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EP0529908A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Catalyst useful for the polymerization of olefin

Assignee: Mitsubishi Chemical Corp
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Filing: 1992-08-18
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Granted: —
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Expires: 2012-08-18
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Abstract

Abstract A catalyst useful for the polymerization of olefins, comprising the following components (A) and (B): Component (A): A transition metallic compound having the following formula [I]: wherein M: a transition metal selected from Ti, Zr and Hf; R¹: a monovalent C₁₋₆ hydrocarbyl group, or a monovalent C₁₋₆ hydrocarbyl group containing Si; R²: a divalent C₄₋₂₀ hydrocarbyl group, or a divalent C₄₋₂₀ hydrocarbyl group containing Si; R³: a divalent C₁₋₃₀ hydrocarbyl group, or a divalent C₁₋₃₀ hydrocarbyl group containing Si or Ge; and X and Y: H, halogen, a monovalent C₁₋₂₀ hydrocarbyl group, or a monovalent C₁₋₂₀ hydrocarbyl group containing N, O or Si. Component (B): Alumoxane having the following formula [II] or [III]: wherein m: 4 to 30; and R⁴: a monovalent hydrocarbyl group. A highly stereoregular polyolefin having a high molecular weight can be obtained by the above catalyst.

Inventors

  • 👤 Takashi Mitsubishi Petrochemical Co. Ltd. Fujita
  • 👤 Toshihiko Mitsubishi Petrochemical Co. Lt Sugano
  • 👤 Hideshi Mitsubishi Petrochemical Co. Lt Uchino

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 17:31
CPC Classifications
C; C08; C08F; C08F10/00; C07; C07F; C07F17/00; C08F110/00; C08F110/04; C08F110/06; C08F210/00; C08F210/04; C08F210/06; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/64; C08F4/659; C08F4/65912; C08F4/6592; C08F4/65922; C08F4/65927; Y; Y10; Y10S; Y10S526/00; Y10S526/943

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 251 words
A catalyst useful for the polymerization of olefins, comprising the following component (A) and component (B): Component (A): A transition metallic compound having the following formula [I]: wherein: M represents a transition metal selected from the group consisting of titanium, zirconium and hafnium; two R¹s may be the same or different, and represent a monovalent hydrocarbyl group having 1 to 6 carbon atoms, or a monovalent hydrocarbyl group having 1 to 6 carbon atoms and containing silicon; two R²s may be the same or different, and represent a divalent hydrocarbyl group having 4 to 20 carbon atoms, or a divalent hydrocarbyl group having 4 to 20 carbon atoms and containing silicon, which residue is bonded to two adjacent carbon atoms of the five-membered cyclic ligand; R³ represents a divalent hydrocarbyl group having 1 to 30 carbon atoms in total, or a divalent hydrocarbyl group having 1 to 30 carbon atoms in total and containing silicon or germanium; and X and Y independently represent hydrogen, halogen, a monovalent hydrocarbyl group having 1 to 20 carbon atoms, or a monovalent hydrocarbyl group having 1 to 20 carbon atoms and containing nitrogen, oxygen or silicon, provided that the two five-membered cyclic ligands each having the substituents R¹ and R² are asymmetric about a plane containing M when viewed from their relative position in terms of the group R³. Component (B): Alumoxane having the following formula [II] or [III]: wherein m is a number of 4 to 30, and R⁴ is a monovalent hydrocarbyl group.
Claim 2
Dependent Claim 16 words
A catalyst as set forth in Claim 1, wherein M in the formula [I] is zirconium.
Claim 3
Dependent Claim 21 words
A catalyst as set forth in Claim 1, wherein the substituent R¹ in the formula [I] is a lower alkyl group.
Claim 4
Dependent Claim 28 words
A catalyst as set forth in Claim 1, wherein the substituent R² in the formula [I] is selected from the group consisting of n-butylene group and 1,3-butadienylene group.
Claim 5
Dependent Claim 41 words
A catalyst as set forth in Claim 1, wherein the substituent R¹ in the formula [I] is a lower alkyl group, and the substituent R² in the formula [I] is selected from the group consisting of n-butylene group and 1,3-butadienylene group.
Claim 6
Dependent Claim 48 words
A catalyst as set forth in Claim 1, wherein M in the formula [I] is zirconium, the substituent R¹ in the formula [I] is a lower alkyl group, and the substituent R² in the formula [I] is selected from the group consisting of n-butylene group and 1,3-butadienylene group.
Claim 7
Dependent Claim 22 words
A catalyst as set forth in Claim 1, wherein the component (B) is selected from the group consisting of methylalumoxane and methylisobutylalumoxane.

References Cited (Backward Citations)

EP0366290B1 Cited
EP0485820A2 Cited
EP0485823B1 Cited

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