EP0409580A2
Expired / Lapsed
EP
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Thermoplastic elastomer composition
Assignee: JSR Corp
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Filing: 1990-07-17
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Granted: —
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Expires: 2010-07-17
Abstract
Abstract A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhydride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by eight of at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer. The above thermopalstic elastomer composition has properties comparable to a vulcanized rubber and is useful in various industrial parts.
Inventors
- 👤 Takateru Imai
- 👤 Masanobu Nagano
- 👤 Masaaki Mawatari
- 👤 Toshio Teramoto
- 👤 Minoru Hasegawa
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-06 13:28
CPC Classifications
C; C08; C08L; C08L53/00; C08L53/005; C08C; C08C19/00; C08C19/02; C08L21/00; C08L51/00; C08L51/006; C08L53/02; C08L53/025; C08L67/00; C08L67/02; C08L9/00; C08L77/00; C08L9/06
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
219 words
A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (d) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhdyride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by weight of (ii) at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer.
Claim 2
Dependent Claim
219 words
A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (d) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhdyride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by weight of (ii) at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer.
Claim 3
Dependent Claim
55 words
The thermoplastic elastomer composition according to Claim 1, wherein component (ii) is a rubbery polymer and at least 10% of the rubbery polymer has been allowed to get by subjecting a mixture of component (i) or (i′), component (ii) and a crosslinking agent for component (ii) to reaction while applying shear deformation to the mixture.
Claim 4
Dependent Claim
76 words
The thermoplastic elastomer composition according to Claim 1, wherein component (ii) is a mixture of at least 10% by weight of the thermoplastic resin and the rubbery polymer, and at least 10% by weight of a total amount of component (i) or (i′) and the rubbery polymer has been allowed to gel by subjecting component (i) or (i′) and component (ii) to reaction in the presence of a crosslinking agent while applying shear deformation to them.
Claim 5
Dependent Claim
67 words
The thermoplastic elastomer composition according to Claim 1, wherein the amount of component (i) or (i′) is 10-90 parts by weight and component (ii) is 90-10 parts by weight of a polyolefin resin, and which further contains (iii) a non-aromatic process oil in a proportion of 1-300 parts by weight per 100 parts by weight of a total amount of component (i) or (i′) and component (ii).
Claim 6
Dependent Claim
55 words
The thermoplastic elastomer composition according to Claim 4, wherein at least 10% by weight of component (i) or (i′) has been allowed to gel by subjecting component (i) or (i′), component (ii) and component (iii) to reaction in the presence of a crosslinking agent for component (i) or (i′) while applying shear deformation to them.
Claim 7
Dependent Claim
83 words
The thermoplastic elastomer composition according to Claim 1, wherein the amount of component (i) or (i′) is 5-95 parts by weight and component (ii) is 95-5 parts by weight of a mixture consisting of 10-90% by weight of a polyolefin resin and 90-10% by weight of an olefinic copolymer rubber and which further contains (iii) a non-aromatic process oil in a proportion of 1-400 parts by weight per 100 parts by weight of a total of component (i) or (i′) and component (ii).
Claim 8
Dependent Claim
58 words
The thermoplastic elastomer composition according to Claim 6, wherein at least 10% by weight of the olefinic copolymer rubber of component (ii) has been allowed to gel by subjecting component (i) or (i′), component (ii) and component (iii) to reaction in the presence of a crosslinking agent for the olefinic copolymer rubber while applying shear deformation to them.
Claim 9
Dependent Claim
141 words
The thermoplastic elastomer composition according to Claim 1, wherein the amount of component (i) or (i′) is 5-95 parts by weight and component (ii) is 95-5 parts by weight of (A) an olefinic polymer having graft-copolymerized thereon at least one member selected from the group consisting of a carboxylic acid derivative and an epoxy derivative or the olefinic polymer having bonded thereto another polymer in the graft or block form and (B) at least one member selected from the group consisting of a polyamide polymer and a polyester polymer [provided that the amount of (A) component is not more than 50% by weight of the weight of component (ii)] and which further contains (iii′) a softening agent in a proportion of 0-400 parts by weight per 100 parts by weight of a total of component (i) or (i′) and component (ii).
Claim 10
Dependent Claim
172 words
A modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhdyride group, hydroxyl group, epoxy group, halogen atom and amino group has been added to a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the polybutadiene block segment (C), D means the block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the block copolymer having been hydrogenated.
Claim 11
Dependent Claim
172 words
A modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhdyride group, hydroxyl group, epoxy group, halogen atom and amino group has been added to a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the polybutadiene block segment (C), D means the block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the block copolymer having been hydrogenated.
References Cited (Backward Citations)
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