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EP0457435A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Biocide composition and use

Assignee: Syngenta Ltd
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Filing: 1991-04-12
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Granted: —
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Expires: 2011-04-12
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Abstract

Abstract A composition which contains a 4,5-polymethylene-4-isothiazolin-3-one and either a 2-halo-2-halomethylglutaronitrile or a defined isothiazolinone which is different from the 4,5-polymethylene-4-isothiazolin-3-one and which can be a 4,5-optionally halogenated N-alkyl isothiazolin-3-one. The compositions exhibit anti-microbial activity and certain combinations are surprisingly effective against bacteria.

Inventors

  • 👤 Fraser Forrest Morpeth

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-01 06:07
CPC Classifications
A; A01; A01N; A01N43/00; A01N43/72; A01N43/80

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 39 words
A composition which comprises a) at least one 4,5-polymethylene-4-isothiazolin-3-one or a derivative thereof, and b) at least one 2-halo-2-halomethyl glutaronitrile, or c) at least one isothiazolin-3-one derivative which does not contain a fused ring attached to the isothiazole ring.
Claim 2
Dependent Claim 191 words
A composition as claimed in claim 1 wherein a) is at least one compound of the general formula: wherein R¹ and R² together represent a polymethylene chain having 3 or 4 carbon atoms, or a polymethylene chain having 3 or 4 carbon atoms substituted by at least one lower alkyl radical having from 1 to 4 carbon atoms; R³ represents hydrogen, linear or branched alkyl having up to 12 carbon atoms, linear or branched alkyl having up to 3 carbon atoms substituted by at least one hydroxyl group, an alkenyl group having from 3 to 6 carbon atoms, a radical of the formula wherein n is 0 or 1; m is 1 or 2; R⁴ represents hydrogen or alkyl having from 1 to 4 carbon atoms; and R⁵ represents hydrogen, alkyl having from 1 to 4 carbon atoms, nitro, trifluoromethyl or halogen, cycloalkyl having from 3 to 6 carbon atoms, a radical of formula wherein R⁶ represents hydrogen, linear or branched alkyl having up to 12 carbon atoms or a radical of formula as defined above, or their salts or complex with a mineral or organic acid, or with a base.
Claim 3
Dependent Claim 19 words
A composition as claimed in either claim 1 or claim 2 wherein component a) is either 4,5-trimethylene-4-isothiazolin-3-one or 2-methyl-4,5-trimethylene-4-isothiazolin-3-one.
Claim 4
Dependent Claim 37 words
A composition as claimed in any one of claims 1 to 3 where component b) is at least one compound of general formula wherein each X, which may be the same or different, is a halogen atom.
Claim 5
Dependent Claim 22 words
A composition as claimed in any one of claims 1 to 4 wherein component b) is either 2-chloro-2-chloromethyl glutaronitrile or 2-bromo-2-bromomethyl glutaronitrile.
Claim 6
Dependent Claim 18 words
A composition as claimed in any one of claims 1 to 5 which comprises 2-methyl-4,5-trimethylene-4-isothiazolin-3-one and 2-bromo-2-bromomethyl glutaronitrile.
Claim 7
Dependent Claim 57 words
A composition as claimed in any one of claims 1 to 3 where component (c) is at least one compound of general formula wherein Y is a hydrogen atom, an alkyl, substituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or aryl; and R⁷ is hydrogen, halogen or an alkyl group; and R⁸ is hydrogen, halogen or an alkyl group.
Claim 8
Dependent Claim 22 words
A composition as claimed in claim 7 wherein component (c) is selected from 2-methylisothiazolin-3-one, 5-chloro-2-methylisothiazolin-3-one and 4,5-dichloro-2-methylisothiazolin-3-one either alone or in combination.
Claim 9
Dependent Claim 20 words
A composition as claimed in claim 8 which comprises 2-methyl-4,5-trimethylene-4-isothiazolin-3-one together with at least one of 2-methylisothiazolin-3-one, 5-chloro-2-methylisothiazolin-3-one and 4,5-dichloro-2-methylisothiazolin-3-one.
Claim 10
Dependent Claim 45 words
A composition as claimed in any one of claims 1 to 9 which contains from one part by weight of component (a) or of component (b) or component (c) and up to 2000 parts by weight of component (b) or component (c) or component (a).
Claim 11
Dependent Claim 27 words
A composition as claimed in any one of claims 1 to 10 wherein the sum of the fractional inhibitory concentration of the components is less than 0.7.
Claim 12
Dependent Claim 17 words
A composition as claimed in any one of claims 1 to 11 which additionally includes a carrier.
Claim 13
Independent Claim 34 words
A medium which is susceptible to attack by micro-organisms and which contains from 0.00001 to 10% by weight of the medium of a composition as claimed in any one of claims 1 to 12.
Claim 14
Dependent Claim 52 words
A medium as claimed in claim 13 which is selected from a cooling water system, a paper mill liquor, a metal working fluid, a geological drilling lubricant, a polymer emulsion, a paint, a lacquer, a varnish, a hydrocarbon fluid, an adhesive, a dyestuff or ink formulation, an agrochemical formulation, leather or wood.
Claim 15
Independent Claim 31 words
A method for inhibiting the growth of micro-organisms on, or in, a medium, which comprises treating the medium with a composition as claimed in any one of claims 1 to 12.
Claim 16
Independent Claim 44 words
A method for inhibiting the growth of micro-organisms on, or in, a medium, which comprises treating the medium with component (a) and component (b) sequentially, wherein a) is at least one 4,5-polymethylene-4-isothiazolin-3-one or a derivative thereof, and b) is at least one 2-halo-2-halomethyl glutaronitrile.
Claim 17
Independent Claim 55 words
A method for inhibiting the growth of micro-organisms on, or in, a medium which comprises treating the medium with component (a) and component (c) sequentially, wherein a) is at least one 4,5-polymethylene-4-isothiazolin-3-one or a derivative thereof, and c) is at least one isothiazolin-3-one which does not contain a fused ring attached to the isothiazole ring.
Claim 18
Independent Claim 60 words
A method as claimed in any one of claims 15 to 17 wherein the medium which is treated is a cooling water system, a paper mill liquor, a metal working fluid, a geological drilling lubricant, a polymer emulsion, a paint, a lacquer, a varnish, a hydrocarbon fluid, an adhesive, a dyestuff or ink formulation, an agrochemical formulation, leather or wood.

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