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EP0839883A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Counterion substitution in macromolecular chromophores for ink-jet printing

Assignee: HP Inc
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Filing: 1997-10-15
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Granted: —
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Expires: 2017-10-15
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Abstract

Abstract The ink of the invention comprises a vehicle and a colorant. The colorant is a water-insoluble macromolecule that has been chemically modified to be water soluble by addition of functional groups to the surface of the chromaphores resulting in water soluble colorant particles. The resulting chromaphore is called a macromolecular chromaphore (MMC). The performance of these MMCs is improved by substitution of (a) the normal counter-cations with substituted ammonium cations or (b) the normal counter-anions with any of a variety of organic and inorganic anions. The inks described herein demonstrate high edge acuity, high optical density, fast drying times, high waterfastness, and high smearfastness.

Inventors

  • 👤 Joseph W. Tsang
  • 👤 John R. Moffatt

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-24 07:44
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; B; B41; B41J; B41J2/00; B41J2/005; B41J2/01

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 43 words
An ink-jet ink for ink-jet printing which comprises: (a) a vehicle, and (b) at least one water-soluble ionic colorant and a corresponding counterion, wherein said ionic colorant is selected from the group consisting of anionic functionalized colorant particles and cationic functionalized colorant particles.
Claim 2
Dependent Claim 33 words
The ink-jet ink of Claim 1, wherein said ionic colorant comprises a colorant particle which has anions on the surface, wherein said anions are selected from the group consisting of sulfonate or carboxylate.
Claim 3
Dependent Claim 66 words
The ink-jet ink of Claim 2, wherein said corresponding counterion is a cation selected from the group consisting of N,N',N"-substituted ammonium ions, N,N',N"-unsubstituted ammonium ions, N,N',N",N"'-substituted amides of 1,w-amino acids, N,N',N",N"'-unsubstituted amides of 1,w-amino acids, N,N'-substituted lactams of 1,w-amino acids, N,N'-unsubstituted lactams of 1,w-amino acids, N,N',N"-substituted esters of 1,w-amino acids, N,N',N"-unsubstituted esters of 1,w-amino acids, N,N'-substituted lactones of 1,w-amino acids, and N,N'-unsubstituted lactones of 1,w-amino acids.
Claim 4
Dependent Claim 24 words
The ink-jet ink of Claim 3, wherein said corresponding counterion is selected from the group consisting of dimethyl ammonium, trimethyl ammonium, and dipropyl ammonium.
Claim 5
Dependent Claim 26 words
The ink-jet ink of Claim 1, wherein said ionic colorant is a colorant particle which has cations on the surface, wherein said cations are ammonium ions.
Claim 6
Dependent Claim 55 words
The ink-jet ink of Claim 1, wherein said ionic colorant comprises cationic functionalized colorant particles and said corresponding counterion is an anion selected from the group consisting of halide, sulfate, nitrate, phosphate, sulfonate, carboxylate, carbonate, bicarbonate, borate, tetraborate, tetrafluoroborate, methane sulfonate, methyl benzene sulfonate, phosphite, phosphonate, hexaflurophosphonate, phosphene, phenolate, perchlorate, tungstate, molybdate, and silicate ions.
Claim 7
Dependent Claim 16 words
A method of ink-jet printing comprising printing on a medium with said ink of Claim 1.
Claim 8
Dependent Claim 63 words
A method for preparing said ink-jet ink of Claim 1 for ink-jet printing comprising: (a) providing colorant particles; (b) functionalizing said colorant particles to form a macromolecular chromaphore having either anionic functionalities or cationic functionalities; (c) adding a compatible counterion to said macromolecular chromaphore using ion exchange techniques; (d) mixing said macromolecular chromaphore and associated counterion with said vehicle to form said ink.

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