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EP0957522A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Semiconductor memory device and method for fabricating the same

Assignee: Panasonic Holdings Corp
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Filing: 1999-05-12
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Granted: —
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Expires: 2019-05-12
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Abstract

Abstract A low-leakage-current layer, made of BST in which the content of Ti deviates from its stoichiometric composition, is interposed between a high-dielectric-constant layer, made of BST with the stoichiometric composition, and an upper electrode. And a charge-storable dielectric film is made up of the high-dielectric-constant layer and the low-leakage-current layer. Such a BST film containing a larger number of Ti atoms than that defined by stoichiometry can suppress the leakage current to a larger degree. Also, if such a film is used, then the relative dielectric constant does not decrease so much as a BST film with the stoichiometric composition. Accordingly, the leakage current can be suppressed while minimizing the decrease in relative dielectric constant of the entire charge-storable dielectric film, which is a serial connection of capacitors, thus contributing to the downsizing of a semiconductor memory device. As a result, a semiconductor memory device, including a charge-storable dielectric film with decreased leakage current and enhanced charge storability, can be obtained.

Inventors

  • 👤 Michihito Ueda
  • 👤 Takashi Ohtsuka

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-27 16:00
CPC Classifications
H; H10; H10B; H10B12/00; H10D; H10D1/00; H10D1/60; H10D1/68; H10D1/682; H10D1/684

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 121 words
A semiconductor memory device comprising a plurality of cells, each said cell including: a lower electrode; a charge-storable dielectric film, formed on the lower electrode and made of a dielectric in which information is storable; and an upper electrode formed on the charge-storable dielectric film, wherein the charge-storable dielectric film includes: a first dielectric layer made of an oxide containing at least two metal elements and a dielectric with a high relative dielectric constant or a ferroelectric; and a second dielectric layer, which is formed over and/or under the first dielectric layer and made of an oxide containing at least two metal elements and through which a smaller amount of leakage current flows than that flowing through the first dielectric layer.
Claim 2
Dependent Claim 30 words
The device of Claim 1, wherein the first dielectric layer has an approximately stoichiometric composition, and wherein the second dielectric layer has a composition deviated from the stoichiometric composition thereof.
Claim 3
Dependent Claim 19 words
The device of Claim 1, wherein the first dielectric layer contains the three elements of Ba, Sr and Ti.
Claim 4
Dependent Claim 24 words
The device of Claim 3, wherein the first dielectric layer has a composition expressed by Ba x Sr 1-x TiO 3 , where 0≦x≦1.
Claim 5
Dependent Claim 19 words
The device of Claim 1, wherein the second dielectric layer contains the three elements of Ba, Sr and Ti.
Claim 6
Dependent Claim 38 words
The device of Claim 5, wherein the number of Ti atoms accounts for larger than 50% and equal to or smaller than 60% of the total number of Ba, Sr and Ti atoms in the second dielectric layer.
Claim 7
Dependent Claim 86 words
The device of Claim 2, wherein the first and second dielectric layers of the charge-storable dielectric film both contain the three elements of Ba, Sr and Ti, and wherein the first and second dielectric layers are formed such that a ratio of the number of Ti atoms to the total number of Ba, Sr and Ti atoms in the charge-storable dielectric film is represented as a continuous function of a distance as measured from the lower surface of the charge-storable dielectric film in the thickness direction.
Claim 8
Dependent Claim 49 words
The device of Claim 7, wherein the ratio of the number of Ti atoms to the total number of Ba, Sr and Ti atoms is 50% in part of the charge-storable dielectric film that corresponds to at least one half of the total thickness of the charge-storable dielectric film.
Claim 9
Independent Claim 155 words
A method for fabricating a semiconductor memory device, comprising the steps of: a) forming a lower electrode over a substrate; b) forming a charge-storable dielectric film on the lower electrode, the charge-storable dielectric film being made of a dielectric in which information is storable; and C) forming an upper electrode on the charge-storable dielectric film, wherein the step b) includes: i) forming a first dielectric layer made of an oxide containing at least two metal elements and a dielectric with a high relative dielectric constant or a ferroelectric; and ii) forming a second dielectric layer over and/or under the first dielectric layer, the second dielectric layer being made of an oxide containing the same elements as those of the first dielectric layer but having a different composition than that of the first dielectric layer, the amount of leakage current flowing through the second dielectric layer being smaller than that flowing through the first dielectric layer.
Claim 10
Dependent Claim 85 words
The method of Claim 9, wherein in the step i), the first dielectric layer is formed to contain the three elements of Ba, Sr and Ti substantially at a stoichiometric composition, and wherein in the step ii), the second dielectric layer is formed to contain the three elements of Ba, Sr and Ti at such a composition that the number of Ti atoms accounts for larger than 50% and equal to or smaller than 60% of the total number of Ba, Sr and Ti atoms.
Claim 11
Dependent Claim 29 words
The method of Claim 9 or 10, wherein a heat treatment is conducted to heat the substrate at 650°C or more before the steps i) and ii) are performed.
Claim 12
Dependent Claim 53 words
The method of Claim 10, wherein in the step b), while the first and second dielectric layers are formed by a metalorganic chemical vapor deposition process, the temperature of the substrate is changed, thereby changing the ratio of the number of Ti atoms to the total number of Ba, Sr and Ti atoms.
Claim 13
Dependent Claim 28 words
The method of Claim 12, wherein in the step b), the temperature of the substrate is kept constant in the step i), but changed in the step ii).

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