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EP0878843A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method of sputtering copper to fill trenches and vias

Assignee: Applied Materials Inc
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Filing: 1998-05-08
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Granted: —
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Expires: 2018-05-08
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Abstract

Abstract The present disclosure pertains to a method of filling features (typically trenches or vias) on a semiconductor workpiece surface with copper using sputtering techniques previously believed incapable of achieving a copper fill. In particular, when the feature is to be filled with a single, continuous application of sputtered copper, the surface of the substrate to which the sputtered copper is applied should range between about 200 °C and about 600 °C; preferably the surface temperature of the substrate ranges between about 300 °C and about 500 °C. When the feature (411) is to be filled using a thin wetting layer (416) of copper, followed by a fill layer of copper, the wetting layer (416) may be applied by sputtering techniques or by other methods such as evaporation or CVD, while the fill layer of copper is applied using sputtering techniques. The thin wetting layer (416) of copper is applied at a substrate surface temperature ranging between about 20 °C to about 250 °C, and subsequently the temperature of the substrate (410) is increased, with the application of the sputtered copper fill layer beginning at above at least about 200 °C and continuing while the substrate temperature is increased to a temperature as high as about 600 °C. Preferably the substrate temperature during application of the sputtered fill layer ranges between about 300 °C and about 500 °C.

Inventors

  • 👤 Peijun Ding
  • 👤 Tony Chiang
  • 👤 Barry L. Chin

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 06:58
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056; H10P; H10P14/00; H10P14/40; H10P14/42; H10P14/44

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 73 words
A method of providing a complete copper fill of a trench or via or other feature upon a surface of a semiconductor workpiece, said method comprising the steps of: a) adjusting said substrate surface temperature within a range from about 20 °C to about 600 °C; and b) while said substrate surface is adjusted within such temperature range, applying at least one layer of copper to said substrate surface using a sputtering technique.
Claim 2
Dependent Claim 28 words
The method of Claim 1, wherein said at least one layer of copper is applied with said substrate temperature ranging between about 200 °C and about 600 °C.
Claim 3
Dependent Claim 28 words
The method of Claim 2, wherein said at least one layer of copper is applied with said substrate temperature ranging between about 300 °C and about 500 °C.
Claim 4
Dependent Claim 43 words
The method of Claim 1, or Claim 2, or Claim 3, wherein said at least one layer of copper is applied using a sputtering technique selected from the group consisting of Gamma-sputtering, Coherent sputtering, IMP, and traditional, standard sputtering, or a combination thereof.
Claim 5
Dependent Claim 66 words
The method of Claim 1, wherein a first layer of copper is applied to wet and bond to said substrate surface while said substrate surface is at a temperature ranging from about 20 °C to about 250 °C, followed by application of a second layer of copper to said substrate while said substrate is at a temperature ranging between about 200 °C and about 600 °C.
Claim 6
Dependent Claim 26 words
The method of Claim 5, wherein said second layer of copper is applied with said substrate temperature ranging between about 250 °C and about 600 °C.
Claim 7
Dependent Claim 26 words
The method of Claim 6, wherein said second layer of copper is applied with said substrate temperature ranging between about 300 °C and about 500 °C.
Claim 8
Dependent Claim 43 words
The method of Claim 5, or Claim 6, or Claim 7, wherein said first layer of copper is applied using a technique selected from the group consisting of CVD, Evaporation, Gamma sputtering, Coherent sputtering, IMP, and traditional standard sputtering, or a combination thereof.
Claim 9
Dependent Claim 35 words
The method of Claim 8, wherein said second layer of copper is applied using a technique selected from the group consisting of Gamma sputtering, Coherent sputtering, IMP and traditional, standard sputtering, or a combination thereof.
Claim 10
Dependent Claim 56 words
The method of Claim 5, wherein, subsequent to application of said first layer of copper, the temperature of said substrate surface is adjusted downward to a temperature of 200 °C or less and then adjusted upward to said temperature ranging between about 200 °C and about 600 °C during application of said second layer of copper.
Claim 11
Dependent Claim 17 words
The method of Claim 1 applied to a substrate surface having at least one barrier layer thereon.
Claim 12
Dependent Claim 37 words
The method of Claim 11, wherein said at least one barrier layer is selected from the group consisting of tantalum, tantalum nitride, tantalum-silicon nitride, titanium nitride, titanium-silicon nitride, tungsten nitride, and tungsten-silicon nitride or a combination thereof.
Claim 13
Dependent Claim 15 words
The method of Claim 11, wherein at least one wetting layer overlays said barrier layer.
Claim 14
Dependent Claim 23 words
The method of Claim 13, wherein said at least one wetting layer is comprised of aluminum, titanium, or copper, or a combination thereof.
Claim 15
Dependent Claim 15 words
The method of Claim 5 applied to a substrate surface having a barrier layer thereon.
Claim 16
Dependent Claim 30 words
The method of Claim 15, wherein said barrier layer is selected from the group consisting of tantalum, tantalum nitride, tantalum-silicon nitride, titanium nitride, titanium-silicon nitride, tungsten nitride, and tungsten-silicon nitride.
Claim 17
Dependent Claim 13 words
The method of Claim 5, wherein a wetting layer overlays said barrier layer.
Claim 18
Dependent Claim 21 words
The method of Claim 17, wherein said wetting layer is comprised of aluminum, or titanium, or copper or a combination thereof.

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