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EP0345441A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

High-Tc superconductor-gallate crystal structures

Assignee: International Business Machines Corp
•
Filing: 1989-04-15
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Granted: —
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Expires: 2009-04-15
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Abstract

Abstract High-T c oxide superconductive structures (22, 24) can be formed on gallate layers (18, 20), where the gallate layers (18, 20) include a rare earth element or a rare earth-like element. Combinations of rare earth elements and rare earth-like elements can also be utilized. 'The superconductive films can be epitaxially deposited on these gallate layers to form single crystals or, in the minimum, highly oriented superconductive layers. Any high-T c superconductive oxide material can be utilized, but the best lattice matches are to superconductive materials including copper oxides. Examples include Y-Ba-Cu-O systems, Bi-based systems and Tl-based systems.

Inventors

  • 👤 William Joseph Gallagher
  • 👤 Edward August Giess
  • 👤 Arunava Gupta
  • 👤 Robert Benjamin Laibowitz
  • 👤 Eugene John M. O'sullivan
  • 👤 Robert Lee Sandstrom

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 23:31
CPC Classifications
H; H01; H01P; H01P3/00; H01P3/02; H01P3/08; H01P3/085; C; C30; C30B; C30B23/00; C30B23/02; C30B29/00; C30B29/10; C30B29/16; C30B29/22; C30B29/225; H10; H10N; H10N60/00; H10N60/01; H10N60/0268; H10N60/0296; H10N60/0576; H10N60/0604; H10N60/0661; H10N60/0716; H10N60/20; H10N60/203; Y; Y10; Y10S; Y10S428/00; Y10S428/901; Y10S428/922; Y10S428/9265; Y10S428/93; Y10S505/00; Y10S505/70; Y10S505/701; Y10S505/702; Y10S505/704; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49014

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 65 words
A superconductive combination, including at least one crystalline gallate substrate layer (12; 18, 20), at least one superconductive layer (10; 22, 24) thereon, said superconductive layer (10; 22, 24) having a transition temperature in excess of 77 K and being an oxide material having Cu-O planes whose Cu and O atoms substantially align with Ga and O atoms in said gallate substrate (12; 18, 20).
Claim 2
Dependent Claim 65 words
A superconductive combination, including at least one crystalline gallate substrate layer (12; 18, 20), at least one superconductive layer (10; 22, 24) thereon, said superconductive layer (10; 22, 24) having a transition temperature in excess of 77 K and being an oxide material having Cu-O planes whose Cu and O atoms substantially align with Ga and O atoms in said gallate substrate (12; 18, 20).
Claim 3
Dependent Claim 30 words
Combination in accordance with claim 1, characterized in that said gallate layer (12; 18, 20) and/or said superconductive layer (10; 22, 24) includes a rare earth or rare earth-like element.
Claim 4
Dependent Claim 20 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) includes an alkaline earth element.
Claim 5
Dependent Claim 17 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) includes Bi.
Claim 6
Dependent Claim 17 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) includes Tl.
Claim 7
Dependent Claim 20 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) has a 1-2-3 superconducting phase.
Claim 8
Dependent Claim 33 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) has an orthorhombic structure with its a-­and b-axes substantially in the plane of said layer (10; 22, 24).
Claim 9
Dependent Claim 25 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) and said gallate layer (12; 18, 20) have perovskite-like structures.
Claim 10
Dependent Claim 62 words
Combination in accordance with claim 1, characterized in that said crystalline gallate substrate (12; 18, 20) includes a rare earth or rare earth-like element, and that said superconductor layer (10; 22, 24) is in contact with said substrate (12; 18, 20), said superconductor layer (10; 22, 24) being a high-T c copper oxide composition substantially lattice-matched to said substrate (12; 18, 20).
Claim 11
Dependent Claim 23 words
Combination in accordance with claim 9, characterized in that said superconductor layer (10; 20, 24) and said substrate (12; 18, 20) exhibit orthorhombicity.
Claim 12
Dependent Claim 24 words
Combination in accordance with claim 9, characterized in that said superconductor layer (10; 22, 24) and said substrate (12; 18, 20) are single crystals.
Claim 13
Dependent Claim 34 words
Combination in accordance with claim 9, characterized in that the arrangement of atoms on the surface of said substrate (12; 18, 20) contacting said superconductor layer (10; 22, 24) approximates a (100) cubic perovskite.
Claim 14
Dependent Claim 35 words
Combination in accordance with claim 10, characterized in that the unit cell of said superconductor layer (10; 22, 24) is rotated approximately 45° with respect to the unit cell of said substrate (12; 18, 20).
Claim 15
Dependent Claim 102 words
Combination in accordance with claim 1, characterized in that the gallate layer (12; 18, 20) includes at least one rare earth or rare earth-like element, that said superconductor layer (10; 22, 24) is in contact with said gallate layer (12; 18, 20), said superconductor layer (10, 22, 24) being comprised of an oxide material having a transition temperature in excess of 30 K, said superconductor layer (10; 22, 24) being capable of carrying an electrical supercurrent, and that an electrical source (26) is connected to said superconductor layer (10; 22, 24) for providing electrical supercurrents in said superconductor layer (10; 22, 24)
Claim 16
Dependent Claim 20 words
Combination in accordance with claim 14, characterized in that said gallate layer (12; 18, 20) is a rare earth gallate.
Claim 17
Dependent Claim 36 words
Combination in accordance with claim 14, characterized in that it further includes a superconducting ground plane (24) electrically isolated from said superconductor layer (22), said ground plane (24) being comprised of a high-T c oxide superconductor.
Claim 18
Dependent Claim 59 words
Combination in accordance with claim 1, characterized by a rare earth gallate substrate (12; 18, 20), and an oriented layer (10; 22, 24) of a high-T c superconductor on said substrate (12; 18, 20) said superconductor being comprised of Cu-O planes where the Cu-Cu spacing in said superconductor closely approximates the Ga-Ga spacing in said substrate (12; 18, 20).
Claim 19
Dependent Claim 25 words
Combination in accordance with claim 1, characterized in that said superconductive layer (10; 22, 24) is substantially epitaxial with said gallate layer (12; 18, 20).
Claim 20
Dependent Claim 30 words
Combination in accordance with claim 1, characterized by a a second high-T c oxide superconductive layer (24), said gallate layer (18, 20) being located between said superconductive layers (22, 24).
Claim 21
Dependent Claim 22 words
Combination in accordance with claim 1, characterized in that said gallate layer (12; 18, 20) is sufficiently thin to permit tunneling therethrough.

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