EP0488627A2
Expired / Lapsed
EP
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Oxygen permeable contact lens and method of manufacture therefor
Assignee: Paragon Vision Sciences Inc
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Filing: 1991-11-25
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Granted: —
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Expires: 2011-11-25
Abstract
Abstract An oxygen permeable bifocal contact lens which has a distance vision portion and a near vision portion is made from materials having differing refractive indexes. The near vision portion has a higher refractive index than the distance portion with a Dk of at least 10. The distance portion forms the major portion of the lens and is formed as a crosslinked copolymer with a refractive index of not more than 1.49 from monomeric materials which impart oxygen permeability to the finished lens, and the near vision portion similarly is formed as a crosslinked copolymer from a monomer mixture which includes one or more monomers at a concentration and with a refractive index such that the near vision portion has a refractive index of at least 1.54. The monomer of the near vision portion includes at least one vinyl monomer having a substituted aromatic ring structure to make the monomer bulky and ensure there is only a limited shrinkage on polymerization of such monomers and mixtures containing them.
Inventors
- 👤 Lisa Pettigrew
- 👤 Donald A. Ratkowski
- 👤 William E. Burke
- 👤 Joseph I.Iii Weinschenk
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-10-30 02:16
CPC Classifications
G; G02; G02C; G02C7/00; G02C7/02; G02C7/04; G02C7/041; G02C7/043; B; B29; B29C; B29C39/00; B29C39/02; B29C39/021; B29C39/025; B29D; B29D11/00; B29D11/00009; B29D11/00028; B29D11/00038; B29D11/00076; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; G02C7/045; G02C7/049; B29K; B29K2105/00; B29K2105/0002; B29K2995/00; B29K2995/0037; B29K2995/0065; G02C2202/00; G02C2202/16
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
152 words
An oxygen permeable bifocal contact lens having a distance vision portion with one refractive index and a near vision portion with another higher refractive index and a Dk of at least 10, the distance portion forming the major portion of the lens and being formed as a crosslinked copolymer with a refractive index of not more than 1.49 from monomeric materials which include one or more monomers capable of imparting oxygen permeability to the finished lens, and the near vision portion similarly being formed as a crosslinked copolymer from a monomer mixture which includes one or more monomers at a concentration and with a refractive index such that the near vision portion has a refractive index of at least 1.540 including at least one vinyl monomer having substituted aromatic ring structure which makes such monomers bulky and ensures there is only limited shrinkage on polymerization of such monomers and mixtures containing them.
Claim 2
Dependent Claim
23 words
An oxygen permeable bifocal contact lens as claimed in claim 1, in which the distance vision portion is formed as an interpenetrating network.
Claim 3
Dependent Claim
26 words
An oxygen permeable bifocal contact lens as claimed in claim 1 or claim 2, in which the near vision portion is formed as an interpenetrating network.
Claim 4
Dependent Claim
47 words
An oxygen permeable bifocal contact lens as claimed in claim 2 or claim 3, in which the interpenetrating network is formed by polymerizing a mixture of two monomer mixtures, one of which is being partially polymerized to a selected relative viscosity before being mixed with the other.
Claim 5
Dependent Claim
55 words
An oxygen permeable bifocal contact lens as claimed in Claim 4 in which the distance vision portion is formed as an interpenetrating network from two monomer Mixtures A and B and the composition is selected so that Mixture A contains 10% to 90% (w/w) of the total monomer formula weight, the balance being Mixture B.
Claim 6
Dependent Claim
30 words
An oxygen permeable bifocal contact lens as claimed in Claim 5 where Mixture A contains 50% to 95% of the total monomer formula weight, and the balance is Mixture B.
Claim 7
Dependent Claim
68 words
An oxygen permeable bifocal contact lens as claimed in any one of claims 2 to 4, in which the near vision portion is formed as an interpenetrating network with a refractive index of at least 1.540 from two monomer Mixtures C and D and the resultant composition is selected so that Mixture C containsl10 to 90% of the total monomer formula weight, and the balance is Mixture D.
Claim 8
Dependent Claim
231 words
An oxygen permeable bifocal contact lens as claimed in claim 5 or 6 in which the total monomer content of Mixtures A and B is selected from: a) 0 to 30% of an alkyl acrylate having the formula: where R = H or a monovalent organic radical having not more than 7 carbon atoms and R′ = a monovalent organic radical having up to 20 carbon atoms. b) 0 to 35% of a fluoroacrylate monomer having the formula: where R = H or a monovalent organic radical having not more than 7 carbon atoms; A = H or E and E is a fluorinated monovalent radical having no more than 20 carbon atoms. c) 10 to 70% of a silicone acrylate of the general formula: where R = H or monovalent organic radical having from 1 to 7 carbon atoms or Z; Y is a monovalent organic radical having from 1 to 7 carbon atoms or Z; and where R1, R2 and R3 are the same or different monovalent organic radicals having from 1 to 7 carbon atoms and R4 is OH or a monovalent organic radical having from 1 to 7 carbon atoms; and k = 0-1; m = 1-3; n = 1-5; and p = 1-3. d) from 0.1 to 20% of at least one crosslinking agent. e) from 1 to 10% of a polymerizable vinyl hydrophilic wetting agent.
