EP0355497A2
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Polyorganosiloxane compounds
Assignee: JNC Corp
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Filing: 1989-08-01
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Granted: —
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Expires: 2009-08-01
Abstract
Abstract A polyorganosiloxane compound which has a fluorine-containing group at its α -position and one or more than one hydrosilyl group at its ω -position, has a fluorine-containing group located at least at its α -and α ′-position and one or more than one hydrosilyl group at its ω -position or has a fluorine-containing group at least at its α -,α ′- and α ˝-position and one or more than one hydrosilyl group at its ω -position. The polyorganosiloxane compound can provide various improved properties as well as new properties to synthetic resins by a chemical connection to the synthetic resins with a functional group or groups reactive with the amino group at the other terminal thereof.
Inventors
- 👤 Takahiro Saho
- 👤 Yoshinori Akutsu
- 👤 Takaharu Nakano
- 👤 Nobumasa Ohtake
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-06 12:24
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0834; C07F7/0838; C08G77/22; C08G77/24; C08G77/382; C08G77/385; C08G77/48; C08G77/50
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
213 words
A polyorganosiloxane compound represented by the following general formula (I): [in which j is an integer from 2 to 2,000; R¹ is a pentafluorophenyl group or a linear or branched fluoroalkyl group as represented by the following general formula (II): C a H b F 2a-b+1 (II) (wherein a is an integer from 3 to 18; and b is 0 or an integer of 2 a ) R² is 3-(m-hydroxyphenyl)propyl group, 3-(o-hydroxyphenyl)propyl group, 3-(p-hydroxyphenyl)propyl group, a substituent as represented by the general formula (III): (wherein h⁰ is an integer from 1 to 6; and h¹ and h² are independently each 0 or an integer from 1 to 20), a substituent as represented by the following general formula (IV): (wherein X¹ is a hydrogen atom, methyl group or ethyl group; h³, h⁴, h⁵ and h⁶ are independently 0 or an integer from 1 to 20; and h⁰, h¹ and h² have the same meanings as above), or a substituent as represented by the following general formula (V): (wherein X² is a hydrogen atom, methyl group or ethyl group; and h⁰, h¹, h², h³, h⁴, h⁵ and h⁶ have the same meanings as above); and R³ and R⁴ are independently each an alkyl group having from 1 to four carbon atoms or a phenyl group).
Claim 2
Dependent Claim
213 words
A polyorganosiloxane compound represented by the following general formula (I): [in which j is an integer from 2 to 2,000; R¹ is a pentafluorophenyl group or a linear or branched fluoroalkyl group as represented by the following general formula (II): C a H b F 2a-b+1 (II) (wherein a is an integer from 3 to 18; and b is 0 or an integer of 2 a ) R² is 3-(m-hydroxyphenyl)propyl group, 3-(o-hydroxyphenyl)propyl group, 3-(p-hydroxyphenyl)propyl group, a substituent as represented by the general formula (III): (wherein h⁰ is an integer from 1 to 6; and h¹ and h² are independently each 0 or an integer from 1 to 20), a substituent as represented by the following general formula (IV): (wherein X¹ is a hydrogen atom, methyl group or ethyl group; h³, h⁴, h⁵ and h⁶ are independently 0 or an integer from 1 to 20; and h⁰, h¹ and h² have the same meanings as above), or a substituent as represented by the following general formula (V): (wherein X² is a hydrogen atom, methyl group or ethyl group; and h⁰, h¹, h², h³, h⁴, h⁵ and h⁶ have the same meanings as above); and R³ and R⁴ are independently each an alkyl group having from 1 to four carbon atoms or a phenyl group).
Claim 3
Dependent Claim
24 words
A polyorganosiloxane compound as claimed in claim 1, wherein the substituent represented by the symbol R¹ is 3,3,3-trifluoropropyl group, tridecafluoro-1,1,2,2-tetrahydrooctyl group or heptadecafluoro-1,1,2,2-tetrahydrodecyl group.
