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EP0343496A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Conductive composite filament and process for producing the same

Assignee: Kuraray Co Ltd
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Filing: 1989-05-17
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Granted: —
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Expires: 2009-05-17
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Abstract

Abstract Provided by the invention is a highly oriented, undrawn, conductive, composite filament which is white or colorless and has antistatic properties durable over a long period when wears utilizing the fiber are actually put on and washed. The filament is a sheath-core composite fila­ment comprising a sheath of a fiber-forming thermoplastic polymer (A) and a core of a composition (B) comprising a conductive material which comprises a conductive metal oxide(s) and a thermoplastic polyamide, having a core resistance of not more than 9 x 10¹⁰Ω/cm·filament, and maintaining a critical elongation --- an elongation reached in the course of extending a composite filament at which the core resistance exceeds 1 x 10¹¹Ω/cm·filament at a D.C. voltage of 1 kV --- of at least 5% and a shrinkage in hot water at 100°C of not higher than 20%. Such fiber can be obtained by conducting high orientation melt spinning at at least 2,500 m/min while selecting a polyamide as the core component to contain the white or colorless conductive material and having the composition previously dried to a moisture content of 100 to 1,200 ppm.

Inventors

  • 👤 Kazuhiko Tanaka
  • 👤 Yoshiteru Matsuo
  • 👤 Eiichirou Nakamura
  • 👤 Shoji Asano
  • 👤 Masao Kawamoto

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 22:36
CPC Classifications
D; D01; D01F; D01F8/00; D01F8/04; D01F8/12; D01F1/00; D01F1/02; D01F1/09

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 115 words
A highly oriented, undrawn, conductive, composite fila­ment which is a sheath-core composite filament comprising a sheath of a fiber-forming thermoplastic polymer (A) and a core of a composition (B) comprising a conductive material which comprises a conductive metal oxide(s) and a thermo­plastic polyamide, having a critical elongation of at least 5% and a shrinkage in hot water at 100°C of not higher than 20%, said core having a core resistance at a D.C. voltage of 1 kV of less than 9 x 10¹⁰Ω/cm·filament; wherein the criti­cal elongation means an elongation reached in the course of extending a composite filament at which the core resistance exceeds 1 x 10¹¹Ω/cm·filament at a D.C. voltage of 1 kV.
Claim 2
Dependent Claim 115 words
A highly oriented, undrawn, conductive, composite fila­ment which is a sheath-core composite filament comprising a sheath of a fiber-forming thermoplastic polymer (A) and a core of a composition (B) comprising a conductive material which comprises a conductive metal oxide(s) and a thermo­plastic polyamide, having a critical elongation of at least 5% and a shrinkage in hot water at 100°C of not higher than 20%, said core having a core resistance at a D.C. voltage of 1 kV of less than 9 x 10¹⁰Ω/cm·filament; wherein the criti­cal elongation means an elongation reached in the course of extending a composite filament at which the core resistance exceeds 1 x 10¹¹Ω/cm·filament at a D.C. voltage of 1 kV.
Claim 3
Dependent Claim 95 words
The highly oriented, undrawn, conductive, composite filament of Claim 1, wherein said conducive material is a particulate conductive material (W₁) having an average parti­cle diameter of 0.01 to 0.3µ comprising titanium dioxide or barium sulfate coated on the surface thereof with a metal oxide (D) selected from stannic oxide and zinc oxide contain­ing antimonium oxide (C), the ratios by weight of said antimonium oxide (C) and said metal oxide (D) to said particulate conductive material (W₁) satisfying the following formulae (1) and (2) C/W₁ = 0.01 to 0.10      (1) D/W₁ = 0.05 to 0.20      (2).
Claim 4
Dependent Claim 28 words
The highly oriented, undrawn, conductive, composite filament of Claim 1, wherein said conducive material is incorporated in said polyamide in an amount of 60 to 75% by weight.
Claim 5
Dependent Claim 38 words
The highly oriented, undrawn, conductive, composite filament of Claim 1, wherein the ratio by weight of said fiber-forming thermoplastic polymer (A) and said composition (B) comprising a conductive material and a polyamide is: (B)/(A) = 8/92 to 22/78.
Claim 6
Dependent Claim 122 words
A process for producing a highly oriented, undrawn, conductive, composite filament which is a sheath-core composite filament comprising a sheath component of a fiber-­forming thermoplastic polymer (A) and a core component of a composition (B) comprising a conductive material which comprises a conductive metal oxide(s) and a thermoplastic polyamide, which comprises extruding said fiber-forming thermoplastic polymer (A) having an intrinsic viscosity, [η], of at least 0.55 and said composition (B) having a moisture content adjusted by drying to 100 to 1,200 ppm separately through different extruders, and conducting high orientation melt spinning using a composite spinning apparatus at at least 2,500 m/min so that the filaments thus spun will have a shrinkage in hot water of 100°C of not more than 20%.
Claim 7
Dependent Claim 122 words
A process for producing a highly oriented, undrawn, conductive, composite filament which is a sheath-core composite filament comprising a sheath component of a fiber-­forming thermoplastic polymer (A) and a core component of a composition (B) comprising a conductive material which comprises a conductive metal oxide(s) and a thermoplastic polyamide, which comprises extruding said fiber-forming thermoplastic polymer (A) having an intrinsic viscosity, [η], of at least 0.55 and said composition (B) having a moisture content adjusted by drying to 100 to 1,200 ppm separately through different extruders, and conducting high orientation melt spinning using a composite spinning apparatus at at least 2,500 m/min so that the filaments thus spun will have a shrinkage in hot water of 100°C of not more than 20%.

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