Hydride and carbonyl triphenylphosphine derivatives of ruthenium and osmium
Abstract
Abstract PENTACOORDINATE COMPLEXES OF RUTHENIUM AND OSMIUM OF THE GENERAL FORMULA M(CO)S-N(P(C6H5)3)N M=RU, OS, N=1,2, ARE PREPARED BY REACTING THE CORRESPONDING PENTACARBONYLS WITH TRIPHENYLPHOSPHINE. ALSO DIHYDRIDO COMPOUNDS OF FORMULA MH2(CO)2(P(C6H5)2)2 (M=RU, OS) ARE DESCRIBED. THESE DIHYDRIO DERIVATIVES CAN BE PRODUCED BY REACTING THE CORRESPONDING TRICARBONYLBIS (TRIPHENYLPHOSHINE) COMPOUNDS, M(CO)3(P(C6H5)2)2, WITH HYDROGEN. ALSO THE PREPARATION OF OSH2(CO)2P(C6H5)3 FROM OS(CO)4P(C6H5)O AND HYDROGEN IS DICLOSED IN THE PRESENT INVENTION. THE TETRACARBONYL COMPOUNDS M(CO)4P(C5H5)2 AND THE DIHYDRIDO COMPOUNDS MH2(CO)2(P(C6H5)2)2 ARE NEW CHEMICAL COMPOUNDS. THE COMPOUNDS HAVE UTILITY AS HYDROGENATION CATALYSTS.
Inventors
- 👤 Francois L Eplattenier
- 👤 Fausto Calderazzo
Bibliographic Details
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