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EP0533275A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Diol-terminated polycarbonates and their use in reactive adhesive and/or sealing formulations

Assignee: Enichem SpA
•
Filing: 1992-09-15
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Granted: —
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Expires: 2012-09-15
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Abstract

Abstract Diol-polycarbonates having the general formula Ho-(R₁-O-CO-O) x - -(R₂-O-CO-O-) y -R₃-OH   (I) where R₁, R₂, R₃ , X and Y have the meaning specified in the text, are used in the synthesis of prepolymers which in turn can be used in reactive adhesive and/or sealing formulations of the hygro-, photo- or thermo-setting type, and the procedure for their preparation. The sealing compositions deriving from these diolterminated-polycarbonates are mainly used in transport industry, in the textile and wood industry, for cellular products and in the bookbinding industry.

Inventors

  • 👤 Alberto Greco

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 12:26
CPC Classifications
C; C09; C09J; C09J175/00; C09J175/04; C09J175/14; C09J175/16; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/40; C08G18/42; C08G18/44; C08G18/67; C08G18/671; C08G18/672; C08G18/70; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158; C08G18/8175; C08G64/00; C08G64/02; C08G64/0208; C08G64/16; C08G64/1608; C08G64/18; C08G64/183

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 237 words
Diol-terminated polycarbonates having the general formula (I): HO - (R₁-O-CO-O) x - (R₂-O-CO-O) y -R₃OH wherein: the succession of radicals -R₁-O-CO-O- and -R₂-O-CO-O- inside the copolymer is of a purely random type, R₁ is a linear alkylenic radical deriving from a HO-R₁-OH diol by the loss of the two hydroxyls and containing from 8 to 14 carbon atoms, or represents a mixture of the same radicals. R₂, different from R₁, is a bivalent radical selected from: a) alkylenic radicals linear or branched or cycloalkylenic radicals, containing from 2 to 14 carbon atoms; b) Divalent radicals deriving from polyetherdiglycol terminated by the loss of the two hydroxyls. c) the Divalent radical: d) the bivalent radical -(CH₂) m --COO-(CH₂-) n - deriving from the condensation of a lactone with a linear aliphatic glycol, by the loss of the two hydroxyls, where m is a number between 3 and 5 whereas n is a number from 4 to 14, or e) a mixture of 2 or more bivalent radicals among those listed in paragraphs a), b), c), and d), R₃ is a Divalent radical equal to R₁ or R₂, and x and y have such values that: a) the fraction of the structural units corresponding to: ―(R₁OCO-O) x ― represents from 50 to 95% by weight of the whole copolymer; b) the number molecular weight (MW) of the polycarbonate diol having general formula (I) must be between 1500 and 15,000.
Claim 2
Dependent Claim 61 words
Diol-terminated polycarbonates according to Claim 1, characterized in that R₁ preferably represents a polyethylene radical containing from 9 to 12 carbon atoms, or their mixtures, R₂ represents one or more bivalent radicals deriving from the following diols by the loss of the two hydroxyls: 1,4-butandiol 2,2-dimethyl-1,3-propandiol, 1,5-pentandiol, 1,6-hexandiol, 1,4-bishydroxymethyl-cyclohexane, triethylenglycol or the diol deriving from the condensation of caprolactone with 1,6-hexandiol.
Claim 3
Dependent Claim 17 words
Diol-terminated polycarbonates according to Claim 1, characterized in that their molecular weight is between 2000 and 8000.
Claim 4
Dependent Claim 18 words
Diol-terminated polycarbonates according to Claim 1, characterized in that the crystallization temperature (Tc) ranges from +20°C to +45°C.
Claim 5
Dependent Claim 22 words
Diol-terminated polycarbonates according to Claim 1, characterized in that they have a melting temperature (T m ) of between +40 and +70°C.
Claim 6
Dependent Claim 32 words
Diol-terminated polycarbonates according to Claim 1, characterized in that they have a content of alpha-omega-diol of 50 to 95% by weight (35-95% in moles) referring to the total weight off the polycarbonate.
Claim 7
Dependent Claim 19 words
Polycarbonate diols according to Claim 1, characterized in that they have a (F OH ) hydroxylic function of 2.
Claim 8
Dependent Claim 19 words
Polycarbonate diols according to Claim 1, characterized in that the glass transition temperature (Tg) ranges from -40°C to -60°C.
Claim 9
Dependent Claim 18 words
Polycarbonate diols according to Claim 1, characterized in that they have crystallization enthalpies of 50 to 110 J/g.
Claim 10
Dependent Claim 46 words
Polycarbonate diols characterized in that in the general formula (I), R₁ represents a single alkylenic radical, selected from those cited above, R₂, different from R₁, represents a single bivalent radical among those mentioned above and the units -R₁-O-CO-O- and R₂-O-CO-O- being randomly distributed inside the macromolecule.
Claim 11
Dependent Claim 34 words
Synthesis procedure characterized in that the polycarbonate diol (I) is obtained by transesterification of an organic carbonate and the mixture of diols HO-R₁-OH and HO-R₂-OH where R₁ and R₂ have the previously defined meaning.
Claim 12
Dependent Claim 57 words
Synthesis procedure according to Claim 4, characterized in that the transesterification is normally carried out with a molar ratio diols/organic carbonate of 1.03 to 1.3, at a temperature ranging from 80 to 200 °C, for a period of 4 to 10 hours and eliminating the alcohol, the glycol or the phenol which are formed as reaction by-products.
Claim 13
Dependent Claim 38 words
Reactive adhesive and/or sealing formulations of the hygrosetting type obtained from diol-terminated polycarbonates according to Claim 1 introducing the terminal functions by coupling these respectively with diisocyanate or by coupling with diisocyanate followed by the reaction with N-alkylgamma-aminoalkylenalkoxysilanes.
Claim 14
Dependent Claim 36 words
Reactive adhesive and/or sealing formulations of the photo- or thermo-setting type obtained from diol-terminated polycarbonates according to Claim 1, introducing the terminal function by coupling these with diisocyanates and subsequently by reaction with hydroxyalkylacrylate or hydroxyalkylmethacrylates.
Claim 15
Dependent Claim 33 words
Adhesive and/or sealing formulations according to Claims 13 or 14 characterized in that they contain fillers and additives suitable for increasing the stability and stickiness and/or catalysts capable of increasing their reaction rate.
Claim 16
Dependent Claim 36 words
Non-reactive adhesive and/or sealing formulations in the form of solutions obtained from the formulations according to Claims 13 or 14 after conversion into polymers by hygro- photo- or thermo-setting reaction and their solution in a solvent.
Claim 17
Dependent Claim 35 words
Non-reactive adhesive and/or sealing formulations in the form of emulsions obtained from the formulations according to Claims 13 or 14, after conversion to polymers by hygro-, photo- or thermo-setting reaction and their transformation into emulsion.

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