EP0386674A2
Expired / Lapsed
EP
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Thermoplastic polyester resin composition having improved impact resistance
Assignee: Mitsubishi Chemical Corp
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Filing: 1990-03-05
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Granted: —
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Expires: 2010-03-05
Abstract
Abstract A thermoplastic polyester resin composition having an improved impact resistance is disclosed. This composition is comprised of (A) 30 to 70 weight parts of a polyester resin composed mainly of a polyalkylene terephthalate, (B) 5 to 28 weight parts of a polycarbonate resin, (C) 5 to 35 weight parts of a graft copolymer obtained by graft-polymerizing a monomer selected from aromatic vinyl monomers and methacrylic acid ester monomers in the presence of a rubbery polymer, and (D) 10 to 45 weight parts of a polyphenylene ether resin, which further comprises (E) 2 to 20 weight parts, per 100 weight parts of the resin composition comprising the components (A) through (D), of a copolymer having a main chain of a polyolefin copolymerized with glycidyl methacrylate and a side chain of a styrene polymer, in which the content of glycidyl methacrylate in the polyolefin copolymerized with glycidyl methacrylate is 5 to 30 weight %.
Inventors
- 👤 Hongo C/O Otake Plants Masafumi
- 👤 Shigemitsu C/O Otake Plants Hideyuki
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-06 13:23
CPC Classifications
C; C08; C08L; C08L51/00; C08L51/04; C08L67/00; C08L67/02; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L69/00
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
192 words
A thermoplastic polyester resin composition having an improved impact resistance, which comprises (A) 30 to 70 parts by weight of a polyester resin mainly composed of units derived from an aromatic dicarboxylic acid having 8 to 22 carbon atoms or a functional derivative thereof and units derived from an alkylene glycol, cycloalkylene glycol, or aralkylene glycol, having 2 to 22 carbon atoms, (B) 5 to 28 parts by weight of a polycarbonate resin, (C) 5 to 35 parts by weight of a graft copolymer obtained by graft-polymerizing at least one monomer selected from the group consisting of aromatic vinyl monomers and methacrylic acid ester monomers in the presence of a rubbery polymer, and (D) 10 to 45 parts by weight of a polyphenylene ether resin, which further comprises (E) 2 to 20 parts by weight, per 100 parts by weight of the resin composition comprising the components (A) through (D), of a copolymer having a main chain of a polyolefin copolymerized with glycidyl methacrylate and a side chain of a styrene polymer, in which the content of glycidyl methacrylate in the polyolefin copolymerized with glycidyl methacrylate is 5 to 30% by weight.
Claim 2
Dependent Claim
192 words
A thermoplastic polyester resin composition having an improved impact resistance, which comprises (A) 30 to 70 parts by weight of a polyester resin mainly composed of units derived from an aromatic dicarboxylic acid having 8 to 22 carbon atoms or a functional derivative thereof and units derived from an alkylene glycol, cycloalkylene glycol, or aralkylene glycol, having 2 to 22 carbon atoms, (B) 5 to 28 parts by weight of a polycarbonate resin, (C) 5 to 35 parts by weight of a graft copolymer obtained by graft-polymerizing at least one monomer selected from the group consisting of aromatic vinyl monomers and methacrylic acid ester monomers in the presence of a rubbery polymer, and (D) 10 to 45 parts by weight of a polyphenylene ether resin, which further comprises (E) 2 to 20 parts by weight, per 100 parts by weight of the resin composition comprising the components (A) through (D), of a copolymer having a main chain of a polyolefin copolymerized with glycidyl methacrylate and a side chain of a styrene polymer, in which the content of glycidyl methacrylate in the polyolefin copolymerized with glycidyl methacrylate is 5 to 30% by weight.
Claim 3
Dependent Claim
41 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyester resin (A) is mainly composed of units derived from terephthalic acid and units derived from an alkylene glycol, cycloalkylene glycol or aralkylene glycol, having 2 to 22 carbon atoms.
Claim 4
Dependent Claim
28 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyester resin (A) is selected from the group consisting of polybutylene terephthalate, polyhexylene terephthalate and polyethylene terephthalate.