Claim 9
Dependent Claim
125 words
An oxygen permeable bifocal contact lens as claimed in claim 7 in which the total monomer content of Mixtures C and D is selected from: a) from 30 to 90% of at least one polymerizable vinyl monomer having a refractive index of at least 1.540 and having a substituted aromatic ring structure. b) from 1 to 60 of an acrylate having the formula: where R = H or a monovalent organic radical having not more than 7 carbon atoms and R′ is a monovalent organic radical having up to 20 carbon atoms. c) from 0.1 to 15% of a polymerizable polyvinyl crosslinking agent. d) from 0 to 2% of a polymerizable vinyl silane coupling agent. e) from 0.1 to 3.0% of a vinyl polymerization initiator.
Claim 10
Dependent Claim
41 words
An oxygen permeable bifocal contact lens as claimed in claim 9 in which the polymerizable vinyl monomer having a refractive index of at least 1.540 comprises one or more carbazoles selected from the group consisting of N-vinyl carbazole, 3-(N-carbazoyl) propyl acrylate.
Claim 11
Dependent Claim
45 words
An oxygen permeable bifocal contact lens as claimed in claim 9 in which at least one polymerizable vinyl monomer having a refractive index of at least 1.540 is selected from the group consisting of 2-(N-phenothiazinyl) ethyl acrylate, p-t-butylstyrene, vinyl naphthalene, and phenyl and benzyl methacrylates.
Claim 12
Dependent Claim
29 words
An oxygen permeable bifocal contact lens as claimed in any of claims 1 to 11 in which the distance vision portion of the lens surrounds the near vision portion.
Claim 13
Dependent Claim
24 words
A contact lens button for use in forming an oxygen permeable bifocal contact lens as claimed in any one of claims 1 to 12.
Claim 14
Independent Claim
135 words
A method of producing an oxygen permeable bifocal contact lens having a near vision portion and a distance vision portion as claimed in any one of claims 3 to 12 in which the near vision portion is formed in the body of the lens by polymerizing a partially polymerized mixture of the interpenetrating network forming comonomers in contact with a surface shaped to leave a recess in the material after both polymerization and removal from contact with the shaped surface, the recess being of the same shape as the desired shape of the near vision portion of the finished lens, and a partially polymerized mixture of interpenetrating network comonomers, including at least one vinyl monomer with refractive index of at least 1.540 and a substituted aromatic ring structure is placed in the recess and polymerized.
Claim 15
Dependent Claim
55 words
A method of producing a bifocal contact lens as claimed in claim 14 in which the near vision portion is covered with the material used to form the distance vision portion of the lens by polymerizing a further quantity of said distance vision material in contact with the already formed near and distance vision portions.
Claim 16
Dependent Claim
23 words
A method as claimed in claim 16 in which a base curve is cut in the near vision portion before it is covered.
Claim 17
Dependent Claim
52 words
A method as claimed in claim 14, 15 or 16 in which a quantity of the material used to form the distance vision portion is placed in an open topped mold and a recess formed by providing the mold with a cover whose surface contacting the material is the recess forming surface.
Claim 18
Dependent Claim
37 words
A method as claimed in claim 17 in which a lens blank is formed within the open topped mold and the mold is used as a carrier during machining the lens blank to a final lens form.
Claim 19
Dependent Claim
146 words
An oxygen permeable bifocal contact lens with a Dk of at least 10 x 10⁻¹¹ in which the higher index segment is surrounded by an oxygen permeable low index material by forming the lens in a series of steps comprising first forming a preform from low index material in which there is provided a recess, filling the recess with a partially polymerized high index material formed from a monomer mixture which includes at least one vinyl monomer with a refractive index of at least 1.540 and having a substituted aromatic ring structure completing the polymerization of the high index material, and thereafter covering both the low index material and the high index material with further low index material in a partially polymerized form, and finally completing polymerization of the low index material to form a lens blank which is then machined into a bifocal contact lens.
Claim 20
Independent Claim
181 words
A method of producing an oxygen permeable bifocal contact lens with a Dk of at least 10 x 10⁻¹¹ by embedding a high refractive index polymer segment within a lens blank which has a substantially lower refractive index than that of the internal segment, the lens blank having been prepared by casting a partially polymerized mixture of low refractive index interpenetrating network forming comonomers including a silicone acrylate monomer against a mold with a protrusion so as to form a recess in the blank and polymerizing to a solid state, the recess being then filled with a relatively high refractive index monomer mixture, which includes at least one vinyl monomer with a refractive index of at least 1.540 and a substituted aromatic ring structure, the polymerization of which is then completed in the recess, a sufficient quantity of partially polymerized low refractive index monomer mixture being next added to completely cover the high refractive index segment, and the resulting composition is cured to form the final bifocal contact lens blank, which is in turn machined to form a bifocal contact lens.
References Cited (Backward Citations)
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