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EP1219650A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Star polymer colloidal stabilizers

Assignee: National Starch and Chemical Investment Holding Corp
•
Filing: 2001-12-11
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Granted: —
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Expires: 2021-12-11
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Abstract

Abstract A colloid composition is presented which contains an amphiphilic star polymer having potentially crosslinkable sites on the polymer backbone. The potentially crosslinkable site is either a sterically hindered silane monomer or an acetoacetoxy-containing monomer. When the crosslinkable site is a sterically hindered silane monomer the star polymer also contains an internal catalyst, and when the crosslinkable site is an acetoacetoxy group the colliod composition also contains a non-polymeric polyfunctional amine. The star polymer can be either a random or heteroarm star polymer. The colloid composition is useful in the formation and stabilization of emulsion polymers, as a replacement for surfactants currently used for this purpose. Emulsion polymers formulated with the colloid composition are especially useful for one-part coatings such as paints and adhesives.

Inventors

  • 👤 Lien Phan
  • 👤 Apala Mukherjee
  • 👤 Rajeev Farwaha
  • 👤 John S. Thomaides

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 08:54
CPC Classifications
C; C09; C09J; C09J153/00; C08; C08F; C08F2/00; C08F2/12; C08F2/16; C08F2/22; C08F2/24; C08F293/00; C08F293/005; C08F297/00; C08F297/02; C08F297/026; C08L; C08L53/00; C09D; C09D153/00

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 78 words
A colloid composition comprising an amphiphilic star polymer having at least one potentially crosslinkable site on the polymer backbone, wherein the potentially crosslinkable site is selected from the group consisting of a sterically hindered silane monomer and an acetoacetoxy-containing monomer, wherein when the crosslinkable site is a sterically hindered silane monomer the star polymer also contains an internal catalyst, and wherein when the crosslinkable site is an acetoacetoxy group the colloid composition also contains a non-polymeric polyfunctional amine.
Claim 2
Dependent Claim 16 words
The colloid composition of claim 1 wherein said amphiphilic star polymer is a heteroarm star polymer.
Claim 3
Dependent Claim 16 words
The colloid composition of claim 1 wherein said amphiphilic star polymer is a random star polymer.
Claim 4
Dependent Claim 34 words
The colloid composition of claim 1 wherein said star polymer has a molecular weight in the range of from 10,000 to 100,000, preferably from 15,000 to 75,000, and most preferably from 30,000 to 50,000.
Claim 5
Dependent Claim 25 words
The colloid composition according to Claim 2 wherein the star polymer has at least one arm with a T g of at least about 20°C.
Claim 6
Dependent Claim 16 words
The colloid composition according to Claim 1 wherein the sterically hindered silane monomer is vinyltriisopropoxy silane
Claim 7
Dependent Claim 15 words
The colloid composition of claim 1 comprising 1 to 20 pphm sterically hindered silane monomer.
Claim 8
Dependent Claim 16 words
The colloid composition of claim 1 wherein said internal catalyst is an ethylenically unsaturated carboxy-functional monomer.
Claim 9
Dependent Claim 15 words
The colloid composition of claim 1 comprising 0.1 to 10 pphm of said internal catalyst
Claim 10
Dependent Claim 32 words
The colloid composition of claim 1 wherein said acetoacetoxy containing monomer is selected from the group consisting of acetoacetoxyethyl methacrylate, acetoacetoxybutyl methacrylate, acrylamidomethylacetylacetone, vinyl acetoacetate, allyl acetoacetate, vinyl acetoacetate, and mixtures thereof.
Claim 11
Dependent Claim 14 words
An emulsion composition comprising the colloid composition of claim 1 and an emulsion polymer.
Claim 12
Dependent Claim 15 words
The emulsion composition of claim 11 comprising 5 to 20 pphm of said colloid composition.
Claim 13
Dependent Claim 25 words
The emulsion composition of claim 11 wherein said emulsion polymer comprises a polymer formed from at least one ethylenically unsaturated monomer having a reactive moiety.
Claim 14
Dependent Claim 20 words
The emulsion composition of claim 13 wherein said monomer comprises an acrylic monomer, a vinyl monomer, or a mixture thereof.
Claim 15
Dependent Claim 8 words
The emulsion composition of claim 11 being surfactant-free.
Claim 16
Dependent Claim 24 words
The emulsion composition of claim 11 further comprising a wet adhesion monomer as a part of either the star polymer or the emulsion polymer.
Claim 17
Dependent Claim 11 words
A one-part coating composition comprising the emulsion composition of claim 11.

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