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US3582623A Expired / Lapsed US ⏱️ 0.0 years remaining

Detection of mixtures of narrow band photoluminescers

Assignee: Wyeth Holdings LLC
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Filing: 1969-01-10
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Granted: 1971-06-01
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Expires: 1989-01-10
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Abstract

Abstract Readout process and apparatus for reading coded symbols in a code in which the components are narrow band photoluminescent compositions. The symbols, on suitable substrates such as paper tape, labels on cans, bottles and the like, are illuminated by flashes from a xenon tube with an ultraviolet transmitting filter. The flashing tube is aimable so that it can be directed either on a window in front of which tape containing the symbols is passed or through another window onto containers with labels and the like. Suitable optics are moved into position so that the different locations of the substrate do not change the image path length. When the symbols are illuminated with successive ultraviolet flashes, they luminesce in the visible in the different narrow band colors corresponding to the different components and this is imaged on a filter wheel having the same number of filters as there are components: four for numerical work or six for alphanumeric work. After passing through the filter wheel, the visible beam is imaged on the cathode of a photomultiplier tube. The filter wheel also is provided with magnets which open switches connecting the photomultiplier tube to different circuits for each filter and also generate a trigger pulse which triggers the flashes of the xenon tube in synchronism with the positioning of each filter by the rotation of the wheel. The signal from the photomultiplier tube passes through amplifiers, one for each filter, and into logic circuits which provide for gates to select the particular signal from a particular filtered beam and also start readout at the beginning of a symbol and reset after the filter wheel has made a second full revolution during which no signals are received. Response of each amplifier is delayed about 20 Mu sec. so that the extremely short-persistence fluorescence from such compounds as optical brighteners and the like has died out and response is only from the slower decaying photoluminescence of the narrow band code components. The logic circuits send out coded signals corresponding to the code to display mechanisms, such as Nixie tubes, or a permanent recording, such as a solenoid driven typewriter of the computer readout type, or both, or to a solenoid driven diverter for deflection from a conveyor system.

Inventors

  • 👤 John L Rothery
  • 👤 Walter John Greene

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 08:30
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/22; G; G06; G06K; G06K7/00; G06K7/10; G06K7/12

