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EP0486113A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Biodegradable fabric softeners derived from aspartic acid or glutaminic acid

Assignee: Akzo Nobel NV
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Filing: 1991-11-14
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Granted: —
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Expires: 2011-11-14
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Abstract

Abstract Stable aqueous dispersions are described which display a fabric softening action and contain a biodegradable cationic nitrogen compound. The anion of the compound is the anion of a water-soluble organic Bronstedt acid. The acid is present in an amount more than equivalent to the amount of the nitrogen compound. The cationic nitrogen is obtained from an amine which is prepared from an unsaturated dicarboxylic ester e.g. ditallow maleate and an amine e.g. dimethyl amine.

Inventors

  • 👤 Albert Frank
  • 👤 Werner Güth
  • 👤 Götz Krüger
  • 👤 Hans Rörig

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 11:42
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/38; C11D1/62; C11D1/46; C11D3/00; C11D3/0005; C11D3/001; C11D3/0015; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 133 words
A stable aqueous dispersion of a cationic amino compound derived from an aliphatic aminodicarboxylic acid, characterised in that the cationic amino compound satisfies the following formula: wherein n equals 1 or 2, R¹ and R² may be the same or different and represent hydrogen, alkyl or alkenyl, and R³ and R⁴ may be the same or different and represent alkyl or alkenyl, such that at least 2 of the groups R¹ - R⁴ contain 8-24 carbon atoms and, in the case of neither R¹ nor R² representing hydrogen, at least one of the groups R¹ - R⁴ contains 1-4 carbon atoms, and wherein A⁻ is the anion of a water-soluble organic Bronstedt acid, with the proviso that the acid is present in an amount more than equivalent to the amount of nitrogen compound.
Claim 2
Dependent Claim 27 words
A stable aqueous dispersion according to claim 1, characterised in that the acid is present in it in at least twice the equivalent amount of amino compound.
Claim 3
Dependent Claim 159 words
A stable aqueous dispersion comprising a cationic amino compound derived from an aliphatic aminodicarboxylic acid, characterised in that the cationic amino compound satisfies the following formula: wherein n equals 1 or 2, R¹ and R² may be the same or different and represent hydrogen, alkyl or alkenyl, and R³ and R⁴ may be the same or different and represent alkyl or alkenyl, such that at least 2 of the groups R¹ - R⁴ contain 8-24 carbon atoms and, in the case of neither R¹ nor R² representing hydrogen, at least one of the groups R¹ - R⁴ contains 1-4 carbon atoms, and wherein A⁻ is the anion of a water-soluble organic Bronstedt acid, with the proviso that the acid is added in such an amount that a dispersion diluted with mains water which contains 0,5-30 wt.% of amino compound will have a pH below the value corresponding to the molar equivalence point of the amino compound and the acid.
Claim 4
Dependent Claim 144 words
A stable aqueous dispersion comprising a cationic amino compound derived from an aliphatic aminodicarboxylic acid, characterised in that the cationic amino compound satisfies the following formula: wherein n equals 1 or 2, R¹ and R² may be the same or different and represent hydrogen, alkyl or alkenyl, and R³ and R⁴ may be the same or different and represent alkyl or alkenyl, such that at least 2 of the groups R¹ - R⁴ contain 8-24 carbon atoms and, in the case of neither R¹ nor R² representing hydrogen, at least one of the groups R¹ - R⁴ contains 1-4 carbon atoms, and wherein A⁻ is the anion of a water-soluble organic Bronstedt acid, with the proviso that the amino compound and the carboxylic acid are present in such an amount that the dispersion in the concentrated form has a pH of less than 5.
Claim 5
Dependent Claim 19 words
A stable aqueous dispersion according to claim 4, characterised in that the pH is in the range of 1,5-3.
Claim 6
Dependent Claim 24 words
A stable aqueous dispersion according to any one of the preceding claims, characterised in that the cationic amino compound is dimethyl dihydrogenated tallow aspartate.
Claim 7
Dependent Claim 22 words
A stable aqueous dispersion according to any one of the preceding claims, characterised in that the organic acid is a hydroxycarboxylic acid.
Claim 8
Dependent Claim 24 words
A stable aqueous dispersion according to claim 6, characterised in that the hydroxycarboxylic acid is citric acid, malic acid, lactic acid or glycolic acid.
Claim 9
Dependent Claim 15 words
A fabric softener comprising an aqueous dispersion according to any one of the preceding claims.
Claim 10
Dependent Claim 72 words
A fabric softener comprising a quaternary ammonium compound satisfying the following formula: wherein n equals 1 or 2, R⁵ - R⁸ may be the same or different and represent alkyl or alkenyl, such that at least two of these groups contain 8-24 carbon atoms and at least one of these groups contains 1-4 carbon atoms, Q is an alkyl or hydroxy alkyl group containing 1-6 carbon atoms, and X⁻ is an anion.
Claim 11
Dependent Claim 58 words
Use of a compound satisfying the formula: wherein n equals 1 or 2, R⁹ and R¹⁰ may be the same or different and represent an alkyl or alkenyl group having 1-4 carbon atoms, and R¹¹ and R¹² may be the same or different and represent an alkyl or alkenyl group having 8-24 carbon atoms, in fabric softening compositions.

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