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EP0573201A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Infra-red photoconductor based on octa-substituted phthalocyanines

Assignee: Xerox Corp
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Filing: 1993-05-25
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Granted: —
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Expires: 2013-05-25
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Abstract

Abstract A photoconductor contains octa-substituted phthalocyanines in a charge generation layer. The photoconductor shows good sensitivity in the infra-red region of the electromagnetic spectrum from about 600 nm to about 900 nm.

Inventors

  • 👤 Brian E. Springett

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 16:23
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0696

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 38 words
A photoconductor comprising a charge generation layer (2), wherein the charge generation layer (2) comprises a metal centered, metal-halide centered or 2H centered octa-substituted phthalocyanine, wherein substituents on exterior rings of the phthalocyanine are para to each other.
Claim 2
Dependent Claim 61 words
A photoconductor as claimed in claim 1, wherein the octa-substituted phthalocyanine has the formula: wherein M comprises 2H, zinc, copper, magnesium, iron, lead, manganese, chromium, nickel, cobalt, vanadium, zirconium, titanium, chloroindium, chlorogallium, bromoindium, or bromogallium; R comprises a straight or branched alkyl group having from 1 to 10 carbon atoms or a carboxy group having from 2 to 10 carbon atoms.
Claim 3
Dependent Claim 77 words
A photoconductor as claimed in claim 1 or claim 2, wherein the charge generation layer further comprises a binder, and wherein a ratio of pigment:binder ranges from about 4:1 to about 1:100 by weight of the charge generation layer; or a ratio of pigment:binder ranges from about 1:4 to about 2:1 by weight of the charge generation layer; or a ratio of pigment:binder ranges from about 1:1 to about 2:3 by weight of the charge generation layer.
Claim 4
Dependent Claim 57 words
A photoconductor as claimed in any one of claims 1 to 3, wherein the octa-substituted phthalocyanine comprises 1, 4, 8, 11, 15, 18, 22, 25-octa-n-butoxyphthalocyanine; 1, 4, 8, 11, 15, 18, 22, 25-octa-n-methoxyphthalocyanine; 1, 4, 8, 11, 15, 18, 22, 25-octa-n-ethoxyphthalocyanine; 1, 4, 8,11, 15, 18,22, 25-octa-n-pentoxy phthalocyanine or 1, 4, 8, 11, 15, 18, 22, 25-octa-n-propoxyphthalocyanine.
Claim 5
Dependent Claim 27 words
A photoconductor of claim 1, further comprising a substrate, a charge blocking layer and an adhesive layer between the charge blocking layer and the charge generation layer.
Claim 6
Dependent Claim 53 words
A photoconductor as claimed in any one of claims 1 to 5, wherein the charge generation layer contains from about 20% by volume to about 90% by volume of the octa-substituted phthalocyanine, or wherein the charge generation layer contains from about 35% by volume to about 75% by volume of the octa-substituted phthalocyanine.
Claim 7
Dependent Claim 63 words
A photoconductor comprising a substrate, a charge blocking layer, a charge generation layer and a charge transport layer, wherein the charge generation layer comprises at least one member selected from the group consisting of a 2H centered octa-substituted phthalocyanine, a metal centered octa-substituted phthalocyanine and a metal-halide centered octa-substituted phthalocyanine, wherein substituents on exterior rings of the phthalocyanine are para to each other.
Claim 8
Dependent Claim 50 words
The photoconductor of claim 1, further comprising at least one unsubstituted phthalocyanine selected from the group consisting of 2H(metal-free)-phthalocyanine, titanium oxy-phthalocyanine, vanadium oxy-phthalocyanine, aluminum phthalocyanine, aluminum polycholorphthalocyanine, barium phthalocyanine, beryllium phthalocyanine, cadmium phthalocyanine, calcium phthalocyanine, cerium phthalocyanine, chromium phthalocyanine, cobalt phthalocyanine, cobalt chlorophthalocyanine, copper bromophthalocyanine, copper 4-chlorophthalocyanine and copper phthalocyanine.
Claim 9
Dependent Claim 20 words
The photoconductor of claim 8, wherein the ratio of octa-substituted phthalocyanine: unsubstituted phthalocyanine ranges from about 1:10 to about 1:1.
Claim 10
Independent Claim 48 words
A method for preparing a photoconductor comprising: (a) applying a charge generation layer (2) to a substrate; and (b) applying a charge transport layer to the charge generation layer; wherein the charge generation layer (2) has a composition as defined in any one of claims 1 to 9.

References Cited (Backward Citations)

EP0180931A2 Cited
EP0262761A1 Cited
WO1988006175A1 Cited
EP0513370A1 Cited

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