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EP0389927A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Epoxysiloxane cure promoters and accelerators for cationic UV cure systems

Assignee: General Electric Co
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Filing: 1990-03-20
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Granted: —
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Expires: 2010-03-20
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Abstract

Abstract Photopolymerizable coating compositions are described which comprise an organic cycloaliphatic polyepoxide in admixture with a cure accelerating amount of a low molecular weight alpha, omega-cycloaliphatic epoxy-functional siloxane which, when photocured using an onium salt photoinitiator, require less energy to cure, and thus coatings utilizing these compositions may be cured more rapidly under the same conditions than can compositions containing only the organic cycloaliphatic polyepoxide.

Inventors

  • 👤 Richard Paul Eckberg
  • 👤 Karen Dorothy Riding

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 17:00
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/24; C09; C09D; C09D163/00; C08G59/68; C08G77/00; C08G77/04; C08G77/045

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 63 words
A photopolymerizable cycloaliphatic epoxy coating composition comprising a cure accelerating amount of a cycloaliphatic epoxy-functional siloxane having the nominal formula R′R₂SiO(R₂SiO) x SiR₂R′ where each R individually is a lower alkyl radical having from 1 to 8 carbon atoms, R′is a monovalent organic cycloaliphatic epoxy-functional radical having from 2 to 20 carbon atoms, and x has a value from 0 to about 16.
Claim 2
Dependent Claim 63 words
A photopolymerizable cycloaliphatic epoxy coating composition comprising a cure accelerating amount of a cycloaliphatic epoxy-functional siloxane having the nominal formula R′R₂SiO(R₂SiO) x SiR₂R′ where each R individually is a lower alkyl radical having from 1 to 8 carbon atoms, R′is a monovalent organic cycloaliphatic epoxy-functional radical having from 2 to 20 carbon atoms, and x has a value from 0 to about 16.
Claim 3
Dependent Claim 80 words
A photopolymerizable coating composition comprising: (a) an organic cycloaliphatic polyepoxide; (b) a cure accelerating quantity of a cycloaliphaticepoxy-functional siloxane having the nominal formula R′R₂SiO(R₂SiO) x SiR₂R′ where each R individually is a lower alkyl radical having from 1 to 8 carbon atoms, R′ is a monovalent organic cycloaliphatic epoxy-functional radical having from 2 to 20 carbon atoms, and x has a value from zero to about 16; and (c) a catalytic amount of a photocatalyst or a combination of photocatalysts.
Claim 4
Dependent Claim 80 words
A photopolymerizable coating composition comprising: (a) an organic cycloaliphatic polyepoxide; (b) a cure accelerating quantity of a cycloaliphaticepoxy-functional siloxane having the nominal formula R′R₂SiO(R₂SiO) x SiR₂R′ where each R individually is a lower alkyl radical having from 1 to 8 carbon atoms, R′ is a monovalent organic cycloaliphatic epoxy-functional radical having from 2 to 20 carbon atoms, and x has a value from zero to about 16; and (c) a catalytic amount of a photocatalyst or a combination of photocatalysts.
Claim 5
Dependent Claim 9 words
The composition of claim 2 wherein R is methyl.
Claim 6
Dependent Claim 14 words
The composition of claim 2 wherein the photocatalyst is an aromatic iodonium complex salt.
Claim 7
Dependent Claim 14 words
The composition of claim 2 wherein the value of x is less than 10.
Claim 8
Dependent Claim 13 words
The composition of claim 2 wherein R is methyl and R′ is 3,4-epoxycyclohexyl-1-ethyl.
Claim 9
Dependent Claim 18 words
The composition of claim 2 wherein R is methyl and the value of x is less than 10.
Claim 10
Dependent Claim 16 words
The composition of claim 2 wherein R is methyl and the value of x is zero.

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