EP0420593A2
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EP
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Terminal-modified imide oligomer composition
Assignee: Ube Corp
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Filing: 1990-09-25
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Granted: —
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Expires: 2010-09-25
Abstract
Abstract A terminal-modified imide oligomer composition, comprising (A) 100 parts by weight of a terminal-modified imide oligomer obtained by a reaction in a solvent of a biphenyltetracarboxylic acid compound with an aromatic diamine compound and a monoamine compound containing a carbon-carbon triple bond, and having an unsaturated terminal group at the terminal of the oligomer and an imide bond in the oligomer, and having a logarithmic viscosity number at 30°C, as determined at a concentration of 0.5 g/100 ml of N-methyl-2-pyrrolidone as a solvent, of from 0.1 to 1 and; (B) 5 to 180 parts by weight of an unsaturated imide compound obtained by a reaction in a solvent of a substituent-containing nadic anhydride with a monoamine compound having a carbon-carbon triple bond in an equimolar ratio, and having an unsaturated terminal group at the terminal thereof and an imide bond therein.
Inventors
- 👤 Shinji C/O Ube Industries Ltd. Yamamoto
- 👤 Hideho C/O Ube Industries Ltd. Tanaka
- 👤 Kazuyoshi C/O Ube Industries Ltd. Fujii
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-04 01:45
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/02; C08F290/06; C08F290/065; C08F290/08; C08F290/14; C08F290/145; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1003; C08G73/1007; C08G73/101; C08G73/1017
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
137 words
A terminal-modified imide oligomer composition comprising: (A) 100 parts by weight of a terminal-modified imide oligomer produced by reacting in a solvent, a biphenyltetracarboxylic acid compound with an aromatic diamine compound and a monoamine compound having a carbon-carbon triple bond and having (i) an unsaturated terminal group at the terminal of the oligomer, (ii) an imide bond in the oligomer, and (iii) a logarithmic viscosity number at 30°C, as determined at a concentration of 0.5 g/100 ml of N-methyl-2-pyrrolidone as a solvent, of 0.1 to 1 and; (B) 5 to 180 parts by weight of an unsaturated imide compound produced by reacting, in a solvent, a substituent-containing nadic anhydride with a monoamine compound having a carbon-carbon triple bond in an equimolar ratio and having an unsaturated terminal group at the terminal thereof and an imide bond therein.
Claim 2
Dependent Claim
137 words
A terminal-modified imide oligomer composition comprising: (A) 100 parts by weight of a terminal-modified imide oligomer produced by reacting in a solvent, a biphenyltetracarboxylic acid compound with an aromatic diamine compound and a monoamine compound having a carbon-carbon triple bond and having (i) an unsaturated terminal group at the terminal of the oligomer, (ii) an imide bond in the oligomer, and (iii) a logarithmic viscosity number at 30°C, as determined at a concentration of 0.5 g/100 ml of N-methyl-2-pyrrolidone as a solvent, of 0.1 to 1 and; (B) 5 to 180 parts by weight of an unsaturated imide compound produced by reacting, in a solvent, a substituent-containing nadic anhydride with a monoamine compound having a carbon-carbon triple bond in an equimolar ratio and having an unsaturated terminal group at the terminal thereof and an imide bond therein.
Claim 3
Dependent Claim
21 words
A composition as claimed in claim 1, wherein said terminal-modified imide oligomer (A) has a softening point of 100°C to 300°C.
Claim 4
Dependent Claim
22 words
A composition as claimed in claim 1, wherein said terminal-modified imide oligomer (A) has a logarithmic viscosity number of 0.2 to 0.8.
Claim 5
Dependent Claim
39 words
A composition as claimed in claim 1, wherein said biphenyltetracarboxylic acid is at least one compound selected from the group consisting of 3,3′,4,4′-biphenyltetracarboxylic acid, 3,3′,4,4′-biphenyltetracarboxylic dianhydride (s-BPDA), 2,3,3′,4′-biphenyltetracarboxylic acid, 2,3,3′,4′-biphenyltetracarboxylic dianhydride (a-BPDA) and lower alcohol esters and salts thereof.
Claim 6
Dependent Claim
90 words
A composition as claimed in claim 1, wherein said aromatic diamine compound is at least one compound selected from the group consisting of phenylene diamine type diamine compounds, xylylene type diamine compounds, trialkylbenzene type diamine compounds, benzidine type diamine compounds, diphenyl ether type diamine compounds, diphenyl thioether type diamine compounds, benzophenone type diamine compounds, diphenyl sulfine type diamine compounds, diphenyl sulfide type diamine compounds, diphenyl sulfone type diamine compounds, diphenyl alkane type diamine compounds, bis(phenoxy)benzene type diamine compounds, bis (phenoxy)phenyl propane type diamine compounds, and bis(phenoxy)diphenyl sulfone type diamine compounds.
Claim 7
Dependent Claim
54 words
A composition as claimed in claim 1, wherein said monoamine compound having a carbon-carbon triple bond to be used in the production of the terminal-modified imide oligomer (A) is at least one compound selected from the group consisting of aliphatic and aromatic monoamine compounds having both a carbon-carbon triple bond and a monoamino group.
Claim 8
Dependent Claim
37 words
A composition as claimed in claim 1, wherein said unsaturated imide compound(B) has a logarithmic viscosity number at 30°C, as determined at a concentration of 0.5 g/100 ml of N-methyl-2-pyrrolidone as a solvent, of 0.005 to 0.09.
Claim 9
Dependent Claim
54 words
A composition as claimed in claim 1, wherein said monoamine compound having a carbon-carbon triple bond to be used in the production of the unsaturated imide compound (B) is at least one compound selected from the group consisting of aliphatic and aromatic monoamine compounds having both a carbon-carbon triple bond and a monoamino group.
Claim 10
Dependent Claim
70 words
A composition as claimed in claim 1, wherein said substituent-containlng nadic anhydride is at least one compound selected from the group consisting of nadic anhydrides substituted with an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a halogenated hydrocarbon group having 1 to 6 carbon atoms and 1 to 5 halogen atoms, or halogen group positioned at the 5- or 6-position.
References Cited (Backward Citations)
No citation records indexed.
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