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EP0366492A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Liquid developer for electrostatic photography

Assignee: Fujifilm Holdings Corp
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Filing: 1989-10-27
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Granted: —
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Expires: 2009-10-27
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Abstract

Abstract A liquid developing agent for electrostatic photography comprising at least one resin dispersed in a nonaqueous solvent with an electrical resistance of 10 9 Ω cm or more and a dielectric constant of 3.5 or less, wherein said dispersed resin grains comprise copolymer resin grains produced by polymerization of a solution containing at least one monofunctional monomer (a) which is soluble in said nonaqueous solvent but is rendered insoluble by polymerization and at least one monomer (B) which contains at least two polor groups and/or polar linkage groups and is represented by the general formula (II) below Wherein, V represents -0-, -COO-, -OCO-, -CH 2 0CO-, -S0 2 -, -CONH-, -SO 2 NH-, where W represents a hydrocarbon group or has the same meaning as the linkage group: in general formula (II) Q represents a hydrogen atom, or a hydrocarbon group having 1 to 18 carbon atoms which may be substituted by a halogen atom, -OH, -CN, -NH 2 , -COOH, -SOsH or -PO 3 H 2 ; X 1 and X 2 , which may be the same or different, each represents -O-, -S-, -CO-, -CO 2 -, -OCO-, -SO 2 -, -NHC0 2 - or -NHCONH-where Q 1 , Q 2 , Q 3 , Q 4 and Q 5 have the same meaning as Q above; U 1 and U 2 , which may be the same or different, each represents a hydrocarbon group having 1 to 18 carbon atoms which may be substituted or have inserted in a main chain bond where X 3 and X 4 which may be the same or different has the same measuing as X 1 and X 2 above, U 4 represents a hydrocarbon group having 1 to 18 carbon atoms which may be substituted and Q 6 has the same meaning as Q above; b 1 and b 2 , which may be the same or different, each represents a hydrogen atom, a hydrocarbon group, -COO-L or -COO-L- linked via a hydrocarbon where L represents a hydrogen atom or a hydrocarbon group which may be substituted; and m, n and p, which may be the same or different, each represents an integer of 0 to 4 and contains at least two polar groups and/or polar linkage groups in the presence of a resin for dispersion stabilization which is soluble in said nonaqueous solvent and is a polymer which has repeating units represented by the general formula (I) below Wherein, T 1 represents -COO-, -OCO-, -CH 2 0CO-, -CH 2 COO-, -0- or -SO 2 -. Y 1 represents an aliphatic group having 6 to 32 carbon atoms; a' and a 2 , which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group having 1 to 8 carbon atoms, -COO-Z 1 or -COO-Z 1 linked via a hydrocarbon group having 1 to 8 carbon atoms where Z 1 represents a hydrocarbon group having 1 to 22 carbon atoms, a portion of which is crosslinked and in which an acidic group selected from the group consisting of -P0 3 H 2 , -SOsH, -COOH, -OH, -SH and groups, where where R° represents a hydrocarbon group, is bonded to only one end of at least one polymer main chain.

Inventors

  • 👤 Eiichi C/Ofuji Photo Film Co. Ltd. Kato
  • 👤 Kazuo C/O Fuji Photo Film Co. Ltd. Ishii

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-24 08:03
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/12; G03G9/13; G03G9/131; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/105

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 540 words
A liquid developer for electrostatic photography comprising at least one resin dispersed in a nonaqueous solvent with an electrical resistance of 10 9 Ω cm or more and a dielectric constant of 3.5 or less, wherein said dispersed resin grains comprise copolymer resin grains produced by polymerization of a solution containing at least one monofunctional monomer (a) which is soluble in said nonaqueous solvent but is rendered insoluble by polymerization and at least one monomer (B) which contains at least two polar groups and/or polar linkage groups and is represented by the general formula (11) below Wherein, V represents -0-, -COO-, -OCO-, -CH 2 0CO-, -S0 2 -, -CONH-, -SO 2 NH-, where W represents a hydrocarbon group or has the same meaning as the linkage group: in general formula (II) Q represents a hydrogen atom, or a hydrocarbon group having 1 to 18 carbon atoms which may be substituted by a halogen atom, -OH, -CN, -NH 2 , -COOH, -SO 3 H or -P0 3 H 2 ; X, and X 2 , which may be the same or different, each represents -0-, -S-, -CO-, -C0 2 -, -OCO-, -S0 2 -, -NHCO 2 - or -NHCONH-where Q 1 , Q 2 , Q 3 , Q 4 and Q 5 have the same meaning as Q above; U 1 and U 2 , which may be the same or different, each represents a hydrocarbon group having 1 to 18 carbon atoms which may be substituted or have inserted in a main chain bond where X 3 and X 4 which may be the same or different has the same measuing as X 1 and X 2 above, U 4 represents a hydrocarbon group having 1 to 18 carbon atoms which may be substituted and Q 6 has the same meaning as Q above; b 1 and b 2 , which may be the same or different, each represents a hydrogen atom, a hydrocarbon group, -COO-L or -COO-L- linked via a hydrocarbon where L represents a hydrogen atom or a hydrocarbon group which may be substituted; and m, n and p, which may be the same or different, each represents an integer of 0 to 4; in the presence of a resin for dispersion stabilization which is soluble in said nonaqueous solvent and is a polymer which has repeating units represented by the general formula (I) below Wherein, T 1 represents -COO-, -OCO-, -CH 2 0CO-, -CH 2 COO-, -O- or -S0 2 -. Y 1 represents an aliphatic group having 6 to 32 carbon atoms; a 1 and a 2 , which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group having 1 to 8 carbon atoms, -COO-Z 1 or -COO-Z 1 linked via a hydrocarbon group having 1 to 8 carbon atoms where Z 1 represents a hydrocarbon group having 1 to 22 carbon atoms, a portion of which is crosslinked and in which an acidic group selected from the group consisting of -PO 3 H 2 , -SO 3 H, -COOH, -OH, -SH and groups, where where R° represents a hydrocarbon group, is bonded to only one end of at least one polymer main chain.
Claim 2
Dependent Claim 540 words
A liquid developer for electrostatic photography comprising at least one resin dispersed in a nonaqueous solvent with an electrical resistance of 10 9 Ω cm or more and a dielectric constant of 3.5 or less, wherein said dispersed resin grains comprise copolymer resin grains produced by polymerization of a solution containing at least one monofunctional monomer (a) which is soluble in said nonaqueous solvent but is rendered insoluble by polymerization and at least one monomer (B) which contains at least two polar groups and/or polar linkage groups and is represented by the general formula (11) below Wherein, V represents -0-, -COO-, -OCO-, -CH 2 0CO-, -S0 2 -, -CONH-, -SO 2 NH-, where W represents a hydrocarbon group or has the same meaning as the linkage group: in general formula (II) Q represents a hydrogen atom, or a hydrocarbon group having 1 to 18 carbon atoms which may be substituted by a halogen atom, -OH, -CN, -NH 2 , -COOH, -SO 3 H or -P0 3 H 2 ; X, and X 2 , which may be the same or different, each represents -0-, -S-, -CO-, -C0 2 -, -OCO-, -S0 2 -, -NHCO 2 - or -NHCONH-where Q 1 , Q 2 , Q 3 , Q 4 and Q 5 have the same meaning as Q above; U 1 and U 2 , which may be the same or different, each represents a hydrocarbon group having 1 to 18 carbon atoms which may be substituted or have inserted in a main chain bond where X 3 and X 4 which may be the same or different has the same measuing as X 1 and X 2 above, U 4 represents a hydrocarbon group having 1 to 18 carbon atoms which may be substituted and Q 6 has the same meaning as Q above; b 1 and b 2 , which may be the same or different, each represents a hydrogen atom, a hydrocarbon group, -COO-L or -COO-L- linked via a hydrocarbon where L represents a hydrogen atom or a hydrocarbon group which may be substituted; and m, n and p, which may be the same or different, each represents an integer of 0 to 4; in the presence of a resin for dispersion stabilization which is soluble in said nonaqueous solvent and is a polymer which has repeating units represented by the general formula (I) below Wherein, T 1 represents -COO-, -OCO-, -CH 2 0CO-, -CH 2 COO-, -O- or -S0 2 -. Y 1 represents an aliphatic group having 6 to 32 carbon atoms; a 1 and a 2 , which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group having 1 to 8 carbon atoms, -COO-Z 1 or -COO-Z 1 linked via a hydrocarbon group having 1 to 8 carbon atoms where Z 1 represents a hydrocarbon group having 1 to 22 carbon atoms, a portion of which is crosslinked and in which an acidic group selected from the group consisting of -PO 3 H 2 , -SO 3 H, -COOH, -OH, -SH and groups, where where R° represents a hydrocarbon group, is bonded to only one end of at least one polymer main chain.
Claim 3
Dependent Claim 41 words
The liquid developing agent for electrophotography according to Claim 1, wherein the non-aqueous solvent as a carrier liquid is a linear chain or branched chain aliphatic hydrocarbon, an alicyclic hydrocarbon, an aromatic hydrocarbon, a halogen derivative thereof or a mixture thereof.
Claim 4
Dependent Claim 44 words
The liquid developing agent for electrophotography according to Claim 1, wherein T' is -COO-, -OCO-, -CH 2 0CO-, -CH 2 COO- of -O-, Y 1 is an aralkyl group, an alkenyl group or an alkyl group, each having from 8 to 22 carbon atoms.
Claim 5
Dependent Claim 33 words
The liquid developing agent for electrophotography according to Claim 1, wherein the amount of the repeating unit of the monomer (B) to the repeating unit of monomer (A) is 0.1 to 30 wt%.
Claim 6
Dependent Claim 33 words
The liquid developing agent for electrophotography according to Claim 1, wherein the weight average molecular weight of the resin for dispersion stabilization is from 1 x 104- to 6 x 10 5 .
Claim 7
Dependent Claim 20 words
The liquid developing agent for electrophotography according to Claim 1, wherein the dispersed resin particles are colored dispersed resin particles.
Claim 8
Dependent Claim 34 words
The liquid developing agent for electrophotography according to Claim 1, wherein the dispersed resin particles are present in an amount from 0.5 to 50 parts per 1000 parts by weight of the carrier liquid.

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