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EP0821409A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Collar etch method for DRAM cell

Assignee: International Business Machines Corp
•
Filing: 1997-07-15
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Granted: —
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Expires: 2017-07-15
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Abstract

Abstract In the manufacture of 16 Mbits DRAM chips, a polysilicon strap is used to provide an electrical contact between the drain region of the active NFET device and one electrode of the storage capacitor for each memory cell. In a conventional fabrication process, a Si3N4 pad layer (26) is deposited onto the bare silicon substrate (11) then patterned. Next, deep trenches (17) are formed in the substrate by dry etching. A classic ONO layer (19) is conformally deposited into the trenches. The trenches are filled with undoped polysilicon (18). About 2,5 um of undoped polysilicon are removed from the trench in a plasma etcher. A TEOS SiO2 collar layer (20) is conformally deposited then anisotropically dry etched to leave only the so-called collar. Because trenches are present at the substrate surface, its thickness is not uniform. It is proposed hereunder a novel highly selective dry etch method to anisotropically etch said layer while preserving the Si3N4 pad layer thickness uniformity. According to the present invention, a chemistry having a high TEOS SiO2/Si3N4 selectivity (i.e. which etches TEOS SiO2 faster than Si3N4 by a factor of at least six) is used to etch the TEOS SiO2 collar layer. C4F8/Ar and C4F8/Ar/CO mixtures which have respective selectivities approximately equal to 9:1 and 15:1 (depending on gas ratios) are adequate in all respects. When the surface of the Si3N4 pad layer is reached (this can be accurately detected), the etch is continued by an overetch of the TEOS SiO2 layer to ensure a complete removal of the horizontal portions thereof.

Inventors

  • 👤 Philippe Coronel
  • 👤 Renzo Maccagnan

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 06:25
CPC Classifications
H; H10; H10B; H10B12/00; H10B12/01; H10B12/02; H10B12/03; H10B12/038

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 118 words
An improved dry etch method for etching a TEOS SiO2 layer (20) having a non-uniform thickness that is conformally formed onto a semiconductor structure (10) consisting of a silicon substrate (11) coated by a patterned Si3N4 pad layer (26) exposing trenches (17) formed in the substrate; said method comprising the steps of: a) anisotropically dry etching the structure with a highly selective TEOS SiO2/Si3N4 chemistry that etches TEOS SiO2 at least six times faster than Si3N4; b) detecting the instant the underlying Si3N4 pad layer is reached; and c) continuing said dry etching for a determined period of time to completely remove the TEOS SiO2 material atop the Si3N4 pad layer and at the bottom of the trench.
Claim 2
Dependent Claim 15 words
The method of claim 1 wherein said highly selective chemistry consists of a C4F8/Ar mixture.
Claim 3
Dependent Claim 59 words
The method of claim 2 wherein the dry etching of steps a) and c) is conducted in the reaction chamber of a plasma etcher tool with the following operating conditions: Ar 150 sccm C4F8 5 sccm Pressure 20 Pa (150 mTorr) Mag field 50 Gauss RF Power 900 watt Endpoint detect. Yes Sel. SiO2/Si3N4 9/1 (blanket) Uniformity < 4%
Claim 4
Dependent Claim 15 words
The method of claim 1 wherein said highly selective chemistry consists of a C4F8/Ar/CO mixture.
Claim 5
Dependent Claim 62 words
The method of claim 4 wherein the dry etching of steps a) and c) is conducted in the reaction chamber of a plasma etcher tool with the following operating conditions: Ar 90 sccm C4F8 4 sccm CO 15 sccm Pressure 7 Pa (50 mTorr) Mag field 17 Gauss RF Power 800 watt Endpoint detect. Yes Sel. SiO2/Si3N4 15/1 (blanket) Uniformity < 4%
Claim 6
Dependent Claim 141 words
The method of claim 1 wherein the dry etching of step a) is conducted in the reaction chamber of a plasma etcher tool with the following operating conditions: CHF3 100 sccm He/O2 20 sccm Pressure 9 Pa (70 mTorr) Mag. field 0 Gauss RF Power 470 watt Endpoint detect. Yes and the the dry etching of step c) is conducted in the same reaction chamber of the plasma etcher tool but with either one of the following operating conditions: Ar 150 sccm C4F8 5 sccm Pressure 20 Pa (150 mTorr) Mag field 50 Gauss RF Power 900 watt Endpoint detect. Yes Sel. SiO2/Si3N4 9/1 (blanket) Uniformity < 4% or Ar 90 sccm C4F8 4 sccm CO 15 sccm Pressure 7 Pa (50 mTorr) Mag field 17 Gauss RF Power 800 watt Endpoint detect. Yes Sel. SiO2/Si3N4 15/1 (blanket) Uniformity < 4%
Claim 7
Independent Claim 19 words
The method of any above claim wherein said Si3N4 pad layer top surface is detected by an interferometric technique.

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