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EP0358153A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Automotive coating compositions

Assignee: Kansai Paint Co Ltd
•
Filing: 1989-09-04
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Granted: —
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Expires: 2009-09-04
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Abstract

Abstract Disclosed is an automotive coating composition comprising (i) a basal resin which is either (a) a copolymer containing a specific polysiloxane macromonomer having two or more functional groups selected from the class consisting of hydroxyl and alkoxy groups per molecule and a number average molecular weight of 400 to 100,000 and an oxirane group-containing vinyl monomer as comonomer units or (b) a mixture of a polymer (I) containing said polysiloxane macromonomer as an essential monomer unit and a polymer (II) containing an oxirane group-containing vinyl monomer as an essential monomer unit and (ii) a chelate compound selected from the class consisting of aluminium chelate compounds, titanium chelate compounds and zirconium chelate compounds.

Inventors

  • 👤 Ichiro Tabuchi
  • 👤 Noboru Nakai
  • 👤 Osamu Isozaki
  • 👤 Takao Matoba
  • 👤 Shinji Sugiura

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:05
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; C09D183/06; C08; C08K; C08K5/00; C08K5/0091; C09D143/00; C09D143/04

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 258 words
An automotive coating composition comprising (i) 100 parts by weight of a basal resin which is either (a) a copolymer containing a polysiloxane macro­monomer having two or more functional groups selected from the class consisting of hydroxyl and alkoxy groups per molecule and a number of average molecular weight of 40 to 100,000 as obtainable by reacting 70 to 99.999 mole percent of a compound (A) of the general formula: wherein R₁ is an aliphatic hydrocarbon group of 1 to 8 carbon atoms or a phenyl group; R₂, R₃ and R₄ in­dependently mean an alkoxy group of 1 to 4 carbon atoms or a hydroxyl group with 30 to 0.001 mole percent of a compound (B) of the general formula wherein R₅ is a hydrocarbon atom or a methyl group; R₆, R₇ and R₈ independently mean a hydroxyl group, an alkoxy group of 1 to 4 carbon atoms or an aliphatic hydrocarbon group of 1 to 8 carbon atoms; provided, however, that not all of R₆, R₇ and R₈ are aliphatic hydrocarbon groups of 1 to 8 carbon atoms; n is an integer equal to 1 to 6, inclusive, and an oxirane group-containing vinyl monomer as comonomer units or (b) a mixture of a polymer (I) containing said polysiloxane macromonomer as an essential monomer unit and a polymer (II) containing an oxirane group-­containing vinyl monomer as an essential monomer unit and (ii) 0.1 to 30 parts by weight of a chelate compound selected from the class consisting of aluminum chelate compounds, titanium chelate compounds and zirconium chelate compounds.
Claim 2
Dependent Claim 258 words
An automotive coating composition comprising (i) 100 parts by weight of a basal resin which is either (a) a copolymer containing a polysiloxane macro­monomer having two or more functional groups selected from the class consisting of hydroxyl and alkoxy groups per molecule and a number of average molecular weight of 40 to 100,000 as obtainable by reacting 70 to 99.999 mole percent of a compound (A) of the general formula: wherein R₁ is an aliphatic hydrocarbon group of 1 to 8 carbon atoms or a phenyl group; R₂, R₃ and R₄ in­dependently mean an alkoxy group of 1 to 4 carbon atoms or a hydroxyl group with 30 to 0.001 mole percent of a compound (B) of the general formula wherein R₅ is a hydrocarbon atom or a methyl group; R₆, R₇ and R₈ independently mean a hydroxyl group, an alkoxy group of 1 to 4 carbon atoms or an aliphatic hydrocarbon group of 1 to 8 carbon atoms; provided, however, that not all of R₆, R₇ and R₈ are aliphatic hydrocarbon groups of 1 to 8 carbon atoms; n is an integer equal to 1 to 6, inclusive, and an oxirane group-containing vinyl monomer as comonomer units or (b) a mixture of a polymer (I) containing said polysiloxane macromonomer as an essential monomer unit and a polymer (II) containing an oxirane group-­containing vinyl monomer as an essential monomer unit and (ii) 0.1 to 30 parts by weight of a chelate compound selected from the class consisting of aluminum chelate compounds, titanium chelate compounds and zirconium chelate compounds.
Claim 3
Dependent Claim 53 words
The automotive coating composition of claim 1 wherein said compound (A) is at least one compound selected from the class consisting of methyltrimethoxy­silane, phenyltrimethoxysilane, butyltrimethoxysilane, methyltriethoxysilane, methyltributoxysilane, phenyl­trisilanol and methyltrisilanol and said compound (B) is at least one compound selected from the class consisting of γ-methacryloxypropyltrimethoxysilane, γ-methacryloxypropyltriethoxysilane, γ-acryloxypropyl­trimethoxysilane, γ-methacryloxybutyltriethoxysilane, γ-acryloxypropyltrisilanol, γ-acryloxypropylmethyl­dimethoxysilane and γ-methacryloxypropylmethyl­dimethoxysilane.
Claim 4
Dependent Claim 30 words
The automotive coating composition of at least one of the claims 1 to 2 wherein said polysiloxane macromonomer has an average of 0.2 to 1.9 polymerizable unsaturated bonds per molecule.
Claim 5
Dependent Claim 27 words
The automotive coating composition of at least one of the claims 1 to 3 wherein said oxirane group-containing vinyl monomer is an alicyclic oxirane group-containing vinyl monomer.
Claim 6
Dependent Claim 45 words
The automotive coating composition of at least one of the claims 1 to 4 wherein said basal resin is a copolymer containing a polysiloxane macromonomer and an oxirane group-containing vinyl monomer as comonomer units and having a number average molecular weight of 3,000 to 30,000.
Claim 7
Dependent Claim 50 words
The automotive coating composition of at least one of the claims 1 to 4 wherein said basal resin is a polymer mixture consisting of, based on the total amount of polymers, 5 to 95 weight percent of said polymer (I) and 95 to 5 weight percent of said polymer (II).
Claim 8
Dependent Claim 30 words
The automotive coating composition of at least one of the claims 1 to 6 wherein said chelate compound contains a compound capable of keto-enol tautomerism as a chelate ring-­forming ligand.
Claim 9
Dependent Claim 62 words
The automotive coating composition of at least one of the claims 1 to 7 which further contains a low molecular weight compound contaiing at least two oxirane groups per molecule and having a number average molecular weight of not more than 2,000 in a proportion of 5 to 60 parts by weight based on 100 parts by weight of said basal resin.
Claim 10
Dependent Claim 21 words
The automotive coating composition of at least one of the claims 1 to 8 which is used as an intermediate coating.
Claim 11
Dependent Claim 21 words
The automotive coating composition of at least one of the claims 1 to 8 which is used as a top coating.

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