← Back to Patent Explorer
EP0486044A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Damage tolerant composites containing infusible particles

Assignee: Hercules LLC
•
Filing: 1991-11-15
•
Granted: —
•
Expires: 2011-11-15
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Damage tolerant structural composites comprising high strength filaments in the form of bundles or tows of continuous fiber and a crosslinked epoxy resin matrix are disclosed. The invention, more particularly relates to improvements in the crosslinked epoxy resin matrix which provide the structural composites with high post impact compressive strength while maintaining such other desirable attributes of epoxy composites as good high temperature performance, solvent resistance and good processing characteristics. The crosslinked epoxy resin matrix contains infusible particles that reside primarily between plies of the composite and have a median particle size between 5 - 75 microns. Prepregs for making the damage tolerant composites and methods of making such prepregs and the epoxy resin compositions thereof are also disclosed. The epoxy resin compositions contain the infusible particles which become segregated as to size on a surface layer of the prepreg during the process of combining the high strength filaments of the prepreg and the resin containing the epoxy resin composition. Alternatively, the infusible particles may be disposed directly on the epoxy resin surface of the prepreg.

Inventors

  • 👤 Anita Ngai Chan
  • 👤 Samuel Anthony Thompson
  • 👤 Mary Ann White

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 18:01
CPC Classifications
C; C08; C08L; C08L63/00

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 71 words
In a resin composition comprising from about 70 to about 99 wt% of an epoxy resin composition and from about 1 to about 30 wt% of ex situ particles, wherein said particles have a median size between 5 and 75 microns the improvement wherein said particles are selected from the group consisting of elastomeric particles having a Tg below about 15 °C and mixtures of said elastomeric particles and inorganic particles.
Claim 2
Dependent Claim 16 words
The resin composition in accordance with claim 1 wherein said elastomeric particles comprise butadiene-acrylonitrile copolymer particles.
Claim 3
Dependent Claim 24 words
The resin composition in accordance with claim 2 wherein said elastomeric particles contain functionalities selected from the group consisting of carboxyl and amine functionality.
Claim 4
Dependent Claim 16 words
The resin composition in accordance with claim 1 wherein said inorganic particles are a mineral filler.
Claim 5
Dependent Claim 19 words
The resin composition of claim 1 wherein said particles are carboxylated butadiene-acrylonitrile copolymer particles reinforced with a mineral filler.
Claim 6
Dependent Claim 13 words
The resin composition of claim 1 wherein said inorganic particles comprise glass particles.
Claim 7
Dependent Claim 88 words
The resin composition in accordance with claim 1 wherein said epoxy resin composition comprise: about 100 parts by weight of an epoxy resin component having at least two epoxide groups per molecule; between about 5 and 100 parts by weight of a curing agent or mixture of curing agents; between about 10 and 70 parts by weight of a polymeric toughener selected from the group consisting of reactive aromatic oligomers and thermoplastics and mixtures thereof; and between about 0 and 10 parts by weight of a cure accelerator.
Claim 8
Dependent Claim 17 words
The resin composition of claim 7 wherein said curing agent comprises a mixture of 4,4'-diaminodiphenylsulfone and dicyandiamide.
Claim 9
Dependent Claim 17 words
The resin composition of claim 7 wherein said reactive oligomer comprises a terminally functional polyarylene polyether sulfone.
Claim 10
Dependent Claim 12 words
The resin composition of claim 7 wherein said thermoplastic is a polyethersulfone.
Claim 11
Dependent Claim 35 words
A prepreg useful in making damage tolerant structural composites, said prepreg comprising one or more high strength filament tows or bundles that is impregnated with the resin composition of any one of the preceding claims.
Claim 12
Dependent Claim 92 words
In a multi-layer damage tolerant, structural composite, said composite comprising: (a) a crosslinked epoxy matrix; (b) high strength filaments within said matrix in the form of tows or rovings that comprise a multitude of said filaments, said tows or rovings being in layers extending throughout said composite; and (c) ex situ particles, the improvement wherein said particles have a median size between 5 and 75 microns and are selected from the group consisting of elastomeric particles having a Tg below about 15 °C and mixtures of said elastomeric particles and inorganic particles.
Claim 13
Dependent Claim 13 words
The composite of claim 12 wherein said elastomeric particles comprise butadiene-acrylonitrile copolymer particles.
Claim 14
Dependent Claim 21 words
The composite of claim 13 wherein said elastomeric particles contain functionalities selected from the group consisting of carboxyl and amine functionality.
Claim 15
Dependent Claim 13 words
The composite of claim 12 wherein said inorganic particles are a mineral filler.
Claim 16
Dependent Claim 12 words
The composite of claim 12 wherein said inorganic particles comprise glass particles.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Maintenance schedule is calculated for granted US utility patents.

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag