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US3593794A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and composition for treating low-temperature subterranean formations

Assignee: Individual
•
Filing: 1970-02-24
•
Granted: 1971-07-20
•
Expires: 1990-02-24
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Abstract

Abstract A water-insoluble particulate composition having controlled oil solubility is disclosed. This composition is comprised of solid particles of a homogenous mixture of (1) about 10 to 13 weight percent of an ethylene-vinyl acetate copolymer that contains about 23 to 30 weight percent vinyl acetate and exhibits a melt index of about 300 to 500 grams per 10 minutes and (2) a paraffin wax that contains at least 70 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule. Also, a process employing this particulate composition in drilling wells into lowtemperature subterranean formations, and in fracturing and treating such formations, is disclosed.

Inventors

  • 👤 Paul W Fischer
  • 👤 John W Scheffel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 22:48
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/62; C09K8/70; C09K8/66; C09K8/68; C09K8/72; C09K8/74; C09K8/76; Y; Y10; Y10S; Y10S507/00; Y10S507/922

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 54 words
The method defined in claim 1 wherein said ethylene-vinyl acetate copolymer contains about 24 to 26 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes, and wherein said paraffin wax contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 2
Dependent Claim 54 words
The method defined in claim 1 wherein said ethylene-vinyl acetate copolymer contains about 27 to 29 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes, and wherein said paraffin wax contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 3
Dependent Claim 18 words
The method defined in claim 1 wherein the temperature of said formation is less than about 125* F.
Claim 4
Independent Claim 122 words
The method of completing a well drilled into a permeable, low-temperature, subterranean formation which comprises circulating a completion fluid from the surface to a drilling zone in said formation during the drilling operation and returning to the surface at least a portion of said fluid, said completion fluid comprising a liquid having suspended therein discrete slowly oil-soluble, water-insoluble, solid particles comprised of a homogeneous mixture of (1) about 10 to 13 weight percent of an ethylene-vinyl acetate copolymer that contains about 23 to 30 weight percent vinyl acetate and exhibits a melt index of about 300 to 500 grams per 10 minutes and (2) parafin wax that contains at least 70 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 5
Dependent Claim 54 words
The method defined in claim 5 wherein said ethylene-vinyl acetate copolymer contains about 24 to 26 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes, and wherein said paraffin wax contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 6
Dependent Claim 54 words
The method defined in claim 5 wherein said ethylene-vinyl acetate copolymer contains between about 27 to 29 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes, and wherein said paraffin wax contains at least 90 percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 7
Dependent Claim 18 words
The method defined in claim 5 wherein the temperature of said formation is less than about 125* F.
Claim 8
Independent Claim 116 words
A method of fracturing a permeable, low-temperature subterranean formation penetrated by a well which comprises injecting a fracturing fluid into said well and into contact with said formation at a pressure and volumetric flow rate sufficient to fracture said formation, said fracturing fluid comprising a liquid having suspended therein discrete oil-soluble, water-insoluble, solid particles of a homogeneous mixture of (1) about 10 to 13 weight percent of an ethylene-vinyl acetate copolymer that contains about 23 to 30 weight percent vinyl acetate and that exhibits a melt index of about 300 to 500 gramS per 10 minutes and (2) paraffin wax that contains at least 70 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 9
Dependent Claim 54 words
The method defined in claim 9 wherein said ethylene-vinyl acetate copolymer contains about 24 to 26 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes, and wherein said paraffin wax contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 10
Dependent Claim 54 words
The method defined in claim 9 wherein said ethylene-vinyl acetate copolymer contains about 27 to 29 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes, and wherein said paraffin wax contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 11
Dependent Claim 18 words
The method defined in claim 9 wherein the temperature of said formation is less than about 125* F.
Claim 12
Dependent Claim 68 words
A well-treating composition comprising discrete solid particles of a homogeneous mixture of (1) about 10 to 13 weight percent of an ethylene-vinyl acetate copolymer that contains about 23 to 30 weight percent vinyl acetate and exhibits a melt index of about 300 to 500 grams per 10 minutes and (2) paraffin wax that contains at least 70 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 13
Dependent Claim 24 words
The composition defined in claim 13 wherein said wax contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 14
Dependent Claim 34 words
The composition defined in claim 13 wherein said ethylene-vinyl acetate copolymer contains about 24 to 26 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes.
Claim 15
Dependent Claim 34 words
The composition defined in claim 13 wherein said ethylene-vinyl acetate copolymer contains about 27 to 29 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes.
Claim 16
Dependent Claim 25 words
The composition defined in claim 13 wherein said discrete particles have a mean diameter within the range of about 1 micron to about one-half inch.
Claim 17
Dependent Claim 73 words
A well-treating composition comprising discrete solid particles of a homogeneous mixture of (1) about 10 to 13 weight percent of an ethylene-vinyl acetate copolymer that contains about 24 to 26 weight percent vinyl acetate and that exhibits a melt index of about 335 to 465 grams per 10 minutes and (2) a fully refined crystalline paraffin wax that contains at least 90 weight percent hydrocarbons having 25 to 32 carbon atoms per molecule.
Claim 18
Dependent Claim 73 words
A well-treating composition comprising discrete solid particles of a homogeneous mixture of (1) about 10 to 13 weight percent of an ethylene-vinyl acetate copolymer that contains about 27 to 29 weight percent vinyl acetate and exhibits a melt index of about 335 to 465 grams per 10 minutes and (2) a fully refined, crystalline paraffin wax that contains at least 90 weight percent hydrocarbons having about 25 to 32 carbon atoms per molecule.

References Cited (Backward Citations)

US3316965A Cited
US3370650A Cited
US3455390A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-07-19 1975-01-18 1975-07-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-07-19 1979-01-18 1979-07-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-07-19 1983-01-18 1983-07-20 $7700.00 Window Closed / Lapsed

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