Bituminous compositions containing methylol phenol derivatives

Claim 1

A STRIP-RESISTANT BITUMINOUS COMPOSITION CONTAINING AN ASHPALT AND A MINOR AMOUNT OF AMOUNT OF A MEMBER SELECTED FORM THE GROUP CONSISTING OF: (1) ACYLATED, (2) OXYALKYLATED, (3) ACYLATED THEN OXYALKYLATED, (4) OXYALKYLATED AND THEN ACYLATED, (5) ACYLATED, THEN OXALKYLATED AND THEN ACYLATED, MONOMERIC POLYAMINOMETHYL PHENOLS CHARACTERIZED BY REACTING A PREFORMED METHYLOL PHENOL HAVING ONE TO FOUR METHYLOL GROUP IN THE 2, 4, 6, POSITION WITH A POLYMMINE CONTAINING AT LEAST ONE SECONDARY AMINE GROUP IN AMOUNTS OF AT LEAST ONE MOLE OF SECONDARY POLYMAINE PER QUIVALENT OF METHYLOL GROUP ON THE PHENOL UNTIL ONE MOLE OF WATER PER EQUIVALENT OF METHYLOL GROUP IS REMOVED, IN THE ABSENCE OF AN EXTRANEOUS CATALYST; AND THEN REACTING THE THUS FORMED MONOMERIC POLYAMINOMETHYL PHENOL WITH A MEMBER SELECTED FROM THE GROUP CONSISTING OF (1) AN ACYLATION AGENT, (2) AN OXYALKYLATION AGENT, (3) AN ACYLATION THEN AN OXYALKYLATION AGENT, (4) AN OXYALKYLATION THEN AN ACYLATION AGENT, AND (5) AN ACYLATION THEN ON OXYALKYLATION AND THEN AN ACYLATION AGENT, THE PERFORMED METHYLOL PHENOL HAVING ONLY FUNCTIONAL GROUPS SELECTED FROM THE CLASS CONSISTING OF METHYLOL GROUPS AND PHENOLIC HYDROXYL GROUPS, THE POLYAMINE HAVING ONLY FUNCTIONAL GORUPS SELECTED FORM THE CLASS CONSISTING OF PRIMARY AMINO GROUPS, SECONDARY AMINO GROUPS AND HYDROXYL GROUPS, THE ACYLATION AGENT HAVING UP TO 40 CARBON ATOMS AND BEING SELECTED FORM THE CLASS CONSISTING OF UNSUBSTITUTED CARBOXYLIC ACIDS, UNSUBSTITUTED HYDROXY CARBOXYLIC ACIDS, UNSUBSTITUTED ACYLATED HYDROXY CARBOLIC ACIDS, LOWER ALKANOL ESTERS OF UNSUBSITUTED CARBOLYIC ACIDS, GYCERIDES OF UNSUBSTITUTED CARBOLYC ACIDS, UNSUBSTITUTED CARBOXYLIC ACID CHLORIDES AND UNSUBSTITUTED CARBOXYLIC ACID ANHYDRIDES, AND THE OXYALKYLATION AGENT BEING SELECTED FROM THE CLASS CONSISTING OF ALPHA-BETA ALKLENE OXIDES AND STYRENE OXIDE.