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EP0402546A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Printed circuit board

Assignee: Poly Flex Circuits Inc
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Filing: 1989-06-29
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Granted: —
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Expires: 2009-06-29
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Abstract

Abstract A method for producing a circuit board involves printing a U.V. curable ink (10) onto a substrate in a desired circuit pattern and curing the ink by exposing it to a pulsed U.V. source or subjecting the circuit pattern prepared from a U.V. curable ink (10) containing magnetite particles (12) to a magnetic field to move the magnetite particles (12) to the upper surface of the U.V. curable ink (10). Other embodiments include circuit boards made in accordance with these methods and the use of the U.V. curable ink as a shielding composition for enclosures housing electronic equipment.

Inventors

  • 👤 David Durand

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 14:32
CPC Classifications
H; H05; H05K; H05K3/00; H05K3/10; H05K3/12; H05K3/1283; C; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/101; C09D11/52; H01; H01B; H01B1/00; H01B1/20; H01B1/22; H01F; H01F41/00; H01F41/14; H01F41/16; H05K1/00; H05K1/02; H05K1/09; H05K1/092; H05K1/095; H05K3/22; H05K3/24; H05K3/245; H05K2201/00; H05K2201/08; H05K2201/083; H05K2203/00; H05K2203/10; H05K2203/104