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 228 words
A process for the readout of coded symbols, the code being represented by the absence or presence in at least one level of photoluminescent materials which luminesce under ultraviolet illumination and which therefore permit a choice of symbols represented by Xn-1, where X is one more than the levels at which the components may be present, which comprises, a. illuminating a marking area containing the coded symbol with brief flashes of short wave radiation, b. optically imaging photoluminescence from the marking area onto at least one detector, transforming radiation striking the detector into an electrical signal, c. sequentially limiting radiation to the detector to that of a single code component, d. starting electrical readout by the occurrence of two signals, one in synchronism with sequential limitation of the whole number of different components and the second the first electrical signal from the detector above a predetermined low level, e. amplifying the signals from the detector in separate channels sequentially, the channel amplifying only the signals corresponding to its component, f. temporarily storing the amplified signals from each channel, and g. decoding the stored signals after a full sequence into forms corresponding to the symbols represented by the code and of suitable nAture for initiating at least one operation selected from the group consisting of visual display, printout, and other logical operations requiring the same type of electrical signal.
Claim 2
Dependent Claim 228 words
A process for the readout of coded symbols, the code being represented by the absence or presence in at least one level of photoluminescent materials which luminesce under ultraviolet illumination and which therefore permit a choice of symbols represented by Xn-1, where X is one more than the levels at which the components may be present, which comprises, a. illuminating a marking area containing the coded symbol with brief flashes of short wave radiation, b. optically imaging photoluminescence from the marking area onto at least one detector, transforming radiation striking the detector into an electrical signal, c. sequentially limiting radiation to the detector to that of a single code component, d. starting electrical readout by the occurrence of two signals, one in synchronism with sequential limitation of the whole number of different components and the second the first electrical signal from the detector above a predetermined low level, e. amplifying the signals from the detector in separate channels sequentially, the channel amplifying only the signals corresponding to its component, f. temporarily storing the amplified signals from each channel, and g. decoding the stored signals after a full sequence into forms corresponding to the symbols represented by the code and of suitable nAture for initiating at least one operation selected from the group consisting of visual display, printout, and other logical operations requiring the same type of electrical signal.
Claim 3
Dependent Claim 29 words
A process according to claim 1 in which the code is represented by the presence or absence of a photoluminescent component and the choice of symbols is, therefore, 2n-1.
Claim 4
Dependent Claim 59 words
A process according to claim 2 in which the components of the code have multimicrosecond decay half-lives and storage of the signals from the detectors takes place after a delay less than the decay half-life of the component but much longer than the decay half-life of organic fluorescers which have decay half-lives of a small fraction of a microsecond.
Claim 5
Dependent Claim 53 words
A process according to claim 3 in which there is a single detector and the sequential irradiation in the wavelength ranges of the photoluminescence of the different components is effected by filtering out luminescence in wavelength ranges outside that of the particular detector components the luminescence from which is to irradiate the detector.
Claim 6
Dependent Claim 27 words
A process according to claim 4 in which the photoluminescent components of the code are complexes containing different lanthanide ions having an atomic number greater than 57.
Claim 7
Dependent Claim 345 words
An apparatus for carrying out the process of claim 4 comprising in combination, a. a short-duration, intense, gaseous-discharge flash tube provided with a filter passing ultraviolet light but substantially opaque to visible light, b. means for imaging flashes from the flash tube onto the plane of a marking area containing a coded symbol, c. a single detector responsive to longer wave radiation at least through the visible range, d. means for imaging radiation from the marking area corresponding to coded components therein onto the detector, e. a filter wheel and means for rotating it, the wheel being located to interpose successive filters in the luminescent radiation, each filter passing a wavelength band including the wavelength range of only a single component, f. means driven in synchronism with the filter wheel to trigger flashes from the flash tube each time a filter is interposed in the luminescence beam, g. a plurality of electronic amplifying and processing circuits receiving inputs from the photodetector, the number of channels being equal to the number of components, h. means operated in synchronism with the filter wheel to open the electronic circuits for a single channel only each time a particular filter is interposed in the luminescence radiation, i. a plurality of temporary electronic signal storage means equal in number to the channels and responsive to input signals of at least one level, means for connecting the output of each channel to one of the electronic signal storage means, j. electronic decoding means for transforming stored signals into separate signals corresponding to particular coded symbols represented by one or more photoluminescent components, and k. means for initiating actuation of a full sequence of channels representing a full revolution of the filter wheel, said means being operated in synchronism with the filter wheel and including means controlled by the first filter receiving luminescence radiation to produce a signal from the photodetector of predetermined level and means for resetting the electronic circuits actuated by a full revolution of the filter wheel during which no signals of predetermined level are produced from any component.
Claim 8
Dependent Claim 52 words
An apparatus according to claim 6 in which the electronic processing circuits include an electronic time delay less than the half-life decay of photoluminescence from any components but more than a microsecond whereby very short life luminescence from organic fluorescent material, such as optical brighteners, do not reach the electronic signal storage.
Claim 9
Dependent Claim 53 words
An apparatus according to claim 7 in which the flash tube is movable to one of at least two positions and optical means moved by the same movement to image the flashes from the flash tube onto substrates at different distances and to image luminescent radiation from these different distances onto the photodetector.
Claim 10
Dependent Claim 14 words
An apparatus according to claim 8 in which the photodetector is a photomultiplier tube.
Claim 11
Dependent Claim 14 words
An apparatus according to claim 7 in which the photodetector is a photomultiplier tube.

References Cited (Backward Citations)

US3059112A Cited
US3289172A Cited
US3387285A Cited
US3502851A Cited
US3473027A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-05-31 1974-11-30 1975-06-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-05-31 1978-11-30 1979-06-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-05-31 1982-11-30 1983-06-01 $7700.00 Window Closed / Lapsed

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