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US3625915A Expired / Lapsed US ⏱️ 0.0 years remaining

Antistatic styrene/acrylonitrile-type interpolymer compositions

Assignee: Monsanto SAS
•
Filing: 1968-02-09
•
Granted: 1971-12-07
•
Expires: 1988-02-09
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Abstract

Abstract The electrostatic properties characteristically associated with styrene/acrylonitrile-type interpolymers is greatly reduced by blending with such polymers a combination of certain alkanolamines and certain polyalkylene glycols.

Inventors

  • 👤 Michel Gubler
  • 👤 Joseph Guillon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 06:34
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/17; Y; Y10; Y10S; Y10S260/00; Y10S260/15; Y10S260/17; Y10S260/19

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 14 words
A composition according to claim 1 in which said alkene nitrile compound is acrylonitrile.
Claim 2
Dependent Claim 17 words
interpolymers formed by polymerizing a monovinyl aromatic compound, an alkene nitrile compound, and a conjugated alkadiene monomer;
Claim 3
Dependent Claim 52 words
mechanical blends of (1) or (2) or mixtures of (1) and (2) with a preformed diene polymer rubber produced by polymerizing at least one conjugated alkadiene monomer, optionally in the presence of a monovinyl aromatic compound or an alkene nitrile or a mixture of a monovinyl aromatic compound and an alkene nitrile;
Claim 4
Dependent Claim 14 words
A composition according to claim 2 in which said vinyl aromatic compound is styrene.
Claim 5
Dependent Claim 13 words
A composition according to claim 1 in which the conjugated alkadiene is butadiene.
Claim 6
Dependent Claim 36 words
graft blends of (1) or (2) or mixtures of (1) and (2) produced by polymerizing the monomers used to make such interpolymers in the presence of a preformed diene polymer as characterized in (3) above; and
Claim 7
Dependent Claim 166 words
mixtures of at least two of the foregoing; said monovinyl aromatic compound being selected from the group consisting of styrene, alkyl-substituted styrenes, halogen substituted styrenes, mixed halogen plus alkyl-substituted styrenes, vinyl naphthalene, vinyl anthracene and mixtures of the foregoing; said alkene nitrile compound being selected from the group consisting of acrylonitrile, methacrylonitrile, ethacrylonitrile and mixtures thereof; b. at least one amine of the formula R-N((CH2CHR''-O)mH)nH2 -n where, R is a monovalent aliphatic hydrocarbon group containing from about six through 22 carbon atoms, R'' is selected from the group consisting of hydrogen and methyl, m is an integer of from one through eight, n is the integer 1 or 2, and c. polypropylene glycol having a molecular weight of from 100 through 10,000, and d. said composition containing from about 0.001 to 30 parts by weight of said amine, from about 0.001 to 10 parts by weight of said polypropylene glycol with the balance up to 100 weight percent being said interpolymer system in any given composition.
Claim 8
Dependent Claim 26 words
A composition according to claim 1 in which in the formula of the amine antistatic additive the group R contains from eight to 18 carbon atoms.
Claim 9
Dependent Claim 15 words
A composition according to claim 5 in which R is derived from a coconut oil.
Claim 10
Dependent Claim 18 words
A composition according to claim 1 in which R'' is hydrogen, m is 1 and n is 2.
Claim 11
Dependent Claim 20 words
A composition according to claim 1 in which the amount of amine present is between about 0.5 and 4 percent.
Claim 12
Dependent Claim 19 words
A composition according to claim 1 in which the polypropylene glycol has a molecular weight between 100 and 5,000.
Claim 13
Dependent Claim 21 words
A composition according to claim 1 in which the amount of polypropylene glycol present is between about 0.1 and 0.8 percent.
Claim 14
Dependent Claim 19 words
A composition of claim 1 containing in addition up to about 4 weight percent of a pigment or dye.

References Cited (Backward Citations)

FR1139315A Cited
GB820541A Cited
US3450794A Cited
US3354108A Cited
GB1089810A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-12-06 1975-06-07 1975-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-12-06 1979-06-07 1979-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-12-06 1983-06-07 1983-12-07 $7700.00 Window Closed / Lapsed

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