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 101 words
A method for producing a circuit board having conductive circuit elements with a specific resistivity of less than .05 chm-cm patterned on a nonconductive substrate comprising: a) printing a U.V. curable ink onto the nonconductive substrate in a desired circuit pattern; and b) effecing U.V. radiation cure of the U.V. curable ink by exposing the U.V. curable ink to a U.V. source having an output in the reange of from 360 nm to 420 nm in a pulsing manner comprising 5 to 8 one-half second exposure periods, each exposure period followed by a non-exposure period of about 2 to 3 seconds.
Claim 2
Independent Claim 101 words
A method for producing a circuit board having conductive circuit elements with a specific resistivity of less than .05 chm-cm patterned on a nonconductive substrate comprising: a) printing a U.V. curable ink onto the nonconductive substrate in a desired circuit pattern; and b) effecing U.V. radiation cure of the U.V. curable ink by exposing the U.V. curable ink to a U.V. source having an output in the reange of from 360 nm to 420 nm in a pulsing manner comprising 5 to 8 one-half second exposure periods, each exposure period followed by a non-exposure period of about 2 to 3 seconds.
Claim 3
Dependent Claim 16 words
A method as claimed in claim 1 wherein the U.V. source is an electrodeless U.V. source.
Claim 4
Dependent Claim 20 words
A method as claimed in claim 2 wherein the electrodeless U.V. source is provided with iron oxide as a dopant.
Claim 5
Independent Claim 55 words
A method as claimed in any one of the preceding claims wherein the U.V. curable ink comprises from 30 to 33 weight percent of a thermosetting resin binder and from 70 to 67 weight percent of spherical or spheroidal conductive particles having a particle size distribution in the range of from 1 to 30 micrometres.
Claim 6
Dependent Claim 47 words
A method as claimed in claim 4 wherein the conductive particles comprise silver coated glass spheres, preferably having an average particle size of about 15 micrometres, wherein the silver comprises from 8 to 12 weight percent based on the total weight of the silver coated glass spheres.
Claim 7
Independent Claim 37 words
A method as claimed in any one of the preceding claims wherein the U.V. curable ink also includes an effective amount of a ketone-amine curing agent, preferably Michler's ketone or a mixture of benzophenone and Michler's ketone.
Claim 8
Dependent Claim 43 words
A U.V. curable ink comprising from 30 to 33 weight percent of a thermosetting resin binder and from 70 to 67 weight percent of spherical or spheroidal conductive particles having a particle size distribution in the range of from 1 to 30 micrometres.
Claim 9
Dependent Claim 43 words
A U.V. curable ink comprising from 30 to 33 weight percent of a thermosetting resin binder and from 70 to 67 weight percent of spherical or spheroidal conductive particles having a particle size distribution in the range of from 1 to 30 micrometres.
Claim 10
Dependent Claim 31 words
A U.V. curable ink as claimed in claim 7 which also contains an effective amount of a ketone-amine curing agent, preferably Michler's ketone or a mixture of benzophenone and Michler's ketone.
Claim 11
Dependent Claim 42 words
A U.V. curable ink as claimed in claim 7 or claim 8 wherein the conductive particles comprise silver coated glass spheres wherein the silver comprises from 8 to 12 weight percent based on the total weight of the silver coated glass spheres.
Claim 12
Dependent Claim 117 words
A printed circuit board comprising a substrate and at least one conductive line printed on the substrate, the line comprising a U.V. cured ink comprising from 30 to 33 weight percent of a thermosetting resin binder and from 70 to 67 weight percent of spherical or spheroidal conductive particles having a particle size distribution in the range of from 1 to 30 micrometres, the line having been cured by exposure to U.V. radiation emanating from an electrodeless source having an output in the range of from 360 nm to 420 nm in a pulsed manner comprising 5 to 8 one-half second exposure periods, each exposure period followed by a non-exposure period of about 2 to 3 seconds.
Claim 13
Dependent Claim 117 words
A printed circuit board comprising a substrate and at least one conductive line printed on the substrate, the line comprising a U.V. cured ink comprising from 30 to 33 weight percent of a thermosetting resin binder and from 70 to 67 weight percent of spherical or spheroidal conductive particles having a particle size distribution in the range of from 1 to 30 micrometres, the line having been cured by exposure to U.V. radiation emanating from an electrodeless source having an output in the range of from 360 nm to 420 nm in a pulsed manner comprising 5 to 8 one-half second exposure periods, each exposure period followed by a non-exposure period of about 2 to 3 seconds.
Claim 14
Dependent Claim 49 words
A printed circuit board as claimed in claim 10 wherein the conductive particles comprise silver coated glass spheres, preferably having an average particle size of about 15 micrometres, wherein the silver comprises from 8 to 12 weight percent based on the total weight of the silver coated glass spheres.
Claim 15
Dependent Claim 35 words
A printed circuit board as claimed in claim 11 wherein the U.V. curable ink also includes an effective amount of a ketone-amine curing agent, preferably Michler's ketone or a mixture of benzophenone and Michler's ketone.
Claim 16
Independent Claim 153 words
A method for producing a circuit board having conductive circuit elements with a specific resistivity of less than 0.05 ohm/cm 2 patterned on a non-conductive substrate comprising: a) printing a film of U.V. curable ink onto the non-conductive substrate in a desired circuit pattern, the U.V. curable ink comprising a suspension of a silver-coated magnetite particles in a U.V. curable resin; b) subjecting the resulting printed circuit pattern to a magnetic field sufficient to move the magnetite particles to a position at or near the upper surface of the resin without breaking the surface tension thereof or substantially increasing the thickness of the ink film from the substrate; and c) effecting a U.V. radiation cure of the U.V. curable ink by exposing the U.V curable ink to a U.V. source having an output in the range of from 360 nm to 420 nm for a time sufficient to cure the U.V. curable ink.
