← Back to Patent Explorer
EP0400531A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

A method for the preparation of destructured-starch-based compositions produced thereby

Assignee: Novamont SpA
•
Filing: 1990-05-28
•
Granted: —
•
Expires: 2010-05-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract In order to prepare a starch-based composition usable for the production of articles of biodegradable plastics material, a starch is mixed in a heated extruder with a high-boiling plasticizer and a destructuring agent for a time sufficient to cause the starch to be destructured, in dependence on the destructuring agent used, at a tempera­ture below the boiling point of the plasticizer used and between 120 and 170°C. The composition thus obtained is particularly suitable for the formulation of polymer mixtures with polymers which have relatively high melting points, since it can be processed at temperatures higher than 120°C and is suit­able for extrusion at low pressure with these polymers. In particular, compositions thus obtained and mixed with polyvinyl alcohol and/or ethylene vinyl alcohol are suitable for the formation of films by blow-extrusion, since they have the desired characteristics of mechanical strength and resistance to tearing and perforation, or for the formation of articles finished by injection moulding, thermoforming or blowing.

Inventors

  • 👤 Catia Bastioli
  • 👤 Roberto Lombi
  • 👤 Gianfranco Del Tredici
  • 👤 Italo Guanella

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-28 21:06
CPC Classifications
C; C08; C08B; C08B30/00; C08B30/12; B; B29; B29C; B29C48/00; B29C48/022; C08L; C08L3/00; C08L3/02; B29C48/03; B29C48/04; B29C48/07; B29C48/08

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 81 words
A method for the preparation of a destructured-­starch-based composition usable for the production of articles of biodegradable plastics material, including the step of mixing starch as it is, in a heated extruder, with a high-boiling plasticizer and a destructuring agent selected from the group consisting of urea, alkaline and alkaline-earth hydroxides, and mixtures thereof for a time sufficient to bring about destructuring of the starch and at a temperature below the boiling point of the plasticizer and between 120 and 170°C.
Claim 2
Independent Claim 81 words
A method for the preparation of a destructured-­starch-based composition usable for the production of articles of biodegradable plastics material, including the step of mixing starch as it is, in a heated extruder, with a high-boiling plasticizer and a destructuring agent selected from the group consisting of urea, alkaline and alkaline-earth hydroxides, and mixtures thereof for a time sufficient to bring about destructuring of the starch and at a temperature below the boiling point of the plasticizer and between 120 and 170°C.
Claim 3
Dependent Claim 28 words
A method according to Claim 1, in which the plasticizer is selected from the group consisting of glycerine, polyethylene glycol, ethylene glycol, propylene glycol, sorbitol, and mixtures thereof.
Claim 4
Dependent Claim 30 words
A method according to Claim 1 or Claim 2, in which the quantity of plasticizer added to the starch is from 0.05 to 100% of the weight of the starch.
Claim 5
Independent Claim 32 words
A method according to any one of Claims 1 to 3, in which the quantity of plasticizer added to the starch is from 20 to 100% of the weight of the starch.
Claim 6
Independent Claim 44 words
A method according to any one of Claims 1 to 4, in which the mixing operation is carried out with the addi­tion of a quantity of an ethylene/acrylic acid and/or polyvinyl alcohol copolymer of up to 15% of the total weight of the mixture.
Claim 7
Independent Claim 31 words
A method according to any one of the preceding claims, in which the starch used is a natural starch which is not dried beforehand and to which water is not added.
Claim 8
Independent Claim 34 words
A method according to any one of the preceding claims, in which the destructuring agent is constituted by urea added in a proportion of from 2 to 20% of the weight of the starch.
Claim 9
Independent Claim 20 words
A method according to any one of the preceding claims, in which the destructuring agent is constituted by sodium hydroxide.
Claim 10
Dependent Claim 22 words
A method according to Claim 5, in which the mixing of the starch is carried out with the addition of ammonium hydroxide.
Claim 11
Independent Claim 45 words
A method according to any one of the preceding claims, including the addition to the starch of additives selected from the group consisting of UV stabilisers, flameproofing agents, cross-linking agents, fungicides, herbicides, antioxidants, fertilisers, opacifiers, and stabilisers which do not interfere with the destructuring process.
Claim 12
Dependent Claim 16 words
A destructured-starch-based composition obtainable by a method according to any one of Claims 1 to 10.

References Cited (Backward Citations)

EP0032802A1 Cited
EP0118240A2 Cited
EP0282451A2 Cited

USPTO Annuity & Maintenance Windows

Maintenance schedule is calculated for granted US utility patents.

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag