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EP0396085A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Catalyst for purification of exhaust gases

Assignee: Toyota Motor Corp
•
Filing: 1990-04-30
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Granted: —
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Expires: 2010-04-30
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Abstract

Abstract A catalyst used for purifying exhaust gases resulting from the combustion of a lean fuel-air mixture mixture comprises a porous support material having a framework formed by MO2, where M is silicon or a metal, AlO2 and PO2, and at least one base metal and at least one metal of the platinum group which are carried on the support material. The catalyst exhibits a high level of NOx conversion for a long time even at a high temperature owing to the high heat resistance and durability of the support material, and the cooperative action of the two kinds of metals, i.e. the promotion of the catalytic action of the base metal (e.g. copper) by the metal of the platinum group (e.g. palladium) serving as a cocatalyst.

Inventors

  • 👤 Yoshihide Watanabe
  • 👤 Mareo Kimura
  • 👤 Shinichi Matsumoto

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 05:48
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01J; B01J27/00; B01J27/14; B01J27/185; B01J27/1856; B01J27/186; B01J29/00; B01J29/82; B01J29/84; B01J29/85; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 67 words
A catalyst for purifying exhaust gases compris­ing: a porous support material having a framework comprising MO₂, where M is an element selected from silicon and a metal selected from the group consisting of Mg, Mn, Zn, Co, Fe, and Ti, AlO₂ and PO₂; and catalytically active elements comprising at least one base metal and at least one metal of the platinum group, carried on said support material.
Claim 2
Dependent Claim 67 words
A catalyst for purifying exhaust gases compris­ing: a porous support material having a framework comprising MO₂, where M is an element selected from silicon and a metal selected from the group consisting of Mg, Mn, Zn, Co, Fe, and Ti, AlO₂ and PO₂; and catalytically active elements comprising at least one base metal and at least one metal of the platinum group, carried on said support material.
Claim 3
Dependent Claim 15 words
The catalyst as set forth in claim 1, wherein said support material comprises crystalline silicoaluminophos­phate.
Claim 4
Dependent Claim 15 words
The catalyst as set forth in claim 1, wherein said support material comprises crystalline metalloalumino­phosphate.
Claim 5
Dependent Claim 23 words
The catalyst as set forth in claim 1, wherein said support material has uniformly sized pores with a nominal diameter exceeding 3 Å.
Claim 6
Dependent Claim 18 words
The catalyst as set forth in claim 4, wherein said nominal diameter is Between 5 and 10 Å.
Claim 7
Dependent Claim 53 words
The catalyst as set forth in claim 1, wherein said support material is of the chemical composition represented mainly by the empirical formula: (Si x Al y P z )O₂ where x + y + z = 1, 0.01 ≦ x < 0.8, and 0.01 ≦ z, when it is an anhydrous compound.
Claim 8
Dependent Claim 22 words
The catalyst as set forth in claim 1, wherein said at least one base metal is selected from the 3d transition metals.
Claim 9
Dependent Claim 32 words
The catalyst as set forth in claim 1, wherein said at least one metal of the platinum group is selected from the group consisting of Pd, Pt, Rh, Ir, Ru and Re.
Claim 10
Dependent Claim 23 words
The catalyst as set forth in claim 1, wherein said base metal is copper, while said metal of the platinum group is palladium.
Claim 11
Dependent Claim 28 words
The catalyst as set forth in claim 9, wherein said support material carries said palladium in an amount rang­ing from 10 to 50% by weight of said copper.
Claim 12
Dependent Claim 36 words
The catalyst as set forth in claim 1, wherein said base metal and said metal of the platinum group are so located on said support material as to be capable of per­forming a cooperative catalytic action.
Claim 13
Dependent Claim 31 words
The catalyst as set forth in claim 11, wherein said base metal and said metal of the platinum group form a mixture in which they exist alternately in a random pattern.
Claim 14
Dependent Claim 39 words
The catalyst as set forth in claim 11, wherein said base metal and said metal of the platinum group form a two-layer structure in which particles of one of said metals cover the surfaces of particles of the other.

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