Nitrogen oxides decreasing apparatus for internal combustion engine

Claim 2

An NOx decreasing apparatus according to claim 1, further comprising air-fuel ratio control means for decreasing an air-fuel ratio of the internal combustion engine from a lean ratio to at least a stoichiometric ratio when the NOx absorption and release material (2) is releasing NOx.

Claim 3

An NOx decreasing apparatus according to claim 1, further comprising an NOx decomposition catalyst (4) capable of decomposing NOx under oxidizing gas conditions and installed in the first portion of the exhaust conduit (6) downstream of the NOx absorption and release material (2).

Claim 4

An NOx decreasing apparatus according to claim 1, further comprising: NOx absorption and release material regeneration means for temporarily operating the heater (24) to heat the NOx absorption and release material (2) to a temperature above the predetermined temperature to cause the NOx absorption and release material (2) to release absorbed NOx.

Claim 5

An NOx decreasing apparatus according to claim 4, wherein the NOx absorption and release material (2) comprises a composite oxide of alkaline earth and copper.

Claim 6

An NOx decreasing apparatus according to claim 5, wherein the composite oxide of alkali earth and copper is MnO₂.BaCuO₂.

Claim 7

An NOx decreasing apparatus according to claim 4, wherein the NOx absorption and release material (2) comprises a combination of a rare-earth element and a noble metal.

Claim 8

An NOx decreasing apparatus according to claim 7, wherein the rare-earth element is lanthanum and the noble metal is platinum.

Claim 9

An NOx decreasing apparatus according to claim 4, further comprising: an NOx decomposition catalyst (4) capable of decomposing NOx under oxidizing gas conditions and installed in the first portion of the exhaust conduit (6) downstream of the NOx absorption and release material (2).

Claim 10

An NOx decreasing apparatus according to claim 9, wherein the NOx decomposition catalyst (4) is a zeolite-type catalyst including zeolite and copper ion-exchanged and deposited onto the zeolite.

Claim 11

An NOx decreasing apparatus according to claim 9, wherein the NOx decomposition catalyst (4) is a three-way catalyst.

Claim 12

An NOx decreasing apparatus according to claim 9, wherein the predetermined temperature above which the NOx absorption and release material (2) releases NOx is about 500°C.

Claim 13

An NOx decreasing apparatus according to claim 9 wherein the exhaust conduit (6) comprises: a bypass conduit (8) bypassing the portion of the exhaust conduit (6) where the NOx absorption and release material (2) and the NOx decomposition catalyst (4) are installed; a bypass valve (10) installed at a connection point between the bypass conduit (8) and the first portion of the exhaust conduit (6) and operable to throttle exhaust gas flowing through the first portion of the exhaust conduit (6) containing the NOx absorption and release material (2) and the NOx decomposition catalyst (4), while allowing the remainder of the exhaust gas to flow through the bypass conduit (8); and bypass valve control means for controlling the bypass valve so that the bypass valve throttles the exhaust gas flowing through the NOx absorption and release material (2) and the NOx decomposition catalyst (4) while the NOx absorption and release material regeneration means is causing the heater (24) to heat the NOx absorption and release material (2).

Claim 14

An NOx decreasing apparatus according to claim 13 wherein the NOx absorption and release material regeneration means comprises a timer (14g) which is switched on to begin to count time when an accumulated number of engine rotations exceeds a predetermined number and the exhaust gas temperature measured at an inlet of the NOx absorption and release material (2) exceeds a predetermined temperature and which switches off the heater (24) when the counted period of time exceeds a predetermined time period.

Claim 15

An NOx decreasing apparatus according to claim 14, wherein the predetermined time period set in the timer (14g) is about ten seconds.

Claim 16

An NOx decreasing apparatus according to claim 9 wherein the exhaust conduit comprises a single conduit (54), the first portion of the exhaust conduit containing the NOx absorption and release material (56) being located under a vehicle floor and the NOx decomposition catalyst comprising a three-way catalyst (58).

Claim 17

An NOx decreasing apparatus according to claim 16, further comprising: another three-way catalyst (64) installed in the exhaust conduit between the internal combustion engine (52) and the NOx absorption and release material (56).

Claim 18

An NOx decreasing apparatus according to claim 16 wherein the NOx absorption and release material regeneration means comprises: first decision means for determining whether or not a lean burn condition has continued for a first predetermined time period; second decision means for determining whether or not an exhaust gas temperature at the NOx absorption and release material (56) is higher than the predetermined temperature; air-fuel ratio control means for temporarily reducing the air-fuel ratio of the engine to at least a stoichiometric ratio when the first decision means determines that a lean burn condition has continued for the first predetermined time period and the second decision means determines that the exhaust gas temperature is higher than the predetermined temperature; and a timer for counting time since the air-fuel ratio control means reduces the air-fuel ratio to at least a stoichiometric ratio, the timer switching off the heater and clearing the air-fuel ratio control means when the time counted by the timer exceeds a second predetermined time period.

Claim 19

An NOx decreasing apparatus according to claim 18, wherein the second predetermined time period is about twenty seconds.

Claim 20

An NOx decreasing apparatus according to claim 1, wherein the engine is a diesel engine, the exhaust conduit (30) including a second portion (32B) parallel to the first portion (32A), a second one of said NOx absorption and release material (34B) being disposed in the second portion (32B) of the exhaust conduit, the first and second NOx absorption and release materials (34A, 34B) operating also as diesel particulate filters, said first heater (38A) being disposed in the first portion (32A) of the exhaust conduit upstream of the first NOx absorption and release material (34A) and a second heater (38B) being disposed in the second portion (32B) of the exhaust conduit upstream of the second NOx absorption and release material (34B).

Claim 21

An NOx decreasing apparatus according to claim 20, further comprising: a first flow switching valve (40A) disposed in the first portion (32A) of the exhaust conduit and a second flow switching valve (40B) disposed in the second portion (32B) of the exhaust conduit; a first secondary air supply port (46A) located in the first portion (32A) of the exhaust conduit between the first flow switching valve (40A) and the first NOx absorption and release material (34A), and a second secondary air supply port (46B) located in the second portion (32B) of the exhaust conduit between the second flow switching valve (40B) and the second NOx absorption and release material (34B); a first pressure sensor (92) disposed in the exhaust conduit upstream of the first and second NOx absorption and release materials (34A, 34B), and a second pressure sensor (94) disposed in the second conduit downstream of the first and second NOx absorption and release materials (34A, 34B); and NOx absorption and release material regeneration means for temporarily and alternately operating the first and second heaters (38A, 38B) to burn diesel particulates captured by the first and second NOx absorption and release materials (34A, 34B) and causing the first and second NOx absorption and release materials (34A, 34B) to release absorbed NOx.

Claim 22

An NOx decreasing apparatus according to claim 21, further comprising: a first NOx decomposition catalyst (36A) disposed in the first portion (32A) of the exhaust conduit downstream of the first NOx absorption and release material (34A), and a second NOx decomposition catalyst (36B) disposed in the second portion (32B) of the exhaust conduit downstream of the second NOx absorption and release material (34B).

Claim 23

An NOx decreasing apparatus according to claim 21, wherein said NOx absorption and release material regeneration means includes: a timer; means for determining whether or not a difference between the outputs of the first and second pressure sensors (92, 94) exceeds a predetermined value; means for determining which one of the first and second portions (32A, 32B) of the exhaust conduit is currently open to exhaust gas flow; and means for closing the flow switching valve (40A, 40B) in the determined portion of the exhaust conduit, injecting secondary air into the determined portion, switching on the heater (38A, 38B) in the determined portion, and switching on the timer to cause the timer to count time.

Claim 24

An NOx decreasing apparatus according to claim 23, wherein said NOx absorption and release material regeneration means further includes: means for determining whether or not a time counted by the timer exceeds a first predetermined time period and switching off the heater (38A, 38B) when the counted time exceeds the first predetermined time; and means for determining whether or not a time counted by the timer exceeds a second predetermined time period and stopping the supply of secondary air when the counted time exceeds the second predetermined time.

Claim 25

An NOx decreasing apparatus according to claim 24, wherein the first time period is three minutes and the second time period is fifteen minutes.

Claim 26

An NOx decreasing apparatus according to claim 22, further comprising: a first HC supply port disposed in the first portion (32A) of the exhaust conduit between the first NOx absorption and release material (34A) and the first NOx decomposition catalyst (36A), and a second HC supply port disposed in the second portion (32B) of the exhaust conduit between the second NOx absorption and release material (34B) and the second NOx decomposition catalyst (36B).

Claim 27

An NOx decreasing apparatus according to claim 26, wherein said NOx absorption and release material regeneration means includes: means for supplying HC into one of the first and second portions (32A, 32B) of the exhaust conduit through one of the HC supply ports provided in the one of the first and second portions while one of the first and second NOx absorption and release materials (34A, 34B) installed in the one of the first and second portions (32A, 32B) is being regenerated so that supplied HC promotes reduction of NOx by one of the first and second NOx decomposition catalysts (36A, 36B) installed in the one of the first and second portions (32A, 32B).