Claim 17
Independent Claim 153 words
A method for producing a circuit board having conductive circuit elements with a specific resistivity of less than 0.05 ohm/cm 2 patterned on a non-conductive substrate comprising: a) printing a film of U.V. curable ink onto the non-conductive substrate in a desired circuit pattern, the U.V. curable ink comprising a suspension of a silver-coated magnetite particles in a U.V. curable resin; b) subjecting the resulting printed circuit pattern to a magnetic field sufficient to move the magnetite particles to a position at or near the upper surface of the resin without breaking the surface tension thereof or substantially increasing the thickness of the ink film from the substrate; and c) effecting a U.V. radiation cure of the U.V. curable ink by exposing the U.V curable ink to a U.V. source having an output in the range of from 360 nm to 420 nm for a time sufficient to cure the U.V. curable ink.
Claim 18
Dependent Claim 24 words
A method as claimed in claim 13 wherein the U.V. curable ink comprises a mixture of a cycloaliphatic expoxy resin and a cationic photoinitiator.
Claim 19
Dependent Claim 24 words
A method as claimed in claim 13 wherein the U.V. curable resin also contains, as a plasticizer, a plasticizing amount of a polyether polyol.
Claim 20
Dependent Claim 32 words
A method as claimed in claim 13 wherein the U.V. curable ink contains 25 to 67 percent by volume silver coated magnetite spheres based on the total volume of the curable ink.
Claim 21
Dependent Claim 22 words
A U.V. curable ink comprising a suspension of silver coated magnetic particles in a cycloaliphatic epoxy resin binder and a cationic photoinitiator.
Claim 22
Dependent Claim 22 words
A U.V. curable ink comprising a suspension of silver coated magnetic particles in a cycloaliphatic epoxy resin binder and a cationic photoinitiator.
Claim 23
Dependent Claim 19 words
A U.V. curable ink as aimed in claim 17 which also includes a platicizing amount of a polyether polyol.
Claim 24
Dependent Claim 75 words
A printed circuit board comprising a substrate and at least one conductive line printed on the substrate, the line comprising a U.V. cured ink comprising a cycloaliphatic epoxy resin and silver- coated magnetite particles, the line having been subjected to a magnetic field sufficient to move the magnetic particles to a position at or near the upper surface of the line and cured by exposure to U.V. radiation in the presence of a cationic photoinitiator.
Claim 25
Dependent Claim 75 words
A printed circuit board comprising a substrate and at least one conductive line printed on the substrate, the line comprising a U.V. cured ink comprising a cycloaliphatic epoxy resin and silver- coated magnetite particles, the line having been subjected to a magnetic field sufficient to move the magnetic particles to a position at or near the upper surface of the line and cured by exposure to U.V. radiation in the presence of a cationic photoinitiator.
Claim 26
Dependent Claim 28 words
A printed circuit board as claimed in claim 19 wherein the U.V. curable ink is cured also in the presence of a plasticizing amount of a polyether polyol.
Claim 27
Independent Claim 86 words
A method of fabricating shielded plastic enclosure for housing electronic equipment comprising applying a layer to at least one interior surface of the enclosure of a shielding composition comprising a suspension of silver-coated magnetite particles in a U.V. curable resin and effecting a U.V. radiation cure of the U.V. curable shielding composition by exposing the U.V. curable shielding composition to a U.V. source having an output in the range of from 360 nm to 420 nm for a time sufficient to cure the U.V curable ink.
Claim 28
Independent Claim 86 words
A method of fabricating shielded plastic enclosure for housing electronic equipment comprising applying a layer to at least one interior surface of the enclosure of a shielding composition comprising a suspension of silver-coated magnetite particles in a U.V. curable resin and effecting a U.V. radiation cure of the U.V. curable shielding composition by exposing the U.V. curable shielding composition to a U.V. source having an output in the range of from 360 nm to 420 nm for a time sufficient to cure the U.V curable ink.
Claim 29
Dependent Claim 25 words
A method as claimed in claim 21 wherein the U.V. curable shielding composition comprises a mixture of a cycloalipatic epoxy resin and a cationic photoinitiator.
Claim 30
Dependent Claim 27 words
A method as-claimed in claim 21 or claim 22 wherein the U.V. curable shielding composition also contains, as a plasticizer, a plasticizing amount of a polyether polyol.
Claim 31
Independent Claim 38 words
A method as claimed in any one of claims 21 to 23 wherein the U.V. curable shielding composition contains 25 to 67 percent by volume silver-coated magnetite spheres based on the total volume of the curable shielding composition.
Claim 32
Dependent Claim 48 words
A shielded plastic enclosure for housing electronic equipment having at least one interior surface thereof provided with a U.V. cured shielding composition comprising a cycloaliphatic epoxy resin and silver-coated magnetite particles, the composition having been cured by exposure to U.V radiation in the presence of a cationic photoinitiator.
Claim 33
Dependent Claim 48 words
A shielded plastic enclosure for housing electronic equipment having at least one interior surface thereof provided with a U.V. cured shielding composition comprising a cycloaliphatic epoxy resin and silver-coated magnetite particles, the composition having been cured by exposure to U.V radiation in the presence of a cationic photoinitiator.

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