EP0389084A2
Expired / Lapsed
EP
⏱️ 0.0 years remaining
Process for producing a polyborosilazane
Assignee: Tonen General Sekiyu KK
•
Filing: 1990-01-23
•
Granted: —
•
Expires: 2010-01-23
Abstract
Abstract Disclosed is a polyborosilazane having a B/Si atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to about 500,000 which can be pyrolyzed to give ceramics. The polyborosilazane is produced by reacting a polysilazane having a number-average molecular weight of about 100 to about 50,000 with a boron compound.
Inventors
- 👤 Osamu Funayama
- 👤 Mikiro Arai
- 👤 Yuuji Tashiro
- 👤 Takeshi Isoda
- 👤 Kiyoshi Sato
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-04 21:18
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/48; C08G77/56; C08G77/60; C08G77/62; C08G79/00; C08G79/08
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
199 words
A polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to 500,000 and containing (a) skeletal groups of a recurring unit represented by the general formula: wherein R¹, R² and R³, independently from each other, represent hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R¹, R² and R³ is hydrogen and (b) at least one cross-linkage which cross-links said skeletal groups and which is selected from the group consisting of: wherein R⁶ represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group and R⁷ represents a residue bound to the nitrogen atom of R⁶ having a nitrogen atom, and wherein at least two of the six bonds of the group (iv) are used for the crosslinkage with the remaining bond or bonds, if any, being linked to hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group.
Claim 2
Dependent Claim
199 words
A polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to 500,000 and containing (a) skeletal groups of a recurring unit represented by the general formula: wherein R¹, R² and R³, independently from each other, represent hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R¹, R² and R³ is hydrogen and (b) at least one cross-linkage which cross-links said skeletal groups and which is selected from the group consisting of: wherein R⁶ represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group and R⁷ represents a residue bound to the nitrogen atom of R⁶ having a nitrogen atom, and wherein at least two of the six bonds of the group (iv) are used for the crosslinkage with the remaining bond or bonds, if any, being linked to hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group.
Claim 3
Dependent Claim
170 words
A process for producing a polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to 500,000, which comprises reacting a polysilazane having a number-average molecular weight of about 100 to about 50,000 and containing a skeletal structure of a recurring unit represented by the general formula (I): wherein R¹, R² and R³, independently from each other, represent hydrogen, a hydrocaryl group, a substituted hydrocarbyl group, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R¹, R² and R³ is hydrogen, with a boron compound represented by the following general formula (II), (III), (IV) or (V): B(R⁴)₃ (II) (R⁴BO)₃ (III) B(R⁴)₃ : L (V) wherein R⁴ may be the same or different and represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxy group or an amino group, and L represents a compound capable of forming a complex with B(R⁴)₃.
Claim 4
Dependent Claim
170 words
A process for producing a polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to 500,000, which comprises reacting a polysilazane having a number-average molecular weight of about 100 to about 50,000 and containing a skeletal structure of a recurring unit represented by the general formula (I): wherein R¹, R² and R³, independently from each other, represent hydrogen, a hydrocaryl group, a substituted hydrocarbyl group, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R¹, R² and R³ is hydrogen, with a boron compound represented by the following general formula (II), (III), (IV) or (V): B(R⁴)₃ (II) (R⁴BO)₃ (III) B(R⁴)₃ : L (V) wherein R⁴ may be the same or different and represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxy group or an amino group, and L represents a compound capable of forming a complex with B(R⁴)₃.
Claim 5
Dependent Claim
10 words
A polyborosilazane obtained by the process according to claim 2.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
Maintenance schedule is calculated for granted US utility patents.