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EP0393358A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for producing homogeneous aluminoxane solution

Assignee: Idemitsu Kosan Co Ltd
•
Filing: 1990-03-17
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Granted: —
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Expires: 2010-03-17
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Abstract

Abstract The present invention provides a process for producing a homogeneous aluminoxane solution wherein an alkylaminoxane (A) obtained by reacting an organoaluminum compound with water and removing a solid residue by filtration is reacted with an organoaluminum compound (C) in the presence of an aromatic hydrocarbon solvent (B). According to the present invention, the gel-free homogeneous aluminoxane solution can be obtained and the catalytic activity thereof is not deteriorated during the storage.

Inventors

  • 👤 Norio Tomotsu
  • 👤 Masahiko Kuramoto

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 21:53
CPC Classifications
C; C07; C07F; C07F5/00; C07F5/06; C07F5/061; C07F5/066; C07F5/068; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 45 words
A process for producing a homogeneous aluminoxane solution characterized in that an alkylaminoxane (A) ob­tained by reacting an organoaluminum compound with water and removing a solid residue by filtration is reacted with an organoaluminum compound (C) in the presence of an aromatic hydrocarbon solvent (B).
Claim 2
Dependent Claim 45 words
A process for producing a homogeneous aluminoxane solution characterized in that an alkylaminoxane (A) ob­tained by reacting an organoaluminum compound with water and removing a solid residue by filtration is reacted with an organoaluminum compound (C) in the presence of an aromatic hydrocarbon solvent (B).
Claim 3
Dependent Claim 26 words
A process according to Claim 1 wherein the alkyl­aluminoxane (A) is methylaluminoxane having a molecular weight determined by cryoscopic method with benzene of 500 to 4,000.
Claim 4
Dependent Claim 20 words
A process according to Claim 1 wherein the organo­aluminum compound used in the preparation of the alkyl­aluminoxane (A) is trialkylaluminum.
Claim 5
Dependent Claim 18 words
A process according to Claim 1 wherein the aromatic hydrocarbon solvent is benzene, toluene, ethylbenzene, xylene or cumene.
Claim 6
Dependent Claim 20 words
A process according to Claim 1 wherein the organo­aluminum compound (C) is an organoaluminum compound having a branched alkyl group.
Claim 7
Dependent Claim 30 words
A process according to Claim 1 wherein the molar ratio of the organoaluminum compound (C) to the alkyl­aluminoxane (A) to be reacted is 0.01/1 to 1/1 (in terms of aluminum).
Claim 8
Dependent Claim 30 words
A process according to Claim 1 wherein the molar ratio of the organoaluminum compound (C) to the alkyl­aluminoxane (A) to be reacted is 0.01/1 to 0.4/1 (in terms of aluminum).
Claim 9
Dependent Claim 30 words
A process according to Claim 1 wherein the molar ratio of the organoaluminum compound (C) to the alkyl-­aluminoxane (A) to be reacted is 0.01/1 to 0.09/1 (in terms of aluminum).
Claim 10
Dependent Claim 32 words
A process according to Claim 1 wherein the concentra­tion of the organoaluminum compound (C) and the alkyl­aluminoxane (A) in the aromatic hydrocarbon solvent is 0.01 to 5 mol/ℓ (in terms of aluminum).

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