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US3620984A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyurethane catalysts

Assignee: Bayer AG
•
Filing: 1968-06-25
•
Granted: 1971-11-16
•
Expires: 1988-06-25
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Abstract

Abstract Polyurethane foams are prepared in the presence of a compound containing the grouping WHEREIN R1 and R2 are the same or different alkyl, cycloalkyl, alkoxyalkyl, alkenyl or aralkyl radicals or are members of a common cycloaliphatic or heterocyclic structure when the silicon atom is part of a silane or lower polysiloxane grouping; or R1 has the above meaning and R2 denotes an hydroxylalkyl or aminoalkyl group attached to the silicon atom through the oxygen or nitrogen atoms respectively. The invention contemplates complexes or mixtures of these compounds with organic metallic compounds also as catalysts. In addition new activator mixtures containing these catalysts are contemplated.

Inventors

  • 👤 Manfred Dahm
  • 👤 Hans Niederprum
  • 👤 Walter Simmler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 22:53
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/161; C08G18/163; C08G18/18; C08G18/1883; C08G18/20; C08G18/209

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 17 words
The reaction of claim 1 wherein the catalyst is either an aminosilyl-N-heterocyclic compound or a monosiloxy-N-heterocyclic compound.
Claim 2
Dependent Claim 12 words
The reaction of claim 1 wherein the catalyst is an aminomethyl silane.
Claim 3
Dependent Claim 12 words
The reaction of claim 1 wherein the catalyst is an a,w-bis(dialkylaminomethyl) disiloxane.
Claim 4
Dependent Claim 11 words
The reaction of claim 1 wherein the catalyst has the structure
Claim 5
Dependent Claim 28 words
The reaction of claim 1 wherein the catalyst has the structure wherein R4 is an alkoxy group having from one to 12 carbon atoms or a morpholine group.
Claim 6
Dependent Claim 30 words
The reaction of claim 1 wherein a member selected from the group consisting of a tertiary amine and an organometallic catalyst or mixtures thereof is included in the reaction mixture.
Claim 7
Dependent Claim 20 words
The reaction of claim 1 wherein water is used as a blowing agent in the preparation of a cellular polyurethane.
Claim 8
Dependent Claim 18 words
The reaction of claim 1 wherein said compound having the grouping is premixed with an organic metallic compound.
Claim 9
Dependent Claim 11 words
The reaction of claim 1 wherein the catalyst has the structure
Claim 10
Independent Claim 47 words
The method of preparing cellular polyurethanes which comprises reacting in the presence of a blowing agent an organic polyisocyanate with a compound containing at least two active hydrogen containing groups as determined by the Zerewitinoff method in the presence of a catalytic amount of the catalyst containing
Claim 11
Dependent Claim 11 words
The method of claim 11 wherein the catalyst has the formula
Claim 12
Dependent Claim 11 words
The method of claim 11 wherein the catalyst has the formula
Claim 13
Dependent Claim 23 words
The method of claim 11 wherein the reaction mixture contains a stannous salt of a carboxylic acid having one to 18 carbon atoms.
Claim 14
Dependent Claim 15 words
The method of claim 14 wherein the stannous salt is stannous octoate or stannous oleate.
Claim 15
Dependent Claim 14 words
The method of claim 12 wherein the catalyst contains stannous octoate or stannous oleate.
Claim 16
Dependent Claim 14 words
The method of claim 13 wherein the catalyst contains stannous octoate or stannous oleate.
Claim 17
Dependent Claim 102 words
An activator for the reaction between isocyanates and compounds containing active hydrogen groups reactive with isocyanates which comprises a mixture of an organic metallic compound and a sila-amine having the grouping wherein R1 and R2 are the same or different alkyl, cycloalkyl, alkoxyalkyl, alkenyl or aralkyl radicals or are members of a common cycloaliphatic or heterocyclic structure when the silicon atom is part of a silane or lower polysiloxane grouping; or R1 has the above meaning and R2 denotes an hydroxylalkyl or aminoalkyl group attached to the silicon atom through the oxygen or nitrogen atoms respectively in an alkoxysilyl or aminosilyl linkage.
Claim 18
Dependent Claim 14 words
The activator of claim 18 which comprises a mixture of stannous octoate and 2,2,4-trimethyl-2-sila-morpholine.

References Cited (Backward Citations)

US3194773A Cited
US3397158A Cited
US3243475A Cited
DE1246233B Cited
US3420782A Cited
US3170891A Cited
US3278485A Cited
DE1229290B Cited
FR1476500A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-11-15 1975-05-17 1975-11-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-11-15 1979-05-17 1979-11-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-11-15 1983-05-17 1983-11-16 $7700.00 Window Closed / Lapsed

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