Claim 4
Dependent Claim
244 words
A polyorganosiloxane compound as represented by the following general formula (VI): [in which k and l each is an integer from 2 to 2,000; R⁵ and R⁶ are independently each an alkyl group having from 1 to 4 carbon atoms, pentafluorophenyl group or a linear or branched fluoroalkyl group as represented by the following general formula (II): C a H b F 2a-b+1 (II) (wherein a is an integer from 3 to 18; and b is 0 or an integer of 2 a ), provided, however, that at least one of R⁵ and R⁶ is the pentafluorophenyl group or the fluroalkyl group; R² is 3-(m-hydroxyphenyl)propyl group, 3-(o-hydroxyphenyl)propyl group, 3-(p-hydroxyphenyl)propyl group, a substituent as represented by the general formula (III): (wherein h o is an integer from 1 to 6; and h¹ and h² are independently each 0 or an integer from 1 to 20), a substituent as represented by the following general formula (IV): (wherein X¹ is a hydrogen atom, methyl group or ethyl group; h³, h⁴, h⁵ and h⁶ are independently 0 or an integer from 1 to 20; and h⁰, h¹ and h² have the same meanings as above), or a substituent as represented by the following general formula (V): (wherein X is a hydrogen atom, methyl group or ethyl group; and h⁰, h¹, h², h³, h⁴, h⁵ and h⁶ have the same meanings as above); and R⁷ is an alkyl group having 1 to four carbon atoms or a phenyl group].
Claim 5
Dependent Claim
244 words
A polyorganosiloxane compound as represented by the following general formula (VI): [in which k and l each is an integer from 2 to 2,000; R⁵ and R⁶ are independently each an alkyl group having from 1 to 4 carbon atoms, pentafluorophenyl group or a linear or branched fluoroalkyl group as represented by the following general formula (II): C a H b F 2a-b+1 (II) (wherein a is an integer from 3 to 18; and b is 0 or an integer of 2 a ), provided, however, that at least one of R⁵ and R⁶ is the pentafluorophenyl group or the fluroalkyl group; R² is 3-(m-hydroxyphenyl)propyl group, 3-(o-hydroxyphenyl)propyl group, 3-(p-hydroxyphenyl)propyl group, a substituent as represented by the general formula (III): (wherein h o is an integer from 1 to 6; and h¹ and h² are independently each 0 or an integer from 1 to 20), a substituent as represented by the following general formula (IV): (wherein X¹ is a hydrogen atom, methyl group or ethyl group; h³, h⁴, h⁵ and h⁶ are independently 0 or an integer from 1 to 20; and h⁰, h¹ and h² have the same meanings as above), or a substituent as represented by the following general formula (V): (wherein X is a hydrogen atom, methyl group or ethyl group; and h⁰, h¹, h², h³, h⁴, h⁵ and h⁶ have the same meanings as above); and R⁷ is an alkyl group having 1 to four carbon atoms or a phenyl group].
Claim 6
Dependent Claim
41 words
A polyorganosiloxane compound as claimed in claim 3, wherein the substituents represented by the symbols R⁵ and R⁶ in the general formula (VI) are independently each an alkyl group having 1 to four carbon atoms, 3,3,3-trifluoropropyl group, tridecafluoro-1,1,2,2-tetrahydrooctyl group or heptadecafluoro-1,1,2,2-tetrahydrodecyl.
Claim 7
Dependent Claim
232 words
A polyorganosiloxane compound as represented by the following general formula: [in which m , n and p each independently is an integer from 2 to 2,000; R⁸, R⁹ and R¹⁰ are independently each an alkyl group having from 1 to 4 carbon atoms, pentafluorophenyl group or a linear or branched fluoroalkyl group as represented by the following general formula (II): C a H b F 2a-b+1 (II) (wherein a is an integer from 3 to 18; and b is 0 or an integer of 2 a ), provided, however, that at least one of R⁸, R⁹ and R¹⁰ is the pentafluorophenyl group or the fluroalkyl group; R² is 3-(m-hydroxyphenyl)propyl group, 3-(o-hydroxyphenyl)propyl group, 3-(p-hydroxyphenyl)propyl group, a substituent as represented by the general formula (III): (wherein h o is an integer from 1 to 6; and h¹ and h² are independently each 0 or an integer from 1 to 20), a substituent as represented by the following general formula (IV): (wherein X¹ is a hydrogen atom, methyl group or ethyl group; h³, h⁴, h⁵ and h⁶ are independently 0 or an integer from 1 to 20; and h⁰, h¹ and h² have the same meanings as above), or a substituent as represented by the following general formula (V): (wherein X² is a hydrogen atom, methyl group or ethyl group; and h⁰, h¹, h², h³, h⁴, h⁵ and h⁶ have the same meanings as above).
