EP0699654A1
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EP
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Hole-transporting material
Assignee: Artience Co Ltd
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Filing: 1995-08-04
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Granted: —
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Expires: 2015-08-04
Abstract
Abstract A hole-transporting material of formula (1) has excellent hole-transporting capability and excellent durability. H-A-[-B-A-] n -B-A-H wherein A is an aromatic amine derivative residue of formula (2) defined herein, B is a residue of formula (3) defined herein, and n is an integer of 1 to 5,000. The materials may be included in an organic EL device or an electrophotographic photoreceptor which are excellent in stability in continuous long-term use.
Inventors
- 👤 Michiko c/o Toyo Ink Man. Co. Ltd. Tamano
- 👤 Toshikazu C/O Toyo Ink Man. Co. Ltd. Onikubo
- 👤 Toshikyuki c/o Toyo Ink Man. Co. Ltd. Uemura
- 👤 Tadashi c/o Toyo Ink Man. Co. Ltd. Ogawa
- 👤 Toshio c/o Toyo Ink Man. Co. Ltd. Enokida
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-04 07:01
CPC Classifications
H; H05; H05B; H05B33/00; H05B33/12; H05B33/14; C; C07; C07C; C07C211/00; C07C211/43; C07C211/54; C07C217/00; C07C217/78; C07C217/80; C07C217/82; C07C217/92; C07C323/00; C07C323/23; C07C323/31; C07C323/33; C07C323/35; C07C323/37; C09; C09K; C09K11/00; C09K11/06; G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/0618; G03G5/062; G03G5/07; G03G5/075; H10; H10K; H10K85/00; H10K85/10; H10K85/111; H10K85/151; H10K85/60; H10K85/631; H10K85/633; C07C2603/00; C07C2603/02; C07C2603/04; C07C2603/06; C07C2603/10; C07C2603/12; C07C2603/18; C07C2603/22; C07C2603/24; C07C2603/26; H10K2102/00; H10K2102/10; H10K2102/101; H10K2102/103; H10K50/00; H10K50/10; H10K50/14; H10K85/30; H10K85/321; H10K85/324; H10K85/615; Y; Y10; Y10S; Y10S428/00; Y10S428/917; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
254 words
A hole-transporting material of the formula (1), H-A-[-B-A-] n -B-A-H (1) wherein A is an aromatic amine derivative residue of the following formula (2), B is a residue of the following formula (3), and n is from 1 to 5,000, Formula (2): wherein each of R¹ to R¹⁰ is independently hydrogen, halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, an unsubstituted thioalkoxy group, a cyano group, an amino group, a mono- or disubstituted amino group, a hydroxyl group, a mercapto group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group, and adjacent substituents among R¹ to R¹⁰ may form a substituted or unsubstituted ring or rings, X is a divalent aromatic residue or -Ar-Z-Ar- in which each Ar is an aromatic residue having 6 to 20 carbon atoms and Z is a direct bond, oxygen, sulfur, selenium, an aromatic residue which may contain any one of oxygen, sulfur and selenium, or a divalent aliphatic residue which may contain any one of oxygen, sulfur and selenium, and m is 0 or 1, Formula (3): wherein each of R¹¹ to R¹⁴ is independently hydrogen, halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, or a disubstituted amino group, and adjacent substituents among R¹¹ to R¹⁴ may form a substituted or unsubstituted ring, Y is oxygen, sulfur or monosubstituted nitrogen, j is 0 or 1 and k is from 4 to 7.
Claim 2
Dependent Claim
31 words
A hole-transporting material according to claim 1, wherein each of R¹ to R¹⁰ in formula (2) is independently hydrogen, an unsubstituted alkyl group, an unsubstituted alkoxy group or dialkyl-substituted amino group.
Claim 3
Dependent Claim
24 words
A hole-transporting material according to claim 1 or 2, wherein X in formula (2) is a phenylene, biphenylene, substituted biphenylene, terphenylene, naphthylene or anthranylene.
Claim 4
Dependent Claim
35 words
A hole-transporting material according to any of claims 1 to 3, wherein the compound of the formula (3) is 1,1-cyclopentylene, 1,1-cyclohexylene, 1,1-cycloheptylene, 1,1-cyclooctylene or any one of these in which an alkyl group is substituted.
Claim 5
Dependent Claim
48 words
An organic EL device having a pair of electrodes and a light-emitting layer formed of-at least one layer of an organic compound placed between the electrodes, in which at least one layer of the layers forming the light-emitting layer contains a hole-transporting material according to any preceding claim.
Claim 6
Dependent Claim
36 words
A device according to claim 5, wherein the device comprises the light-emitting layer, a combination of the light-emitting layer and a hole-injecting layer or a combination of the light-emitting, a hole-injecting layer and an electron-injecting layer.
Claim 7
Independent Claim
35 words
A device according to claims 5 or 6, wherein at least one of the light-emitting layer, a hole-injecting layer and the electron-injecting layer contains the hole-transporting material according to any of claims 1 to 4.
Claim 8
Dependent Claim
31 words
An electrophotographic photoreceptor comprising an electrically conductive substrate and a photoconductive layer formed on the substrate, the photoconductive layer containing the hole-transporting material according to any of claims 1 to 4.
Claim 9
Dependent Claim
37 words
An electrophotographic photoreceptor according to claim 8, wherein the photoconductive layer contains a charge-generating material and the hole-transporting material, or the photoconductive layer comprises a layer containing a charge-generating layer and a layer containing the hole-transporting material.
Claim 10
Dependent Claim
16 words
Use of a compound of Formula (1) as defined in claim 1, as a hole-transporting material.
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