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EP0458397B1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Bleach activation

Assignee: Unilever PLC
•
Filing: 1991-05-15
•
Granted: 1997-03-26
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Expires: 2011-05-15
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Abstract

No abstract record available.

Inventors

  • 👤 Thomas Louise F. Favre
  • 👤 Ronald Hage
  • 👤 Karin Van Der Helm-Rademaker
  • 👤 Hypolites Koek
  • 👤 Rudolf Johan Martens
  • 👤 Ton Swarthoff
  • 👤 Marten Robert P. Van Vliet

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-24 01:18
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/395; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3932

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 188 words
Use of a metal complex of formula (A) : [L n Mn m X p ] z Y q (A) wherein Mn is manganese, or iron or mixtures thereof, which can be in the II, III, IV or V oxidation state or mixtures thereof; n and m are independent integers from 1-4; X represents a co-ordination or bridging species; p is an integer from 0-12; Y is a counter-ion, the type of which is dependent upon the charge z of the complex which can be positive, zero or negative; q = z/[charge Y]; and L is a ligand being a macrocylic organic molecule of the general formula : wherein R 1 and R 2 can each be zero, H, alkyl or aryl, optionally substituted; t and t' are each independent integers from 2-3; D and D 1 can independently be N, NR, PR, O or S, wherein R is H, alkyl or aryl, optionally substituted; and s is an integer from 2-5, wherein if D=N, one of the hetero-carbon bonds attached thereto will be unsaturated, giving rise to a N=CR 1 -fragment, as a bleach and oxidation catalyst.
Claim 2
Dependent Claim 138 words
Use according to Claim 1, wherein the metal complex is a manganese complex of formula (A) : (A)   [L n Mn m X p ] z Y q wherein Mn is manganese which can be in the II, III, IV or V oxidation state or mixtures thereof; X represents a small co-ordinating ion and/or bridging molecule or combination thereof; L is a macrocyclic organic molecule of the general formula : wherein R 1 and R 2 can each be zero, H, alkyl or aryl, optionally substituted, D and D 1 are each independently N, NR, PR, O or S, wherein R is H, alkyl or aryl, optionally substituted; t and t' are each independently integers from 2-3, s is an integer from 2-4; and n, m, p, q, Y and z have the meaning indicated in claim 1.
Claim 3
Dependent Claim 12 words
Use according to Claim 1 or 2, wherein p is from 3-6.
Claim 4
Dependent Claim 11 words
Use according to Claim 3, wherein n = m = 2.
Claim 5
Dependent Claim 27 words
Use according to Claim 4, wherein D and D 1 are each independently NH or NR; s is 2; and R 1 = R 2 = H.
Claim 6
Dependent Claim 18 words
Use according to Claim 5, wherein D and D 1 are NCH 3 ; and t,t' = 2.
Claim 7
Dependent Claim 31 words
Use according to Claim 4, wherein D and D 1 are each independently NH or NR; s is 2; and R 1 and R 2 are each independently H or alkyl.
Claim 8
Dependent Claim 17 words
Use according to Claim 7, wherein D and D 1 are NCH 3 and t,t' = 2.
Claim 9
Dependent Claim 11 words
Use according to Claim 6, wherein said ligand L is 1,4,7-trimethyl-1,4,7-triazacyclononane.
Claim 10
Dependent Claim 54 words
Use according to Claim 9, wherein the core complex is selected from : (i)   [Mn III 2 (µ-O) 1 (µ-OAc) 2 (Me-TACN) 2 ] (ii)   [Mn III Mn IV (µ-O) 1 (µ-OAc) 2 (Me-TACN) 2 ] (iii)   [Mn IV 2 (µ-O) 3 (Me-TACN) 2 ] (iv)   [Mn IV 2 (µ-O) 3 (Me/Me-TACN) 2 ]
Claim 11
Dependent Claim 38 words
A bleaching or cleaning process employing a bleaching agent comprising a peroxy compound, wherein said bleaching agent is activated by a catalytic amount of a metal complex used and defined according to any of the preceding Claims 1-10.
Claim 12
Dependent Claim 33 words
A process according to Claim 11, wherein said metal complex is a manganese complex and used at a level of from 0.001 ppm to 100 ppm of manganese in an aqueous bleaching solution.
Claim 13
Dependent Claim 17 words
A process according to Claim 12, wherein said level of manganese is from 0.01 to 20 ppm.
Claim 14
Dependent Claim 39 words
A process according to Claim 11, 12 or 13, wherein said bleaching agent is selected from the group consisting of hydrogen peroxide, hydrogen peroxide-liberating compounds, hydrogen peroxide-generating systems, peroxyacids and their salts, and peroxyacid bleach precursors, and mixtures thereof.
Claim 15
Dependent Claim 15 words
A process according to Claim 14, wherein a metal complex of Claim 10 is used.
Claim 16
Dependent Claim 22 words
A bleaching composition comprising a peroxy compound and a metal complex used and defined according to any of the preceding Claims 1-10.
Claim 17
Dependent Claim 40 words
A composition according to Claim 16, which comprises said peroxy compound at a level of from 2 to 30% by weight and said metal complex at a level corresponding to a manganese content of from 0.0005% to 0.5% by weight.
Claim 18
Dependent Claim 17 words
A composition according to Claim 17, wherein said manganese content is from 0.001% to 0.25% by weight.
Claim 19
Dependent Claim 36 words
A composition according to Claims 17-18, wherein said peroxy compound is selected from the group consisting of hydrogen peroxide, hydrogen peroxide-liberating compounds, hydrogen peroxide-generating systems, peroxyacids and their salts, and peroxyacid bleach precursors, and mixtures thereof.
Claim 20
Dependent Claim 20 words
A composition according to Claim 19, which further comprises a surface-active material in an amount up to 50% by weight.
Claim 21
Dependent Claim 22 words
A composition according to Claim 20, which further comprises a detergency builder in an amount of from 5 to 80% by weight.
Claim 22
Dependent Claim 28 words
A composition according to Claim 19, 20 or 21, which further comprises an enzyme selected from the group consisting of proteases, cellulases, lipases, amylases, oxidases and mixtures thereof.
Claim 23
Dependent Claim 19 words
A composition according to any of the preceding Claims 17-22, wherein the metal complex is that of Claim 10.

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