Reaction product of a polyhydroxy compound and a polyisocyanate in the presence of avinyl-substituted heterocyclic nitrogen base

Claim 1

AS A NEW COMPOSITION THE PRODUCT FORMED BY REACTING AN ORANIC POLYHYDROXY COMPOUND WITH AN ORGANIC POLYISOCYANATE IN THE PESENCE OF A VINYL-SUBSTITUTED HETEROCYCLIC NITROGEN BASE AND A VINYL POLYMERIZATION CATALYST, WHEREIN SAID POLYHYDROXY COMPOUND IS SELECTED FROM THE GROUP CONSISTING OF CASTOR OIL, ETHYLENE GLYCOL, 1,3-PROPYLENE GLYCOL, 1,2-PROPYLENE GLYCOL, 1,2-BUTYLENE GLYCOL, 2,3-BUTYLENE GLYCOL, 1,4-BUTYLENE GLYCOL, 2,2-DIMETKHYL-1,3-PROPANEDIOL, PENTAMETHYLKENE GLYCOL, HEXAMETHYLENE GLYCOL, 1,2-OCTYLENE GLYCOL, 4,5-OCTYLENE GLYCOL, 4,5-DECYLENE GLYCOL, DECAMETHYLENE GLYCOL, DODECAMETHYLENE GLYCOL, HEXADECAMETHYLENE JGLYCOL, POLDYETHYLENE GLYCOL, POLYPYROPYLENE GLYCOL, POLY(1,4-BUTYLENE) GLYCOL, POLY(2,3-BUTYLENE) GLYCOL, POLY(1-PHENYLETHYLENE) GLYCOL, POLY(4,5-DECAYLENE) GLYCOL, POLY(2-METHYL - 2 - ETHYL-1,5PENTYLENE)GLYCOL, ETYLENE-PROPYLENE GLYCOL, AND ESTERS OF SUCH GLYCOLS FORMED BY REACTING THE SAME WITH A CARBOXYLIC ACID SELECTED FROM THE GROUP CONSISTING OF SUCCINIC ACID, MONOMETHYL SUCCINIC ACID, GLUTARIC, ACID, ADIPIC ACID, PIMELIC ACID, SUBERIC ACID, AZELAIC ACID, SEBACIC ACID, BRAS SYLIC ACID, THAPSIC ACID, 6-OCTADECENEDFIOIC ACID, OCTADECANEDIOIC ACID, 8-OCTADECENEDIOIC ACID, EICOSANEDIOIC, ACID, 6,8-OCTADECADIENEDIOIC ACID, MALIC ACID, MALEIC ACID, FUMARIC ACID, GLUTACONIC ACID, ITACONIC ACID, CYCLOPENTANE1,2-DICARBOXYLIC ACID, CYCLOPENTANE-1,3-DICARBOXYLIC ACID, PHTHALIC ACID, ISOPHTHALIC ACID, TEREPHTHALIC ACID, NAPHTHALENE-1,2-DICARBODXYLIC ACID, NAPHTHALENE-1,3-DICARBOXYLIC ACID, NAPHTHALENE-1,4-DICARBOXYLIC ACID, NAPHTHALENE-1,5DICARBOXYLIC ACID, NAPTHALENE-1,8-DICARBOXYLIC ACID, DIPHENYL-2,2''-DICARBOXYLIC ACID, DIPHENYL-4,4''-DICARBOXYLIC ACID, DIPHENYL-2,4''-DICARBOXYLIC ACID, 2,6-DIMETHYLBENZENE-1,4-DICARBOXYLIC ACID, AND 4,5-DIMETHYL-BENZENE1,2-DICARBOXYLIC ACID, SAID POLYISOCYANATE BEING SELECTED FROM THE GROUP CONSISTING OF BENZENE-1,3-DIISOCYANATE, BENZENE - 1,4 - DIISOCYANATE, HEXAMETHYLENEDIISOCYANATE, TOLUENE-2,4-DIISOCYANATE, TOLUENE - 2,5 - DIISOCYANATE, DIPHENYLMETHANE-4,4''-DIISOCYANATE, DIPHENYL-4,4''-DIISOCYANATE, DIPHENYL-3,3''-DIMETHYL-4,4''-DIISOCYANATE, DIPHENYL3,3''-DIMETHYL - 4,4''- DIISOCYANATE, 2 - CHLOROPROPANE-1,3DIISOCYANATE, DIPHENYL - 3,3''-DIMETHOXY-4,4''-DIISOCYANATE, NAPHTHALENE-1,5-DIISOCYANATE, PENTAMETHYLENEDIISOCYANATE, TETRAMETHYLENEDIISOCYANATE, OCTAMETHYLENEDIISOCYANATE, DIMETHYLENEDIISOCYANATE, PROPYLENE-1,2-DIISOCYANATE, BENZENE - 1,2,4 - TRIISOCYANATE, TOLUENE - 2,3-DIISOCYANATE, DIPHENYL-2,2''-DIISOCYANATE, NAPHTHALENE - 2,7 - DIISOCYANATE, NAPHTHALENE-1,8-DIISOCYANATE, TOLUENE-2,4,6-TRIISOCYANATE, BENZENE-1,3,5-TRIISOCYANATE, BENZENE - 1,2,3-TRIISOCYANATE, AND TOLUENE-2,3,4-TRIISOCYANATE, SAID VINYL-SUBSTITUTED HETEROCYCLIC NITROGEN BASE BEILNG SELECTED FROM THE GROUP CONSISTING OF 2-VINYLPYRIDINE, 4-VINYLPYRIDINE, 2,4,6-TRIMETHYL - 5 - VINYLPYRIDINE, 3,4,5,6-TETRAMETHYL-2-VINYLPYRIDINE, 3-ETHYL-5-VINYLPYRIDINE, 2-VINYL - 5 - ETHYLPYRIDINE, 2-METHYL-5-VINYLPYRIDINE, 4,6 - DIMETHYL - 2-VINYLPYRIDINE, 2,6-DIETHYL -4- VINYLPYRIDINE, 2-ISOPROPYL-4-VINYLPYRIDINE 2-VINYL-5-PROPYLPYRIDING, 2-VINYL-5-BUTYLPYRIDINE, 2-VINYL 5-HEXYLPYRIDINE, 2-VINYL - 5 - HEPTYLPYRIDINE, 2-METHYLUNDECYL-6-VINYLPYRIDINE, 2,4 - DIMETHYL - 5,6 - DIPENTYL-3VINYLPYRIDINE, 2-VINYL-QUILNOLINE, 2-VINYL-8-ETHYQUINOLINE, 4-HEXYL - 5 - VINYLQUINOLINE, 4 - DODECYL-5-VINYLQUINOLINE 3,4,5,6-TETRAMETHYL-2-VINYLQUINOLINE, AND 1-VINYLSOQULINOLINE, SAID CATALYST BEING SELECTED FROM THE GROUP CONSISTING OF BENZOYL PEROXIDE, N-BUTYL PEROXIDE, LAUROYL PEROXIDE, TERTIARYBUTYL PEROXIDE, CUMENE PEROXIDE, N-PROPYL HYDROPEROXIDE, AND CUMENE HYDROPEROXIDE, WHEREIN THE TOTAL AMOUNT OF SAID POLYDROXY AND POLYISOCYANATE COMPOUNDS IS 50 TO 98 WEIGHT PERCENT WITH 0.5 TO 1.5 EQUILVALENTS OF SAID POLYHYDROXY COMPOUND BEING USED PEREQUIVALENT OF SAID POLYISOCYANATE COMPOUND, SAIND VINYLSUBSTITUTED HETEROCYCLIC NITROGEN BASE BEING USED IN THE AMOUNT OF 1 TO 50 WEIGHT PERCENT, AND SAID CATALYST BEING USED IN THE AMOUNT OF 0.01 TO 10 WEIGHT PERCENT, SAID WEIGHT PERCENTS BEING BASED ON THE TOTAL WEIGHT OF THE REACTION MIXTURE.