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EP0837502A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Improvements in or relating to hydrogen gettering

Assignee: Texas Instruments Inc
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Filing: 1997-10-15
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Granted: —
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Expires: 2017-10-15
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Abstract

Abstract A method, system and materials for use in hydrogen gettering in conjunction with microelectronic and microwave components that are generally hermetically sealed in an enclosure typically referred to as a "package"- Gettering materials that can be used include titanium with or without a hydrogen permeable coating or covering, alloys of zirconium-vanadium iron and zeolites and several ways to apply these materials to the package. In addition, the hydrogen permeable material can be used over a vent from the interior of the package to the exterior wherein hydrogen will escape from the package interior when the hydrogen concentration within the package is greater than without the package.

Inventors

  • 👤 John M. Bedinger
  • 👤 Clyde R. Fuller

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 01:11
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/0005; C01B3/001; C01B3/0018; C01B3/0026; H; H10; H10P; H10P95/00; H10P95/40; H10P95/408; C01B3/0031; C01B3/50; C01B3/501; H10W; H10W76/00; H10W76/40; H10W76/42; H10W76/48; C01B2203/00; C01B2203/04; C01B2203/0405; C01B2203/0465; C01B2203/0495; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/32; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12431; Y10T428/12438; Y10T428/13; Y10T428/131

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 34 words
A device which comprises: a material which is degradable in the presence of hydrogen; a package containing said material; and a layer of a hydrogen getter containing a transition metal disposted within said package.
Claim 2
Dependent Claim 23 words
The device of Claim 1, wherein said transition metal is taken from the group consisting of palladium, platinum and nickel and oxides thereof.
Claim 3
Dependent Claim 17 words
The device of Claim 1 or Claim 2, wherein said material comprises a group III-V semiconductor composition.
Claim 4
Dependent Claim 14 words
The device of Claim 1 or Claim 2, wherein said material comprises gallium arsenide.
Claim 5
Independent Claim 24 words
The device of any preceding claim, wherein said package is a hermetic sealing package hermetically sealing said material and said getter within said package.
Claim 6
Independent Claim 15 words
The device of any preceding claim, wherein said hydrogen getter comprises a elemental transition metal.
Claim 7
Independent Claim 53 words
The device of any of Claims 1 to 5 wherein said package comprises an elemental titanium-containing package having a substantially oxide-free interior surface arranged for housing said material therein, said getter comprising a layer of hydrogen permeable palladium disposed on said oxide-free surface between an inner surface of said package and said material.
Claim 8
Independent Claim 54 words
A method of making a package containing a substantially hydrogen-free interior which comprises the steps of: providing a package having a hollow interior region; and forming a layer of a hydrogen getter taken from the class consisting of elemental titanium, alloys of vanadium, zirconium and iron having hydrogen gettering properties within said interior region.
Claim 9
Dependent Claim 35 words
The method of Claim 8, wherein said step of forming said layer comprises forming an elemental titanium and said method, further comprises the step of forming a hydrogen-permeable layer of palladium over said elemental titanium.
Claim 10
Dependent Claim 22 words
The method of Claim 8 or Claim 9 further comprising the step of disposing a hydrogen degradable material within said hollow interior.
Claim 11
Dependent Claim 23 words
The method of Claim 10 wherein said step of disposing said material comprises disposing a material formed from a group III-V semiconductor compound.
Claim 12
Dependent Claim 22 words
The method of Claim 10 or Claim 11 where said step of disposing said material comprises disposing a material comprising gallium arsenide.
Claim 13
Independent Claim 18 words
The method of any of Claims 10 to 12, further comprising hermetically sealing said material within said package.
Claim 14
Independent Claim 56 words
The method of any of Claims 8 to 13 further comprising forming said layer of hydrogen getter from a mixture of powders of a hydrogen gettering material in an organic vehicle taken from the class consisting of polymeric materials including epoxies, silicones, acrylics, urethanes, polyimides and benzocyclobutene and depositing said mixture within said hollow interior region.
Claim 15
Dependent Claim 23 words
The method of Claim 14, further comprising depositing said mixture by one of screen printing and a numerically controlled placement and dispensing pump.
Claim 16
Independent Claim 37 words
The method of any of Claims 8 to 15 further comprising forming a vent through said package from said hollow interior region to the exterior of said package and forming a hydrogen permeable layer over said vent.
Claim 17
Independent Claim 24 words
The method of any of Claims 8 to 16, wherein said step of forming said hydrogen permeable layer comprises forming a layer of palladium.
Claim 18
Independent Claim 36 words
The method of any of claims 8 to 17 further comprising the step of placing said package in an environment where the concentration of hydrogen is less than the concentration of hydrogen in said hollow region.
Claim 19
Independent Claim 53 words
A method providing hydrogen gettering properties to a device which method comprising: providing a hydrogen getter material in one of powder or particulate form; mixing said getter material with a binder capable of attaching said getter material to a predetermined surface; and adhering the mixture of getter material and binder to said surface.
Claim 20
Dependent Claim 26 words
The method of Claim 19, wherein said step of adhering comprises the steps of screen printing said mixture onto a surface and then curing said mixture.
Claim 21
Dependent Claim 24 words
The method of Claim 19 or Claim 20 further comprising the step of mixing an RF absorber material with said getter material and binder.

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