Claim 8
Dependent Claim
232 words
A polyorganosiloxane compound as represented by the following general formula: [in which m , n and p each independently is an integer from 2 to 2,000; R⁸, R⁹ and R¹⁰ are independently each an alkyl group having from 1 to 4 carbon atoms, pentafluorophenyl group or a linear or branched fluoroalkyl group as represented by the following general formula (II): C a H b F 2a-b+1 (II) (wherein a is an integer from 3 to 18; and b is 0 or an integer of 2 a ), provided, however, that at least one of R⁸, R⁹ and R¹⁰ is the pentafluorophenyl group or the fluroalkyl group; R² is 3-(m-hydroxyphenyl)propyl group, 3-(o-hydroxyphenyl)propyl group, 3-(p-hydroxyphenyl)propyl group, a substituent as represented by the general formula (III): (wherein h o is an integer from 1 to 6; and h¹ and h² are independently each 0 or an integer from 1 to 20), a substituent as represented by the following general formula (IV): (wherein X¹ is a hydrogen atom, methyl group or ethyl group; h³, h⁴, h⁵ and h⁶ are independently 0 or an integer from 1 to 20; and h⁰, h¹ and h² have the same meanings as above), or a substituent as represented by the following general formula (V): (wherein X² is a hydrogen atom, methyl group or ethyl group; and h⁰, h¹, h², h³, h⁴, h⁵ and h⁶ have the same meanings as above).
Claim 9
Dependent Claim
65 words
A polyorganosiloxane compound as claimed in claim 5, wherein the substituents as represented by the reference symbols R⁸, R⁹ and R¹⁰ of the general formula (VII) each independently is an alkyl group having from 1 to four carbon atoms, 3,3,3-trifluoropropyl, tridecafluoro- 1,1,2,2-tetrahydrooctyl group or heptadecafluoro-1,1,2,2- tetrahydrodecyl group and at least one of R⁸, R⁹ and R¹⁰ is the fluorine-containing substituent selected from the above substituents.
Claim 10
Dependent Claim
23 words
A polyorganosiloxane compound as claimed in claim 1, wherein the substituent as represented by the reference symbol R² is: - (CH₂)₃-OCH₂CH₂ - OH
Claim 11
Dependent Claim
23 words
A polyorganosiloxane compound as claimed in claim 2, wherein the substituent as represented by the reference symbol R² is: - (CH₂)₃-OCH₂CH₂ - OH
Claim 12
Dependent Claim
23 words
A polyorganosiloxane compound as claimed in claim 3, wherein the substituent as represented by the reference symbol R² is: - (CH₂)₃-OCH₂CH₂ - OH
Claim 13
Dependent Claim
23 words
A polyorganosiloxane compound as claimed in claim 4, wherein the substituent as represented by the reference symbol R² is: - (CH₂)₃-OCH₂CH₂ - OH
Claim 14
Dependent Claim
23 words
A polyorganosiloxane compound as claimed in claim 5, wherein the substituent as represented by the reference symbol R² is: - (CH₂)₃-OCH₂CH₂ - OH
Claim 15
Dependent Claim
23 words
A polyorganosiloxane compound as claimed in claim 6, wherein the substituent as represented by the reference symbol R² is: - (CH₂)₃-OCH₂CH₂ - OH
Claim 16
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 1, wherein the substituent as represented by the reference symbol R² is:
Claim 17
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 2, wherein the substituent as represented by the reference symbol R² is:
Claim 18
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 3, wherein the substituent as represented by the reference symbol R² is:
Claim 19
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 4, wherein the substituent as represented by the reference symbol R² is:
Claim 20
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 5, wherein the substituent as represented by the reference symbol R² is:
Claim 21
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 6, wherein the substituent as represented by the reference symbol R² is:
Claim 22
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 1, wherein the substituent as represented by the reference symbol R² is:
Claim 23
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 2, wherein the substituent as represented by the reference symbol R² is:
Claim 24
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 3, wherein the substituent as represented by the reference symbol R² is:
Claim 25
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 4, wherein the substituent as represented by the reference symbol R² is:
Claim 26
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 5, wherein the substituent as represented by the reference symbol R² is:
Claim 27
Dependent Claim
19 words
A polyorganosiloxane compound as claimed in claim 6, wherein the substituent as represented by the reference symbol R² is:
References Cited (Backward Citations)
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