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EP0433950A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Thermally assisted method of transferring small electrostatographic toner particles to a thermoplastic bearing receiver

Assignee: Eastman Kodak Co
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Filing: 1990-12-17
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Granted: —
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Expires: 2010-12-17
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Abstract

Abstract The invention provides a method of non-electrostatically transferring dry toner particles which comprise a toner binder and which have a particle size of less than 8 micrometers from the surface of an element to a receiver which comprises a substrate having a coating of a thermoplastic polymer on a surface of the substrate characterized in (A) contacting the toner particles on the surface of an element which has a surface layer which comprises a film-forming, electrically insulating polyester or polycarbonate thermoplastic polymeric resin matrix and a surface energy of not greater than 47 dynes/cm, preferably from 40 to 45 dynes/cm, with said thermoplastic polymer coating on the receiver wherein the thermoplastic polymer is a thermoplastic condensation polymer having a Tg which is less than 10°C above the Tg of the toner binder and the surface energy of the thermoplastic polymer coating is 38 to 43 dynes/cm. (B) heating the receiver to a temperature such that the temperature of the thermoplastic polymer coating on the receiver during the transferring is at least 5°C above the Tg of the thermoplastic polymer; and (C) separating the receiver from the element at a temperature above the Tg of the thermoplastic polymer, whereby virtually all of the toner particles are transferred from the surface of the element to the thermoplastic polymer coating on the receiver in the sence of a layer or a coating of a release agent on the thermoplastic polymer coating or on the element. The method is particularly well suited for providing image having high resolution and low ganularity from very small size toner particles.

Inventors

  • 👤 William A. C/O Eastman Kodak Company Light
  • 👤 Donald S. C/O Eastman Kodak Company Rimai
  • 👤 Louis J. C/O Eastman Kodak Company Sorriero

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 12:31
CPC Classifications
G; G03; G03G; G03G7/00; G03G7/0006; G03G13/00; G03G13/26; G03G7/002; G03G7/0026; G03G7/0046

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 211 words
A method of non-electrostatically transferring dry toner particles which comprise a toner binder and which have a particle size of less than 8 micrometers from the surface of an element to a receiver which comprises a substrate having a coating of a thermoplastic polymer on a surface of the substrate characterized in (A) contacting said toner particles on said surface of an element which has a surface layer which comprises a film-forming, electrically insulating polyester or polycarbonate thermoplastic polymeric resin matrix and a surface energy of not greater than 47 dynes/cm with said thermoplastic polymer coating on said receiver wherein said thermoplastic polymer is a thermoplastic condensation polymer having a Tg which is less than 10°C above the Tg of the toner binder and the surface energy of said thermoplastic polymer coating is 38 to 43 degrees/cm; (B) heating said receiver to a temperature such that the temperature of said thermoplastic polymer coating on said receiver during said transferring is at least 5°C above the Tg of said thermoplastic polymer; and (C) separating said receiver from said element at a temperature above the Tg of said thermoplastic polymer, whereby virtually all of said toner particles are transferred from the surface of said element to said thermoplastic polymer coating on said receiver.
Claim 2
Dependent Claim 17 words
The process of claim 1 wherein said thermoplastic condensation polymer has a Tg of 40°C to 80°C.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein said thermoplastic condensation polymer has a weight average molecular weight of 20,000 to 500,000.
Claim 4
Dependent Claim 263 words
The process of claim 1 wherein said thermoplastic condensation polymer is a polyester and is selected from the group consisting of: (a) polyesters having recurring units derived from at least one dicarboxylic acid component and at least one diol component wherein said dicarboxylic acid component is selected from the group consisting of an aromatic dicarboxylic acid component wherein said aromatic dicarboxylic acid component is a terephthalic acid component, an isophthalic acid component or a naphthalene dicarboxylic acid component; a linear aliphatic dicarboxylic acid component having the formula: HO₂C-R-CO₂H wherein R is an alkyl group or an alkylene group having from 2 to 20 carbon atoms; or a cycloaliphatic dicarboxylic acid component having the formula: HO₂C-R₁-CO₂H wherein R₁ is a cycloaliphatic group having from 4 to 6 carbon atoms, and said diol component is a symmetrical linear alkylene diol having the formulas: wherein R₃ is an alkylene group having from 1 to 9 carbon atoms and R₄ is an alkylene group having from 2 to 7 carbon atoms, and X is oxygen or sulfur, and (b) polyester copolymers having recurring units derived from at least one dicarboxylic acid component and at least one diol component, at least one of said acid or said diol components being a mixture of at least two different acids or two different diols, respectively, so that a copolyester is obtained, and at least one of said acid components is selected from the group of acid components as defined above and at least one of said diol components is selected from the group of said diol components as defined above.
Claim 5
Dependent Claim 11 words
The process of claim 4 wherein said polyester is poly(2,2-oxydiethylene-co-ethylene terephthalate).
Claim 6
Dependent Claim 10 words
The process of claim 4 wherein said polyester is poly(butylene-cyclohexanoate-co-terephthalate).
Claim 7
Dependent Claim 10 words
The process of claim 4 wherein said polyester is poly(butylene-co-hexamethylene-isophthalate-co-terephthalate).
Claim 8
Dependent Claim 16 words
The process of claim 1 wherein said toner binder has a Tg of 40°C to 120°C.
Claim 9
Dependent Claim 30 words
The process of claim 1 wherein said toner particles are transferred to said receiver from a photoconductive element having a surface layer which comprises a polyester thermoplastic polymeric resin matrix.
Claim 10
Dependent Claim 30 words
The process of claim 1 wherein said toner particles are transferred to said receiver from a photoconductive element having a surface layer which comprises a polycarbonate thermoplastic polymeric resin matrix.
Claim 11
Dependent Claim 12 words
The process of claim 9 wherein said polyester resin is poly[4,4'-(2-norbornylidene)bisphenoxy azelate-co-terephthalate].
Claim 12
Dependent Claim 12 words
The process of claim 10 wherein said polycarbonate resin is poly[4,4'-(2-isopropylidene)-bisphenoxy carbonate].

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