EP0732138A2
Expired / Lapsed
EP
⏱️ 0.0 years remaining
Planar solid-state membrane module
Assignee: Air Products and Chemicals Inc
•
Filing: 1996-03-11
•
Granted: —
•
Expires: 2016-03-11
Abstract
Abstract This invention presents planar solid-state membrane modules for separating oxygen from an oxygen-containing gaseous mixture which provide improved pneumatic and structural integrity and ease of manifolding. The modules are formed from a plurality of planar membrane units, each membrane unit which comprises a channel-free porous support having connected through porosity which is in contact with a contiguous dense mixed conducting oxide layer having no connected through porosity. The dense mixed conducting oxide layer is placed in flow communication with the oxygen-containing gaseous mixture to be separated and the channel-free porous support of each membrane unit is placed in flow communication with a removal means for discharging oxygen which has been separated from the oxygen-containing gaseous mixture by permeation through the dense mixed conducting oxide layer of each membrane unit and passage into the removal means via the channel-free porous support of each membrane unit.
Inventors
- 👤 Paul Niger Dyer
- 👤 Eric Minford
- 👤 Steven Lee Russek
- 👤 Michael Francis Carolan
- 👤 Dale M. Taylor
- 👤 Jeffrey Donald Bright
- 👤 Raymond Ashton Cutler
- 👤 David W. Prouse
- 👤 Robin Edward Richards
- 👤 Merrill Anderson Wilson
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-05 20:04
CPC Classifications
B; B01; B01D; B01D69/00; B01D69/14; B01D69/141; B01D69/145; B01D53/00; B01D53/22; B01D53/228; B01D67/00; B01D67/0039; B01D67/0041; B01D67/00411; B01D67/0046; B01D67/0072; B01D71/00; B01D71/02; B01D71/024; B01D71/0271; C; C01; C01B; C01B13/00; C01B13/02; C01B13/0229; C01B13/0248; C01B13/0251; C01B13/0255; C01G; C01G49/00; C01G49/0018; C01G49/009; C01G51/00; C01G51/40; C01G51/66; C01G51/68; C04; C04B; C04B35/00; C04B35/01; C04B35/45; B01D2257/00; B01D2257/10; B01D2257/104; B01D2325/00; B01D2325/26; C01B2210/00; C01B2210/0043; C01B2210/0046; C01P; C01P2002/00; C01P2002/30; C01P2002/34; C01P2002/50; C01P2002/52; C01P2002/54; C01P2004/00; C01P2004/60; C01P2004/61
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
131 words
A module for separating oxygen from an oxygen-containing gaseous mixture comprising a plurality of planar membrane units, each planar membrane unit which comprises a channel-free planar porous support having connected through porosity which is in contact with a contiguous planar dense mixed conducting oxide layer having no connected through porosity wherein the planar dense mixed conducting oxide layer is in flow communication with the oxygen-containing gaseous mixture to be separated and wherein the planar channel-free porous support of each membrane unit is in flow communication with a removal means for discharging oxygen which has been separated from the oxygen-containing gaseous mixture by permeation through the planar dense mixed conducting oxide layer of each membrane unit and passage into the removal means via the planar channel-free porous support of each membrane unit.
Claim 2
Dependent Claim
34 words
The module of Claim 1 wherein each membrane unit further comprises a channeled layer which is contiguous to the planar channel free porous support on a side opposite the dense mixed conducting oxide layer.
Claim 3
Dependent Claim
42 words
The module of Claim 1 wherein each membrane unit further comprises a first planar porous layer having a predetermined average pore radius which is contiguous to the planar channel-free porous support on a side opposite the planar dense mixed conducting oxide layer.
Claim 4
Dependent Claim
34 words
The module of Claim 3 wherein each membrane unit further comprises a channeled layer which is contiguous to the first planar porous layer on a side opposite the planar dense mixed conducting oxide layer.
Claim 5
Dependent Claim
59 words
The module of Claim 4 wherein each membrane unit further comprises a second planar porous layer having a predetermined average pore radius which is situated between the first planar porous layer and the channeled layer wherein the average pore radius of the first planar porous layer is smaller than the average pore radius of the second planar porous layer.
