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US3572838A Expired / Lapsed US ⏱️ 0.0 years remaining

Recovery of aluminum compounds and oil from oil shale formations

Assignee: Shell USA Inc
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Filing: 1969-07-07
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Granted: 1971-03-30
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Expires: 1989-07-07
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Abstract

Abstract An improved, new and novel method of recovery of oil and aluminum-containing compounds from subterranean oil shale formations, by treating such formations with alternating slugs of a pyrolytically extractive fluid and an aqueous alkaline fluid containing an acid-insoluble chelating agent and recovering oil and aluminum compounds from said extractive fluids.

Inventors

  • 👤 Charles C Templeton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 16:03
CPC Classifications
E; E21; E21B; E21B43/00; E21B43/16; E21B43/24; E21B43/243; E21B43/247; E21B43/28

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 97 words
In a method of producing shale oil and soluble aluminum compounds from subterranean dawsonite-containing oil shale formations comprising the steps of: a. creating a fractured or rubblized or fragmented oil shale formation or cavity; b. flowing into the formation or a cavity pyrolytically extractive fluid; c. flowing into the formation or cavity an aqueous liquid containing a chelating agent in an amount sufficient to dissolve soluble aluminum compounds; d. outflowing the liquids produced by steps (a) and (b); e. separating the aqueous phase from the oil phase and, f. recovering an aluminum compound from the aqueous phase.
Claim 2
Dependent Claim 97 words
In a method of producing shale oil and soluble aluminum compounds from subterranean dawsonite-containing oil shale formations comprising the steps of: a. creating a fractured or rubblized or fragmented oil shale formation or cavity; b. flowing into the formation or a cavity pyrolytically extractive fluid; c. flowing into the formation or cavity an aqueous liquid containing a chelating agent in an amount sufficient to dissolve soluble aluminum compounds; d. outflowing the liquids produced by steps (a) and (b); e. separating the aqueous phase from the oil phase and, f. recovering an aluminum compound from the aqueous phase.
Claim 3
Dependent Claim 42 words
The method of claim 1 wherein the in situ combustion for oil recovery and aqueous liquid dissolution of the dawsonite is sequentially repeated and the aqueous liquid is an aqueous alkaline liquid containing a sodium salt of a alkylene polyamine polycarboxylic acid.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein the aluminum compound is recovered from dissolved dawsonite.
Claim 5
Dependent Claim 46 words
The method of claim 3 wherein the oil shale is pyrolyzed by injecting therein an in situ combustible material at an elevated temperature sufficient to effect oil extraction and the chelating agent in the aqueous fluid is an alkali metal salt of an amino carboxylic acid.
Claim 6
Dependent Claim 21 words
The method of claim 4 wherein the aqueous alkaline liquid is an aqueous alkaline solution containing tetra sodium ethylene diamine tetracetate.
Claim 7
Dependent Claim 40 words
The method of claim 4 wherein the fluid is recovered by combustion treatment is shale oil and the aqueous liquid containing a chelating agent used to dissolve the dawsonite is an aqueous alkaline liquid containing an acid insoluble chelating agent.
Claim 8
Dependent Claim 19 words
The method of claim 6 wherein the combustion mixture is maintained as a foamed mixture of air and water.

References Cited (Backward Citations)

US3502372A Cited
US3501201A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1974-03-29 1974-09-28 1975-03-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1978-03-29 1978-09-28 1979-03-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1982-03-29 1982-09-28 1983-03-30 $7700.00 Window Closed / Lapsed

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