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EP0575111A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Polymeric insulating material and formed article making use of the material

Assignee: Prime Polymer Co Ltd
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Filing: 1993-06-11
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Granted: —
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Expires: 2013-06-11
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Abstract

Abstract A polymeric insulating material having a high dielectric breakdown voltage comprises polypropylene which has been obtained in a yield of at least 300,000 g/g-Ti based on titanium in a catalyst upon polymerization, contains ash in an amount not greater than 40 ppm by weight when analyzed by completely burning the polypropylene in air, said ash containing titanium in an amount not greater than 1 ppm by weight based on the weight of the polypropylene, and also contains chlorine in an amount not greater than 2 ppm by weight and boiling n-heptane soluble matter in an amount not smaller than 1 wt.% but not greater than 10 wt.%. To further improve the dielectric breakdown voltage, an inorganic oxide or hydroxide free of particles of 10 µm and greater in diameter and having an average particle size not greater than 1 µm, an organopolysilane, a maleic-anhydride-grafted polypropylene, or a silane compound containing at least one organic polyether group can be added to the polypropylene.

Inventors

  • 👤 Takeo Inoue
  • 👤 Shigeru Kimura
  • 👤 Tutomu Iwatani
  • 👤 Takayukii Yamada
  • 👤 Yukio Ishii
  • 👤 Ryuichi Sugimoto

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 12:28
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/44; C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; H01B3/441; C08L51/00; C08L51/06; C08L83/00; C08L83/04; C08L83/10; C08L83/12; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24975; Y10T428/25

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 107 words
A polymeric insulating material having a high dielectric breakdown voltage, comprising polypropylene which has been obtained in a yield of at least 300,000 g/g-Ti based on titanium in a catalyst upon polymerization, contains ash in an amount not greater than 40 ppm by weight when analyzed by completely burning the polypropylene in air, said ash containing titanium in an amount not greater than 1 ppm by weight based on the weight of the polypropylene, and also contains chlorine in an amount not greater than 2 ppm by weight and boiling n-heptane soluble matter in an amount not smaller than 1 wt.% but not greater than 10 wt.%.
Claim 2
Dependent Claim 55 words
A polymeric insulating material of claim 1, wherein the material comprises high-purity polypropylene containing, per cubic centimeter, not more than 6,000 foreign particles of from 1 µm to 10 µm, both inclusive, not more than 1,000 foreign particles of from 5 µm to 10 µm, both inclusive, and no foreign particles greater than 10 µm.
Claim 3
Dependent Claim 39 words
A polymeric insulating material of claim 1, wherein the polypropylene includes at least one additive selected from an inorganic oxide, an inorganic hydroxide, an organopolysilane, a maleic-anhydride-grafted polypropylene and a silane compound containing at least one organic polyether group.
Claim 4
Dependent Claim 76 words
A polymeric insulating material of claim 3, wherein the inorganic oxide or hydroxide is added as the additive in an amount not smaller than 1 ppm by weight but not greater than 10% by weight, and for example the inorganic oxide or hydroxide is the oxide or hydroxide of magnesium, aluminum or iron, which is free of particles of 10 µm and greater in diameter and has an average particle size not greater than 1 µm.
Claim 5
Dependent Claim 48 words
A polymeric insulating material of claim 3, wherein the additive is present in an amount not smaller than 50 ppm by weight but not greater than 10% by weight, and is the organopolysilane or the maleicanhydride-grafted polypropylene, or the silane compound containing at least one organic polyether group.
Claim 6
Dependent Claim 68 words
A polymeric insulating material of claim 1, wherein the polypropylene has been obtained by polymerizing propylene in the presence of a polymerization catalyst which comprises a solid titanium catalyst component containing titanium, magnesium, a halogen and an electron-donating compound (an internal electron-donating compound), an organometal compound containing a metal selected from Groups 1, 2 and 3 of the Periodic Table and another electron-donating compound (an external electron-donating compound).
Claim 7
Dependent Claim 33 words
A polymeric insulating material of claim 6, wherein the propylene has been subjected to dehalogenation treatment, for example has first been subjected to washing with an inert hydrocarbon, and then to dehalogenation treatment.
Claim 8
Dependent Claim 32 words
A formed polypropylene article having high electrical insulating property, said article having been obtained by stretching the polymeric insulating material of any of claims 1 to 5 in at least one direction.
Claim 9
Dependent Claim 20 words
An electrical insulating film obtained by biaxially stretching the polymeric insulating material of any one of claims 1 to 7.
Claim 10
Dependent Claim 28 words
An electrical insulating film having a thickness of 1 to 6 µm obtained by biaxially stretching the polymeric insulating material of any one of claims 1 to 7.

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