Claim 6
Dependent Claim
32 words
The module of Claim 5 wherein each membrane unit further comprises a second channeled layer which is contiguous to the first channeled layer on a side opposite the second planar porous layer.
Claim 7
Dependent Claim
24 words
The module of Claims 4, 5 or 6 wherein the removal means comprises a conduit which traverses each planar membrane unit of the module.
Claim 8
Dependent Claim
15 words
The module of Claims 4, 5 or 6 wherein the removal means comprises a manifold.
Claim 9
Dependent Claim
24 words
The module of Claim 6 wherein the planar dense mixed conducting oxide layer has a thickness ranging from 0.01 micrometer to about 500 micrometers.
Claim 10
Dependent Claim
31 words
The module of Claim 9 wherein the planar channel-free porous support comprises pores having a diameter of less than 5 times the thickness of the planar dense mixed conducting oxide layer.
Claim 11
Dependent Claim
27 words
The module of Claim 10 wherein the dense mixed conducting oxide layer comprises a mixed conducting oxide and the channel-free porous support comprises a mixed conducting oxide.
Claim 12
Dependent Claim
92 words
The module of Claim 11 wherein the mixed conducting oxide is represented by the formula A x A' x' A'' x'' B y B' y' B'' y'' O 3-z , where A,A',A'' are chosen from the group comprising Groups 1, 2 and 3 and the F block lanthanides; and B,B',B'' are chosen from the D block transition metals according to the Periodic Table of the Elements adopted by the IUPAC wherein 0<x≦1, 0≦x'≦1, 0≦x''≦1, 0<y≦1, 0≦y'≦1, 0≧y''≦1, 1.1>x+x'+x''>0.9, 1.1>y+y'+y''>0.9 and z is a number which renders the mixed conducting oxide charge neutral.
Claim 13
Dependent Claim
30 words
The module of Claim 12 wherein A, A' or A'' of the enumerated formula is a Group 2 metal selected from the group consisting of calcium, strontium, barium and magnesium.
Claim 14
Dependent Claim
60 words
The module of Claim 13 wherein the planar dense layer is formed from a mixed conducting oxide represented by the formula La x A' x' Co y Fe y' Cu y'' O 3-z wherein 1.1>x+x'>0.9, 1.1>y+y'+y''>0.9, 0<y'≦0.4 and 0<y''≦0.4, A' is selected from strontium, barium or calcium, and z is a number which renders the mixed conducting oxide charge neutral.
Claim 15
Dependent Claim
109 words
The module of Claim 14 wherein the planar dense mixed conducting oxide layer is formed from a mixed conducting oxide selected from the group consisting of La 0.2 Ba 0.8 Co 0.8 Fe 0.2 O 3-z , Pr 0.2 Ba 0.8 Co 0.8 Fe 0.2 O 3-z , La 0.2 Ba 0.8 Co 0.6 Cu 0.2 Fe 0.2 O 3-z , La 0.2 Sr 0.8 Co 0.4 Fe 0.4 Cu 0.2 O 3-z , La 0.4 Sr 0.6 Co 0.4 Fe 0.4 Cu 0.2 O 3-z , La 0.3 Sr 0.7 Co 0.8 Fe 0.1 Cu 0.1 O 3-z and SrCo 0.4 Fe 0.4 Cu 0.2 O 3-z .
Claim 16
Dependent Claim
42 words
The module of Claim 11 wherein the planar channel-free porous support is formed from a material selected from the group consisting of alumina, ceria, silica, magnesia, titania, a high temperature oxygen compatible metal alloy, a metal oxide stabilized zirconia and mixtures thereof.
Claim 17
Dependent Claim
37 words
The module according to Claim 11 wherein each membrane unit further comprises a catalyzed layer having through porosity which is contiguous to the planar dense mixed conducting oxide layer on a side opposite the channel-free porous support.
Claim 18
Dependent Claim
16 words
The module according to Claim 4 wherein the channeled layer comprises a plurality of radial channels.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
Maintenance schedule is calculated for granted US utility patents.