EP0348001A1
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EP
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Process for the preparation of zeolitic catalysts
Assignee: Shell Internationale Research Maatschappij BV
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Filing: 1989-06-19
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Granted: —
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Expires: 2009-06-19
Abstract
Abstract Process for the preparation of a zeolitic catalyst which comprises treating a zeolite of the Y-type having an alkali metal oxide/aluminium oxide molar ratio of at most 0.13 with a solution of a multi-valent metal salt having a cationic radius between 0.6 and 1.0 Å and combining the ion-exchanged zeolite without a calcination step with a hydrogenation component of a Group 8 and/or Group 6b metal.
Inventors
- 👤 Tom Huizinga
- 👤 Arend Hoek
- 👤 Hennie Schaper
- 👤 Aan Hendrik Klazinga
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-08 04:43
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/085; B01J29/088; B01J29/084; B01J29/10; B01J29/106; B01J29/12; B01J29/126; B01J29/14; B01J29/146; C; C10; C10G; C10G47/00; C10G47/02; C10G47/10; C10G47/12; C10G47/16; C10G47/20
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
66 words
Process for the preparation of a zeolitic catalyst which comprises treating a zeolite of the Y-type having an alkali metal oxide/aluminium oxide molar ratio of at most 0.13 with a solution of a multi-valent metal salt having a cationic radius between 0.6 and 1.0 Å and combining the ion-exchanged zeolite without a calcination step with a hydrogenation component of a Group 8 and/or Group 6b metal.
Claim 2
Dependent Claim
66 words
Process for the preparation of a zeolitic catalyst which comprises treating a zeolite of the Y-type having an alkali metal oxide/aluminium oxide molar ratio of at most 0.13 with a solution of a multi-valent metal salt having a cationic radius between 0.6 and 1.0 Å and combining the ion-exchanged zeolite without a calcination step with a hydrogenation component of a Group 8 and/or Group 6b metal.
Claim 3
Dependent Claim
32 words
Process according to claim 1 wherein a starting Y zeolite is used which has been obtained by subjecting a high sodium oxide containing Y zeolite to a treatment with an ammonium compound.
Claim 4
Dependent Claim
26 words
Process according to claim 1 or 2 wherein a solution of a multi-valent metal ion is used having a cationic radius between 0.60 and 0.80 Å.
Claim 5
Dependent Claim
22 words
Process according to claim 3 wherein use is made of one or more salts of gallium, iron, copper, magnesium, cobalt and nickel.
Claim 6
Dependent Claim
15 words
Process according to claim 4 wherein use is made of a gallium or nickel salt.
Claim 7
Dependent Claim
24 words
Process according to any one of claims 1 to 5 wherein use is made of a nitrate or a chloride of a multivalent metal.
Claim 8
Dependent Claim
29 words
Process according to any one of claims 1 to 6 wherein use is made of a solution of a multi-valent metal salt having a molarity between 0.005 and 2.
Claim 9
Dependent Claim
24 words
Process according to claim 7 wherein use is made of a solution of a multi-valent metal salt having a molarity between 0.01 and 1.
Claim 10
Dependent Claim
31 words
Process according to any one of claims 1 to 8 wherein the treatment with the multi-valent metal salt solution is carried out at a temperature between 10 and 95 o C.
Claim 11
Dependent Claim
28 words
process according to any one of claims 1 to 9 wherein the ion-exchanged zeolite is subjected to a drying treatment at a temperature up to 200 o C.
Claim 12
Dependent Claim
26 words
Process according to any one of claims 1 to 10 wherein the ion-exchanged zeolite is combined with the hydrogenation component(s) by impregnation, or, in particular, co-mulling.
Claim 13
Dependent Claim
28 words
Process according to claim 11, in which the ion-exchanged zeolite is combined with the hydrogenation component(s) by co-mulling the ion-exchanged zeolite and hydrogenation component(s) together with a binder.
Claim 14
Dependent Claim
30 words
Process according to claim 12, in which the binder is selected from the group of refractory oxides consisting of silica, alumina, silica-alumina, clays, zirconia, silica-zirconia, titania, silica-boria and mixture thereof.
Claim 15
Dependent Claim
16 words
Process according to claim 13, in which the binder is a mixture of silica-alumina and alumina.
Claim 16
Dependent Claim
60 words
Catalyst comprising a zeolite of the Y type having an alkali metal oxide/aluminium oxide molar ratio of at most 0.13 and multi-valent cations with a cationic radius between 0.6 and 1.0 Å at ion-exchangeable positions, and at least one hydrogenation component of a Group 8 and/or Group 6b metal, obtainable by the process according to any one of claims 1-14.
Claim 17
Dependent Claim
20 words
Catalyst according to claim 15, the hydrogenation components having been selected from nickel, cobalt, tungsten, molybdenum, platinum and palladium components.
Claim 18
Dependent Claim
12 words
Catalyst according to claim 15 or 16, which further comprises a binder.
Claim 19
Dependent Claim
13 words
Catalyst whenever prepared by a process according to any one of claims 1-14.
Claim 20
Dependent Claim
15 words
Use of a catalyst according to any one of claims 15-18 in a hydroconversion process.
Claim 21
Dependent Claim
36 words
Hydroconversion process in which a hydrocarbonaceous feedstock is contacted with a zeolite catalyst in the presence of hydrogen under hydroconversion conditions, in which the zeolitic catalyst is a catalyst according to any one of claims 15-18.
Claim 22
Dependent Claim
43 words
Process according to claim 20, in which the temperature is from 250 to 500 o C, the hydrogen pressure is up to 300 bar, the space velocity is from 0.1 to 10 kg/l.h and the H₂/feedstock ratio is from 100 to 5000 Nl/kg.
References Cited (Backward Citations)
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