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EP0365307A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Transparent coatings for graphic applications

Assignee: 3M Co
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Filing: 1989-10-18
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Granted: —
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Expires: 2009-10-18
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Abstract

Abstract This invention relates to transparent films for use in graphics applications, such as, for example, visual transparencies for overhead projectors. One disadvantage of presently available ink-receptive layers for transparent films for pen plotters and ink jet printers is that their high level of sorption capacity leads to poor dimensional stability, which, in turn, leads to curling of the film whenever moisture content changes, either due to imaging, or due simply to changes in humidity or to drying out due to the heat encountered on the stage of an overhead projector. Curl can be reduced by applying the same image receptive layer to both sides of the film, so that any expansion or contraction will be applied symmetrically to both sides of the film. This adds to manufacturing cost, and still may not completely eliminate curl, especially in cases where moisture content differs on opposite sides of the film. Accordingly, it would be desirable to provide an ink-receptive layer for transparent films that has good dimensional stability. This invention provides a hydrophilic, polymeric blend which provides improved durability and reduced curl when used as an image-receptive layer on graphic arts films. The blend comprises at least one water-absorbing, hydrophilic polymeric material, at least one hydrophobic polymeric material having acid functionality, and at least one polyethylene glycol. The layer formed from the blend provides high sorption capacity combined with good physical integrity even when wet, along with dimensional stability. The invention also provides sheets suitable for preparing visual transparencies having a backing bearing on at least one major surface thereof an image-receptive layer formed from the aforementioned blend.

Inventors

  • 👤 Mohammed C/O Minnesota Mining And Igbal
  • 👤 Armin James C/O Minnesota Mining And Paff

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 18:37
CPC Classifications
C; C09; C09D; C09D4/00; C08; C08L; C08L33/00; C08L33/04; C08L33/06; B; B41; B41M; B41M5/00; B41M5/50; B41M5/52; B41M5/5254; C08L101/00; C08L39/00; C09D133/00; C09D133/04; B41M5/5245; C08L71/00; C08L71/02; Y; Y10; Y10S; Y10S430/00; Y10S430/131; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31909

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 55 words
A transparent composition comprising a blend of (a) at least one water-absorbing, hydrophilic, polymeric material, (b) at least one hydrophobic polymeric material having acid functionality, and (c) at least one polyethylene glycol, said composition having a haze value equal to or less than about 15%, as measured in accordance with ASTM D1003 61 (Reapproved 1977).
Claim 2
Dependent Claim 55 words
A transparent composition comprising a blend of (a) at least one water-absorbing, hydrophilic, polymeric material, (b) at least one hydrophobic polymeric material having acid functionality, and (c) at least one polyethylene glycol, said composition having a haze value equal to or less than about 15%, as measured in accordance with ASTM D1003 61 (Reapproved 1977).
Claim 3
Dependent Claim 130 words
The composition of Claim 1 wherein said water absorbing polymeric material is derived from monomeric units selected from the group consisting of: (1) vinyl lactams having the structure wherein n can be 2 or 3; (2) alkyl tertiary amino alkyl acrylates having the structure wherein m can be 1 or 2, R¹ represents hydrogen or -CH₃, R² represents hydrogen or an alkyl group having up to 10 carbon atoms, and R³ represents an alkyl group having up to 10 carbon atoms; (3) alkyl quaternary alkyl acrylates having the structure wherein p can be 1 or 2, R¹, R², and R³ are as defined above, R⁴ represents an alkyl group having up to 10 carbon atoms, and X⁻ represents a halide ion, R²SO₄⁻, R³SO₄⁻ or R⁴SO₄⁻; (4) 2-vinylpyridine; and (5) 4-vinylpyridine.
Claim 4
Dependent Claim 19 words
The composition of Claim 2 wherein R² represents hydrogen or an alkyl group having up to 4 carbon atoms.
Claim 5
Dependent Claim 17 words
The composition of Claim 2 wherein R³ represents an alkyl group having up to 4 carbon atoms.
Claim 6
Dependent Claim 18 words
The composition according to Claim 2 wherein R⁴ represents an alkyl group having up to 4 carbon atoms.
Claim 7
Dependent Claim 82 words
The composition of Claim 1 wherein said hydrophobic monomeric units are selected from the group consisting of (1) acrylates and methacrylates having the structure wherein R⁵ represents hydrogen or -CH₃, and R⁶ represents an alkyl group having up to 4 carbon atoms, a cycloaliphatic group having up to 9 carbon atoms in the cyclic ring, a substituted or unsubstituted aromatic group, and an oxygen-containing heterocyclic group having up to 10 carbon atoms; (2) acrylonitrile; (3) styrene; (4) α-methylstyrene; and (5) vinyl acetate.
Claim 8
Dependent Claim 17 words
The composition of Claim 6 wherein R⁶ represents an alkyl group having 1 or 2 carbon atoms.
Claim 9
Dependent Claim 11 words
The composition of Claim 6 wherein R⁶ represents an isobornyl group.
Claim 10
Dependent Claim 11 words
The composition of Claim 6 wherein R⁶ represents a benzyl group.
Claim 11
Dependent Claim 11 words
The composition of Claim 6 wherein R⁶ represents a tetrahydrofurfuryl groups.
Claim 12
Dependent Claim 50 words
The composition of Claim 1 wherein said at least one hydrophobic polymeric material having acid functionality is a copolymer prepared from hydrophobic monomeric units and acrylic acid or methacrylic acid monomeric units, said acid monomeric units comprising from about 2% by weight to about 20% by weight of said copolymer.
Claim 13
Dependent Claim 50 words
The composition of Claim 1 wherein said at least one hydrophobic polymeric material having acid functionality is a copolymer prepared from hydrophobic monomeric units and acrylic acid or methacrylic acid monomeric units, said acid monomeric units comprising from about 5% by weight to about 12% by weight of said copolymer.
Claim 14
Dependent Claim 17 words
The composition of Claim 1 wherein said polyethylene glycol has a molecular weight of less than 4000.
Claim 15
Dependent Claim 25 words
A transparent sheet comprising a thin, transparent backing bearing on at least one major surface thereof an ink-receptive layer comprising the composition of Claim 1.
Claim 16
Dependent Claim 16 words
The transparent sheet of Claim 14 wherein overlying said ink-receptive layer is an ink-permeable protective layer.
Claim 17
Dependent Claim 13 words
The transparent sheet of Claim 15 wherein said protective layer contains particulate material.
Claim 18
Dependent Claim 12 words
The transparent sheet of Claim 15 wherein said particulate material is starch.

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