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EP0977469A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Improved transparent, flexible permeability barrier for organic electroluminescent devices

Assignee: Agilent Technologies Inc
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Filing: 1999-07-30
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Granted: —
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Expires: 2019-07-30
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Abstract

Abstract A barrier for preventing water or oxygen from a source thereof from reaching a device that is sensitive to water or oxygen. The barrier is constructed by depositing a first polymer layer[191] between the device and the source. An inorganic layer[192] is deposited on the first polymer layer[191] the device by plasma enhanced chemical vapor deposition utilizing an electron cyclotron resonance source ECR-PECVD. A second polymer layer[193] is then deposited on the inorganic layer[192]. The inorganic layer[192] is preferably an oxide or nitride. A second barrier layer[201] having a compound that absorbs oxygen or water can be placed between the inorganic layer[192] and the device to further retard the passage of oxygen or water. The present invention is particularly useful in encapsulating electroluminescent displays[100, 203].

Inventors

  • 👤 James R. Sheats
  • 👤 Mark R. Hueschen
  • 👤 Karen L. Seaward
  • 👤 Daniel B. Roitman

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 02:13
CPC Classifications
H; H05; H05B; H05B33/00; H05B33/02; H05B33/04; H10; H10K; H10K50/00; H10K50/80; H10K50/84; H10K50/844; H10K50/8445; H10K50/846; H10K59/00; H10K59/80; H10K59/87; H10K59/873; H10K59/874

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 63 words
A method for preventing water or oxygen from a source thereof reaching a device (100,203), said method comprising the steps of: depositing a first polymer layer (191) between said device (100, 203) and said source; depositing an inorganic layer (192) on said first polymer layer (191) of said device by ECR-PECVD; and depositing a second polymer layer (193) on said inorganic layer (192).
Claim 2
Dependent Claim 26 words
The method of Claim 1 wherein said inorganic layer (192) comprises a material selected from the group consisting of: an oxide; a nitride; and an oxynitride.
Claim 3
Dependent Claim 35 words
The method of Claim 2 wherein said inorganic layer (192) comprises a material selected from the group consisting of: an aluminum oxide; a silicon oxide; an aluminum nitride; a silicon nitride; and a silicon oxynitride.
Claim 4
Independent Claim 34 words
The method of one of the preceding claims further comprising the step of depositing a layer (201) of material that absorbs oxygen or water between said inorganic layer (192) and said device (100, 203).
Claim 5
Dependent Claim 19 words
The method of Claim 4 wherein said absorbing material comprises a metal uniformly dispersed in an oxide or nitride.
Claim 6
Independent Claim 22 words
The method of one of the preceding claims wherein said inorganic layer (192) further comprises a material that absorbs oxygen or water.
Claim 7
Dependent Claim 12 words
The method of Claim 6 wherein said absorption material comprises a metal.
Claim 8
Dependent Claim 191 words
An electroluminescent device (100, 203) comprising: a flexible sheet (161), said flexible sheet (161) being transparent to light of a first wavelength; a first polymer layer (191) in contact with said flexible sheet (161); a first permeation barrier comprising an inorganic layer (192) in contact with said first polymer layer (191); a second polymer layer (193) in contact with said first permeation barrier; a first electrode (117) comprising a first electrode layer in contact wit said flexible sheet (161), said first electrode layer being transparent to light of said first wavelength; a light emitting layer (118) comprising an organic material in electrical contact with said first electrode layer; a second electrode (131-132) comprising a second electrode layer in electrical contact with said light emitting layer (118), said light emitting layer generating light of said first wavelength when a potential difference is applied across said first and second electrodes; a third polymer layer (181) in contact with said second electrode layer; a second permeation barrier (182) comprising a layer of inorganic material in contact with said third polymer layer; and a fourth polymer (183) layer in contact with said second permeation barrier.
Claim 9
Dependent Claim 19 words
The device (100, 203) of Claim 8 wherein said first and second permeation barriers comprises layers deposited by ECR-PECVD.
Claim 10
Dependent Claim 43 words
The device (100, 203) of Claim 8 or 9 wherein said first permeation barrier comprises a material selected from the group consisting of: an oxide and a nitride, in particular an aluminum oxide, a silicon oxide, an aluminum nitride and a silicon nitride.
Claim 11
Dependent Claim 26 words
The device (100, 203) of Claim 8, 9 or 10 wherein said first and second permeation barriers further comprise a material that absorbs oxygen or water.
Claim 12
Independent Claim 44 words
The device (100, 203) of one of claims 8 to 11 further comprising: a first absorption barrier (201) comprising a layer of material that absorbs oxygen or water, said first absorption barrier being located between said first electrode layer and said first permeation barrier.
Claim 13
Dependent Claim 39 words
The device (100, 203) of Claim 19 further comprising: a second absorption barrier comprising a layer of material that absorbs oxygen or water, said second absorption barrier being located between said second electrode layer and said second permeation barrier.

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