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EP0490335A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Laminates of polymers having perfluorocyclobutane rings and polymers containing perfluorocyclobutane rings

Assignee: Dow Chemical Co
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Filing: 1991-12-10
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Granted: —
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Expires: 2011-12-10
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Abstract

Abstract A laminate has at least two layers, at least one of which comprises a polymer having more than one perfluorocyclobutane group. Such polymers impart qualities of environmental protection, chemical and solvent resistance, hydrolytic stability, lubricity, low dielectric, hydrostatic stability, weatherability, flame resistance, chemical resistance, scratch resistance, surface passivation, water repellancy, lower surface refractive index, lower surface coefficient of friction, fluid barrier properties, oil repellancy, thermal stability, and/or reduced moisture pick-up. Additionally, the coatings are optically clear, easy to apply either neat, in a solvent or otherwise, have relatively low cure temperatures for their temperature resistance, and exhibit insulating and planarizing capabilities.

Inventors

  • 👤 Alvin P. Kennedy
  • 👤 Larry D. Bratton
  • 👤 Zdravko Jezic
  • 👤 Eckel R. Lane
  • 👤 Donald J. Perettie
  • 👤 Franck W. Richey
  • 👤 David A. Babb
  • 👤 Katherine S. Clement

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 10:44
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C09; C09D; C09D127/00; C09D127/02; C09D127/12; C09D157/00; C09D157/06; C09D157/08; C10; C10M; C10M105/00; C10M105/50; C10M105/54; C10M107/00; C10M107/38; H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/14; H01G4/18; C08J2327/00; C08J2327/02; C08J2327/12; Y; Y10; Y10S; Y10S428/00; Y10S428/901; Y10S428/922; Y10S428/9335; Y10S428/934; Y10T; Y10T428/00; Y10T428/13; Y10T428/131; Y10T428/16; Y10T428/29; Y10T428/31504; Y10T428/3154; Y10T428/31551; Y10T428/31554; Y10T428/31558; Y10T428/31565; Y10T428/31573; Y10T428/31598; Y10T428/31601; Y10T428/31652; Y10T428/31667; Y10T428/31678; Y10T428/31692; Y10T428/31725; Y10T428/31739; Y10T428/31743; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/3192

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 27 words
A laminate having at least two layers characterized in that at least one of the layers (polymer layer) comprises a polymer having more than one perfluorocyclobutane group.
Claim 2
Dependent Claim 90 words
The laminate of Claim 1 wherein the polymer is formed from at least one monomer having a structure represented by Formula I or III: Formula I    CF₂=CF-X-R-(X-CF=CF₂)m or wherein R represents an unsubstituted or inertly substituted group; each X is independently a bond or any group which links R and a perfluorovinyl group; m+1 is the number of -X-CF=CF₂ units; n and n' are the number of G and G' groups, respectively; and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups.
Claim 3
Dependent Claim 27 words
The laminate of Claim 2 wherein the polymer has an average molecular weight of at least 10,000 and there is at least one reinforcing or filling layer.
Claim 4
Dependent Claim 65 words
The laminate of Claim 2 or 3 comprising at least one layer of the polymer and at least one other layer having a composition different from the layer of the polymer said layer comprising wood, clay, stone, silicon, silicon oxide, metal oxide, alloy of metal or metal oxide, metal, semiconductor, polymer of different composition, ceramic, glass, optical fiber, paper, synthetic fibers, cloth, or combinations thereof.
Claim 5
Dependent Claim 40 words
The laminate of Claim 1, 2, 3 or 4 wherein the polymer forms an environmentally protective, moisture resistant, hydrostatically stable, radiation resistant or chemically resistant coating on at least one layer having a composition different from that of the polymer.
Claim 6
Dependent Claim 25 words
The laminate of Claim 1, 2, 3, 4, or 5 wherein the laminate is lined pipe, valve liner, a seal, a gasket, or combination thereof.
Claim 7
Dependent Claim 33 words
The laminate of Claim 1, 2, 3, 4, or 5 wherein the laminate is medical equipment, sick room equipment, medical or other clothing, bed linen, an instrument, ignition resistant paint, or combination thereof.
Claim 8
Dependent Claim 30 words
The laminate of Claim 1, 2, 3, 4, or 5 wherein the laminate is eyeglasses, a window, coated glass, greenhouse, skylight, oven window, solar still, UV filter, or combination thereof.
Claim 9
Dependent Claim 33 words
The laminate of Claim 1, 2, 3, 4, or 5 wherein the laminate is packaging, a roasting bag, popcorn bag, boiling bag, frozen food tray, microwavable food container, retortable pouch, or combination thereof.
Claim 10
Dependent Claim 34 words
The laminate of Claim 1, 2, 3, 4, or 5 wherein the laminate is material with anti-fouling coating, object with underwater insulation, object with electrical insulation, object with mildew resistant coating, or combination thereof.
Claim 11
Dependent Claim 36 words
The laminate of Claim 1, 2, 3, 4, or 5 wherein the laminate is automobile body part, vessel, mold, turbine blade, tub, food processing equipment, cryogenic container, autoclave, oven, heat exchanger, fuel container, or combination thereof.
Claim 12
Dependent Claim 52 words
The laminate of Claim 2, 3, 4 or 5 wherein the laminate is a light bulb, carpet, bathtub, shower, sleeping bag, sail, raincoat, protective clothing, mattress, furniture, draperty, pillow, toy, tent, camper, microwave cookware, refrigerator (inside or outside), cookware, utensil for coated cookware, tile, swimming pool liner, siding, roofing, or combination thereof.
Claim 13
Dependent Claim 30 words
The laminate of Claim 1, 2, 3, 4 or 5 wherein the laminate is an electrical switch enclosure, battery, battery separator; photographic, X-ray, or other imaging film; or combination thereof.
Claim 14
Dependent Claim 48 words
An electronic device comprising a laminate of Claim 6 wherein at least one other layer comprises silicon, silicon oxide, a metal, a metal oxide, an alloy of a metal or metal oxide, a semiconductor, a polymer of different composition, ceramic, glass, paper, synthetic fibers, quartz or mixtures thereof.
Claim 15
Dependent Claim 15 words
The electronic device of Claim 14 wherein the polymer is an insulator in the device.
Claim 16
Dependent Claim 13 words
A computer comprising at least one electronic device of Claim 14 or 15.
Claim 17
Dependent Claim 36 words
The laminate of Claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 or 15 wherein the laminate is formed by segregation of the polymer from a material of different composition.
Claim 18
Dependent Claim 31 words
A process of preparing a laminate comprising a step of coating at least one material characterized in that the material is coated with a polymer having more than one perfluorocyclobutane group.
Claim 19
Dependent Claim 34 words
The process of Claim 18 wherein the polymer is prepolymerized to a stage of less than complete polymerization before the step of coating and after coating is exposed to conditions under which polymerization procedes.

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