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EP0382365A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for producing organosilicon products

Assignee: Dow Silicones UK Ltd
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Filing: 1990-01-22
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Granted: —
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Expires: 2010-01-22
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Abstract

Abstract A process for the preparation of an organosilicon condensa­tion product which comprises reacting together at a temperature of at least 50°C (A) an organosilicon compound having in the molecule at least one silicon-bonded hydroxyl group and (B) an organosilicon compound having in the molecule at least one silicon-bonded -OX group, in which X represents an alkyl group having from 1 to 8 carbon atoms or an alkoxyalkyl group having from 2 to 8 carbon atoms, in the presence of a catalytic substance which is selected from strontium hydroxide and barium hydroxide.

Inventors

  • 👤 Sian Beverley Rees
  • 👤 Stephen Westall

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 18:04
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/18; C08G77/06; C08G77/08; C08G77/20; C08G77/22

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 167 words
A process for the preparation of an organosilicon conden­sation product which comprises reacting together at a tempera­ture of at least 50°C (A) an organosilicon compound having in the molecule at least one silicon-bonded hydroxyl group and wherein the organic substituents are selected from monovalent hydrocarbon groups having from 1 to 18 carbon atoms and mono­valent substituted hydrocarbon groups having from 1 to 10 carbon atoms said substituted hydrocarbon groups being non-acidic in character, and (B) an organosilicon compound having in the mole­cule at least one -OX group wherein X represents an alkyl group having from 1 to 8 carbon atoms or an alkoxyalkyl group having from 2 to 8 carbon atoms, any remaining silicon-bonded substi­tuents in the organosilicon compound being selected from mono­valent hydrocarbon groups having from 1 to 18 carbon atoms and monovalent substituted hydrocarbon groups having from 1 to 10 carbon atoms, said substituted hydrocarbon groups being non-­acidic in character, in the presence of a catalyst substance (C) which is strontium hydroxide and/or barium hydroxide.
Claim 2
Dependent Claim 167 words
A process for the preparation of an organosilicon conden­sation product which comprises reacting together at a tempera­ture of at least 50°C (A) an organosilicon compound having in the molecule at least one silicon-bonded hydroxyl group and wherein the organic substituents are selected from monovalent hydrocarbon groups having from 1 to 18 carbon atoms and mono­valent substituted hydrocarbon groups having from 1 to 10 carbon atoms said substituted hydrocarbon groups being non-acidic in character, and (B) an organosilicon compound having in the mole­cule at least one -OX group wherein X represents an alkyl group having from 1 to 8 carbon atoms or an alkoxyalkyl group having from 2 to 8 carbon atoms, any remaining silicon-bonded substi­tuents in the organosilicon compound being selected from mono­valent hydrocarbon groups having from 1 to 18 carbon atoms and monovalent substituted hydrocarbon groups having from 1 to 10 carbon atoms, said substituted hydrocarbon groups being non-­acidic in character, in the presence of a catalyst substance (C) which is strontium hydroxide and/or barium hydroxide.
Claim 3
Dependent Claim 23 words
A process as claimed in Claim 1 wherein (A) and (B) are reacted at a temperture in the range from 60°C to 180°C.
Claim 4
Dependent Claim 18 words
A process as claimed in Claim 1 or Claim 2 wherein organo­silicon compound (A) is a silanol-terminated polydiorgano­siloxane.
Claim 5
Dependent Claim 85 words
A process as claimed in any one of the preceding claims wherein (B) is a compound falling within the general formula G y Si(OX) 4-y wherein y has a value of 1, 2 or 3, G represents a monovalent hydrocarbon group having from 1 to 18 carbon atoms or a monovalent substituted hydrocarbon group having from 1 to 10 carbon atoms and X represents an alkyl group having from 1 to 8 carbon atoms or an alkoxyalkyl group having from 2 to 8 carbon atoms.
Claim 6
Dependent Claim 24 words
A process as claimed in any one of the preceding claims wherein X represents an alkyl group having from 1 to 3 carbon atoms.
Claim 7
Dependent Claim 27 words
A process as claimed in any one of the preceding claims which comprises passing a mixture of (A) and (B) over or through a bed containing (C).
Claim 8
Dependent Claim 29 words
A process as claimed in any one of the preceding claims wherein (C) is present dispersed in or on a particulate solid which is inert under the reaction conditions.
Claim 9
Dependent Claim 44 words
A process as claimed in any one of the preceding claims which also comprises contacting the condensation product with a second catalyst which is effective in catalysing the reaction of at least some of the residual silanol groups in said product with each other.

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