbon atoms, of acrylamides, of methacrylamides and of mixtures of said homopolymers and copolymers.
Claim 8
Dependent Claim 27 words
A process as in claim 1 wherein said impregnated web is in the form of a flat structure having a thickness of about 0.5 to 20 mm.

References Cited (Backward Citations)

US3208875A Cited
GB1102342A Cited
US3428584A Cited
US3527653A Cited
US3492154A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-02-07 1975-08-09 1976-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-02-07 1979-08-09 1980-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-02-07 1983-08-09 1984-02-08 $7700.00 Window Closed / Lapsed

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