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EP0752619A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Improved dye imbibition printing blanks and matrix films

Assignee: Eastman Kodak Co
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Filing: 1996-06-04
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Granted: —
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Expires: 2016-06-04
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Abstract

Abstract Dye imbibition printing blanks are disclosed comprising a support bearing on one side thereof a dye-receiving layer comprising a cationic mordant, and further comprising an antistat layer substantially free of cationic polymers. The antistatic layer is preferably provided on the opposite side of the support relative to the dye-receiving layer. Such antistatic layer provides improved antistatic properties which enable high manufacturing and processing speeds without adversely affecting printed image qualities. In a preferred embodiment, the dye receiving layer comprises a cationic mordant, a hydrophilic colloid and a plasticizer polymer, wherein the plasticizer polymer is a latex polymer having a glass transition temperature below about 30°C comprising from about 2 to 20 wt% of units having a quaternary ammonium group. Use of such latexes provide dye imbibition printing blanks substantially free of haze and brittleness. A process for exposing dye imbibition printing matrix films is also disclosed comprising imagewise exposing a matrix film comprising a visible light sensitive silver halide emulsion containing colloid layer on a support to blue, green or red light, wherein the visible light sensitive emulsion is also sensitive to UV light and the toe contrast of the imaged matrix film is controlled by (i) incorporating a UV absorber in the colloid layer of the matrix film, and (ii) flash exposing the matrix film with UV light in the substantial absence of light having a wavelength above 410 nm, wherein the UV absorber provides sufficiently low absorption above 410 nm such that it does not substantially alter the effective photographic speed of the matrix film during the imagewise exposure or the mid scale contrast of the imaged matrix film, and sufficiently high absorption to the UV light to decrease the resulting toe contrast of the imaged matrix film.

Inventors

  • 👤 Wayne Arthur C/O Eastman Kodak Co. Bowman
  • 👤 Charles Peter c/o Eastman Kodak Co. Hagmaier
  • 👤 Frank Dean c/o Eastman Kodak Co. Manioci
  • 👤 Mitchell Joseph c/o Eastman Kodak Co Bogdanowicz
  • 👤 Roger Wayne c/o Eastman Kodak Co Nelson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-25 01:26
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/22; G03C7/25

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 34 words
A dye imbibition printing blank comprising a support bearing on one side thereof a dye-receiving layer comprising a cationic mordant, wherein the printing blank further comprises an antistatic layer substantially free of cationic polymers.
Claim 2
Dependent Claim 25 words
A printing blank according to claim 1, wherein the antistatic layer is provided on the opposite side of the support relative to the dye-receiving layer.
Claim 3
Dependent Claim 27 words
A printing blank according to claim 1 or claim 2 wherein the antistatic layer comprises an anionic polymer, electronic conducting non-ionic polymer, metal halide or metal oxide.
Claim 4
Dependent Claim 22 words
A printing blank according to any one of claims 1-3 wherein the antistatic layer comprises a metal oxide and a polymer binder.
Claim 5
Dependent Claim 18 words
A printing blank according to claim 4, further comprising a protective polymeric overcoat layer on the antistatic layer.
Claim 6
Dependent Claim 21 words
A printing blank according to any one of claims 1-5, wherein the cationic mordant is a quaternary ammonium or phosphonium mordant.
Claim 7
Dependent Claim 85 words
A printing blank according to claim 6, wherein the cationic mordant is of the formula: wherein A' represents units of an addition polymerizable monomer containing at least two ethylenically unsaturated groups; B' represents units of a copolymerizable α,β-ethylenically unsaturated monomer; Q is N or P; R', R", and R"' are independently carbocyclic or alkyl groups; M - is an anion; a is from 0.25 to 10 mole percent; b is from 0 to 60 mole percent; and c is from 40 to 99 mole percent.
Claim 8
Dependent Claim 53 words
A printing blank according to any one of claims 1-7, wherein the dye receiving layer further comprises a hydrophillic colloid and a plasticizer polymer, wherein the plasticizer polymer is a latex polymer having a glass transition temperature below 30°C comprising from 2 to 20 weight percent of units having a quaternary ammonium group.
Claim 9
Dependent Claim 51 words
A dye imbibition printing blank comprising a support bearing a dye-receiving layer comprising a cationic mordant, a hydrophillic colloid, and a plasticizer polymer, wherein the plasticizer polymer is a latex polymer having a glass transition temperature below 30°C comprising from 2 to 20 wt% of units having a quaternary ammonium group.
Claim 10
Dependent Claim 42 words
A printing blank according to claim 8 or claim 9, wherein the plasticizer polymer is a vinyl co-polymer and wherein the units having a quaternary ammonium group are acrylic or methacrylic esters or amides to which the quaternary ammonium group is appended.
Claim 11
Dependent Claim 107 words
A printing blank according to claim 10, wherein the plasticizer polymer is of the formula wherein A represents units derived from an acrylic or methacrylic ester monomer; B represents units derived from a vinyl benzene monomer; R 1 is H or methyl; L is -C(O)O-, -C(O)NH-, or an aromatic linking group; M is a C 1 to C 12 alkenyl linking group; R 2 , R 3 , and R 4 are C 1 to C 6 alkyl groups; X - is an anionic counterion; w is 50 to 98 weight percent; y is 0 to 48 weight percent; and z is 2 to 20 weight percent.
Claim 12
Dependent Claim 15 words
A printing blank according to any one of claims 1-11, wherein the support is transparent.
Claim 13
Dependent Claim 22 words
A printing blank according to any one of claims 1-12, further comprising a silver halide emulsion layer for recording a sound track.
Claim 14
Dependent Claim 154 words
A process for exposing a dye imbibition printing matrix film comprising imagewise exposing a matrix film comprising a visible light sensitive silver halide emulsion containing colloid layer on a support to blue, green or red light, wherein the visible light sensitive emulsion is also sensitive to UV light and the toe contrast of the imaged matrix film is controlled by (i) incorporating a UV absorber in the colloid layer of the matrix film, and (ii) flash exposing the matrix film with UV light in the substantial absence of light having a wavelength above 410 nm, wherein the UV absorber provides sufficiently low absorption above 410 nm such that it does not substantially alter the effective photographic speed of the matrix film during the imagewise exposure or the mid scale contrast of the imaged matrix film, and sufficiently high absorption to the UV light to decrease the resulting toe contrast of the imaged matrix film.
Claim 15
Dependent Claim 25 words
A process according to claim 14, wherein the matrix film comprises a blue light sensitive silver halide emulsion which is imagewise exposed to blue light.
Claim 16
Dependent Claim 16 words
A process according to claim 14, wherein the matrix film comprises a pan-sensitive silver halide emulsion.
Claim 17
Dependent Claim 37 words
A process according to any one of claims 14-16, wherein the flash UV exposure is performed with a tungsten or tungsten-halogen lamp and a filter that transmits UV light and absorbs substantially all light above 410 nm.
Claim 18
Dependent Claim 21 words
A process according to any one of claims 14-17, wherein the UV absorber has peak absorbance between 360 and 390 nm.
Claim 19
Dependent Claim 14 words
A process according to any one of claims 14-17, wherein the UV absorber is
Claim 20
Dependent Claim 55 words
A matrix film for use in imbibition printing comprising a support bearing a colloid layer comprising (i) a visible light sensitive silver halide emulsion which is also sensitive to UV light, (ii) visible light absorbing non-photosensitive particles, (iii) a hydrophilic colloid, and (iv) a UV absorber having a peak absorbance between 360 and 410 nm.

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