Claim 5
Dependent Claim
71 words
The thermoplastic polyester resin composition according to claim 1, wherein the polycarbonate resin (B) is prepared by reaction of a dihydroxyl compound and an optional polyhydroxyl compound with phosgene or a diester of carbonic acid; said dihydroxyl compound being a dihydroxydiarylalkane selected from the group consisting of 4,4′-dihydroxy-2,2-diphenylpropane (bisphenol A), tetramethylbisphenol A and bis-(4-hydroxyphenyl)-p-diisopropylbenzene; and said optional polyhydroxyl compound is selected from the group consisting of phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptene, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane and 1,3,5-tri-(4-hydroxyphenyl)-benzene.
Claim 6
Dependent Claim
29 words
The thermoplastic polyester resin composition according to claim 1, wherein said graft copolymer (C) comprises 30 to 80% by weight, based on the graft copolymer, of the rubbery polymer.
Claim 7
Dependent Claim
63 words
The thermoplastic polyester resin composition according to claim 1, wherein the rubbery polymer in the graft copolymer (C) is selected from the group consisting of polybutadiene rubbers, copolymers comprising at least 50% by weight of butadiene units and a minor amount of styrene units or acrylonitrile units, polyacrylic acid ester rubbers, polyorganosiloxane rubbers, and composite rubbers comprising at least two of these rubbers.
Claim 8
Dependent Claim
33 words
The thermoplastic polyester resin composition according to claim 1, wherein the monomer to be graft-polymerized comprises at least one monomer selected from the group consisting of styrene, α-methylstyrene, methyl methacrylate and ethyl methacrylate.
Claim 9
Dependent Claim
48 words
The thermoplastic polyester resin composition according to claim 1, wherein said graft copolymer (C) can be obtained by the stepwise graft polymerization wherein a styrene type monomer is graft-polymerized at the final stage or by the simultaneous graft polymerization of a monomer mixture containing a styrene type monomer.
Claim 10
Dependent Claim
67 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyphenylene ether resin (D) is a homopolymer or copolymer having recurring units represented by the following formula: wherein R₁ , R₂ , R₃ and R₄ are independently selected from the group consisting of a hydrogen atom, alkyl groups, halogen atoms, a nitro group and an amino group, and n is a number of at least 30.
Claim 11
Dependent Claim
41 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyphenylene ether resin (D) is selected from the group consisting of poly(2,6-dimethyl-1,4-phenylene)ether, poly(2,3,6-trimethyl-1,4-phenylene)ether, poly(2,6-diethyl-1,4-phenylene)ether, poly(2,6-diethyl-1,4-phenylene)ether, poly(2,6-dipropyl-1,4-phenylene)ether, poly(2-methyl-6-ethyl-1,4-phenylene)ether, poly(2-methyl-6-propyl-1,4-phenylene ether, poly(2-ethyl-6-propyl-1,4-phenyl)ether, a (2,6-dimethyl-1,4-phenylene)ether/(2,3,6-trimethyl-1,4-phenylene)ether copolymer, a (2,6-dimethyl-1,4-phenylene)ether/(2,3,6-trimethyl-1,4-phenylene)ether copolymer, and a (2,6-dimethyl-1,4-phenylene)ether/(2,3,6-triethyl-1,4-phenylene)ether copolymer.
Claim 12
Dependent Claim
30 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyphenylene ether resin (D) has a reduced viscosity of 0.3 to 0.7 dl/g as measured at 25°C in chloroform.
Claim 13
Dependent Claim
33 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyolefin in the copolymer (E) is derived from at least one α-olefin selected from the group consisting of ethylene, propylene and butene-1.
Claim 14
Dependent Claim
33 words
The thermoplastic polyester resin composition according to claim 1, wherein the polyolefin in the copolymer (E) is polyethylene and occupies at least 50% by mole of the main chain of the copolymer (E).
Claim 15
Dependent Claim
47 words
The thermoplastic polyester resin composition according to claim 1, wherein the styrene polymer constituting the side chain of the copolymer (E) is polystyrene or a copolymer comprising at least 80% by weight of styrene and not more than 20% by weight of maleic anhydride or methyl methacrylate.
Claim 16
Dependent Claim
32 words
The thermoplastic polyester resin composition according to claim 1, wherein the content of the styrene polymer in the copolymer (E) is from 10 to 90% by weight based on the copolymer (E).
Claim 17
Dependent Claim
28 words
The thermoplastic polyester resin composition according to claim 1, wherein the amount of the polyester resin (A) is larger than the amount of the polyphenylene ether resin (D).
References Cited (Backward Citations)
No citation records indexed.
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